Hexacoordinate silicon(IV) complexes with SiO6 skeletons and multidentate ligands derived from citric acid or malic acid

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 630, Issue 12, 2004, Pages 2006-2012

  Tacke, Reinhold ^a   Bertermann, Rüdiger ^a   Burschka, Christian ^a   Dragota, Simona ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Citric acid; Coordination chemistry; Hexacoordinate silicon; Malic acid; Silicon; Solid state NMR spectroscopy; Stereochemistry

Indexed keywords

AMINE; ANION; CITRIC ACID; LIGAND; MALIC ACID; SILICATE; SILICON DERIVATIVE; TETRAMETHOXYSILANE; WATER;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DISSOLUTION; HYDROLYSIS; NITROGEN NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE; SOLID STATE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 9144219779     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/zaac.200400237     Document Type: Article

References (34)

1. I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950.
2. R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025.
3. R. Tacke, I. Richter (inventors), PCT Int. Pat. Appl. WO 03/ 061640 Al (applicant: Julius-Maximilians-Universitaet Wuerzburg), 31.07.2003; Chem. Abstr. 2003 139, 154995.
4. 6 skeletons: R. Tacke, O. Seiler, in: Silicon Chemistry: From the Atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, 2003, pp. 325-337.
5. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
6. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
7. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
8. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
9. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
10. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
11. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
12. 6 skeletons: (a) R. Tacke, A. Stewart, J. Becht, C. Burschka, I. Richter, Can. J. Chem. 2000, 78, 1380. (b) R. Tacke, M. Willeke, M. Penka, Z. Anorg. Allg. Chem. 2001, 627, 1236. (c) Ref. [1]. (d) Refs. [2, 3]. (e) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 628, 2427. (g) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chem. 2002, 1, 355. (h) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta 2004, 357, 1955.
13. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
14. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
15. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
16. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
17. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
18. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
19. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
20. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
21. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
22. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
23. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
24. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
25. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
26. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
27. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
28. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
29. Selected reviews dealing with higher-coordinate silicon compounds: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371. (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75-86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pülm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) Ref. [4].
30. The composition of this solvate was deduced from the crystal structure analysis. However, the methanol content of the bulk material might differ from that of the single crystal studied, because the product loses part of the methanol very easily at ambient conditions. This problem also explains the poor quality of the elemental analysis.
31. The hydrogen-bonding systems were analyzed by using the program PLATON: A. L. Spek, PLATON, University of Utrecht, Utrecht, The Netherlands, 1998.
32. G. M. Sheldrick, SHELXS-97, University of Göttingen, Göttingen, Germany, 1997. G. M. Sheldrick, Acta Crystallogr. 1990, A46, 467.
33. G. M. Sheldrick, SHELXS-97, University of Göttingen, Göttingen, Germany, 1997. G. M. Sheldrick, Acta Crystallogr. 1990, A46, 467.
34. G. M. Sheldrick, SHELXL-97, University of Göttingen, Göttingen, Germany, 1997.