Homoleptic rare-earth carbazolates and the trends of their E LnII/III redox potentials: Mixed-valent samarium in ∞1[Sm2(Cbz)5](CbzH) (CbzH = carbazole) and trivalent thulium, neodymium and gadolinium in [Ln 2(Cbz)6]

European Journal of Inorganic Chemistry

Volumn , Issue 21, 2004, Pages 4330-4337

  Müller Buschbaum, Klaus ^a   Quitmann, Catharina C ^a  

^a UNIVERSITY OF COLOGNE   (Germany)

Author keywords

Carbazolates; Lanthanides; N ligands; Solvent free synthesis

Indexed keywords

ATOMS; CHELATION; GADOLINIUM COMPOUNDS; GEOMETRY; NEODYMIUM COMPOUNDS; NITROGEN; POLYCYCLIC AROMATIC HYDROCARBONS; RARE EARTH ELEMENTS; RARE EARTHS; REDOX REACTIONS; SAMARIUM COMPOUNDS; SINGLE CRYSTALS; X RAY ANALYSIS; X RAY POWDER DIFFRACTION;

CARBAZOLATE; GADOLINIA; MELT REACTION; N LIGANDS; N-LIGANDS; NITROGEN ATOM; REDOX POTENTIALS; REDOXPOTENTIAL; SOLVENT FREE SYNTHESIS; TRIVALENTS;

LIGANDS;

BENZENE DERIVATIVE; CARBAZOLE DERIVATIVE; LANTHANUM; NEODYMIUM; NITROGEN DERIVATIVE; SAMARIUM; THULIUM;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; MELTING POINT; MOLECULAR INTERACTION; OXIDATION; RAMAN SPECTROMETRY; REACTION ANALYSIS; REDUCTION; THERMOGRAVIMETRY; X RAY POWDER DIFFRACTION;

EID: 9144265597     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400516     Document Type: Article

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