Environment-friendly organic synthesis using bismuth compounds. Bismuth triflate catalyzed synthesis of substituted 3,4-dihydro-2H-1-benzopyrans

Tetrahedron Letters

Volumn 45, Issue 51, 2004, Pages 9369-9371

  Nguyen, Mai P ^a   Arnold, Joshua N ^a   Peterson, Katherine E ^a   Mohan, Ram S ^a  

^a ILLINOIS WESLEYAN UNIVERSITY   (United States)

Author keywords

Bismuth and compounds; Bismuth triflate; Dihydrobenzopyrans; Green chemistry

Indexed keywords

BENZOPYRAN DERIVATIVE; BISMUTH; PROPANE; SALICYLALDEHYDE;

ARTICLE; CATALYSIS; CATALYST; DIASTEREOISOMER; ENVIRONMENT; POLYMERIZATION; SYNTHESIS;

EID: 8844243286     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.10.118     Document Type: Article

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26. Bismuth triflate was purchased from Lancaster Chemical Company. It can also be synthesized in the laboratory from triphenylbismuth and triflic acid. See M. Labrouillère, C. Le Roux, H. Gaspard, A. Laporterie, J. Dubac, and J.R. Desmurs Tetrahedron Lett. 40 1999 285
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28. A more convenient procedure uses chlorobenzene as the solvent. See S.M. Peyronneau, C. Arrondo, L. Vendier, N. Roques, and C. Le Roux J. Mol. Catal. A 211 2004 89