Complexes of rhodium(I) and iridium(I) with the chiral tridentate phosphane Pigiphos: Structure and reactivity studies

European Journal of Inorganic Chemistry

Volumn , Issue 4, 2003, Pages 601-609

  Hintermann, Lukas ^a   Perseghini, Mauro ^a   Barbaro, Pierluigi ^b   Togni, Antonio ^a  

^a ETH ZURICH   (Switzerland)

^b CNR   (Italy)

Author keywords

Chiral ligands; Ferrocenyl ligands; Iridium; Phosphanes; Rhodium

Indexed keywords

CHLORINE COMPOUNDS; GEOMETRY; IRIDIUM COMPOUNDS; LIGANDS;

CHIRAL LIGAND; COORDINATE COMPLEXES; FERROCENYL; FERROCENYL LIGANDS; PHOSPHANES; REACTIVITY STUDIES; SQUARE PLANAR GEOMETRY; TRIDENTATE LIGANDS;

RHODIUM COMPOUNDS;

BIS [1[2 (DIPHENYLPHOSPHANYL)FERROCENYL]ETHYL]CYCLOHEXYLPHOSPHANE; HYDROCHLORIC ACID; IRIDIUM COMPLEX; LIGAND; METAL COMPLEX; OXYGEN; PHOSPHANE; PHOSPHORUS DERIVATIVE; RHODIUM COMPLEX; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0037294953     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200390082     Document Type: Article

References (58)

1. [1a] F. A. Cotton, B. Hong, Prog. Inorg. Chem. 1992, 40, 179.
2. [1b] C. R. Johnson, T. Imamoto, J. Org. Chem. 1987, 52, 2170.
3. [1c] M. J. Burk, R. L, Harlow, Angew. Chem. 1990, 102, 1511.
4. [1d] M. J. Burk, J. E. Feaster, R. L. Harlow, Tetrahedron: Asymmetry 1991, 2, 569.
5. [13e] T. R. Ward, L. M. Venanzi, A. Albinati, F. Lianza, T. Gerfin, V. Gramlich, G. M. Ramos Tombo, Helv. Chim. Acta 1991, 74, 983.
6. [13f] H. Heidel, G. Huttner, L. Zsolnai, Z Naturforsch., Teil B 1995, 50, 729.
7. [13g] G. Jia, H. M. Lee, 1. D. Williams, Organometallics 1996, 15, 4235.
8. [13h] Y. Yao, C. J. A. Daley, R. McDonald, S. H. Bergens, Organometallics 1997, 16, 1890.
9. [13i] H. M. Lee, C. Yang, G. Jia, J. Organomet. Chem. 2000, 601, 330.
10. [13j] R. B. King, J. Bakos, C. D. Hoff, L. Markó, J. Org. Chem. 1979, 44, 3095.
11. [13k] H. Heidel, J. Scherer, A. Asam, G. Huttner, O. Walter, L. Zsolnai, Chem. Ber. 1995, 128, 293.
12. [2a] P. Barbaro, A. Togni, Organometallics 1995, 14, 3570.
13. [2b] P. Barbaro, C. Bianchini, A. Togni, Organometallics 1997, 16, 3004.
14. P. Barbaro, C. Bianchini, W. Oberhauser A. Togni, J Mol. Cat. A 1999, 145, 139.
15. R. Dorta, A. Togni, Organometallics 1998, 17, 3423.
16. K. Tani, A. Iseki, T Yamagata, Angew. Chem. Int. Ed. 1998, 37, 3381.
17. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986.
18. M. Sekine, W. D. Harman, H. Taube, Inorg. Chem. 1988, 27, 3604.
19. T. E. Nappier, Jr., D. W. Meek, R. M. Kirchner, J. A. Ibers, J. Am. Chem. Soc. 1973, 95, 4194.
20. G. G. Johnston, M. C. Baird, Organometallics 1989, 8, 1894.
21. [9a] A. L. Crumbliss, R. J. Topping, "Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis" (Eds.: J. G. Verkade, L. D. Quin), in: Methods in Stereochemical Analysis 8, VCH, Weinheim, Germany, 1987, chapter 15, p. 531.
22. 13C NMR of Transition Metal Phosphane Complexes (Eds.: P. Diehl, E. Fluck, R. Kosfeld), Springer-Verlag, Berlin, 1979.
23. D. W. Meek, T J. Mazanec, Acc. Chem. Res. 1981, 14, 266.
24. T. G. Appleton, H. C. Clark, L. E. Manzer, Coord. Chem. Rev. 1973, 10, 335.
25. J. G. Verkade, J. A. Mosbo, "Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis" (Eds.: J. G. Verkade, L. D. Quin), in: Methods in Stereochemical Analysis 8, VCH, Weinheim, Germany, 1987, chapter 13, p. 432.
26. P R. Sharp, in: Comprehensive Organometallic Chemistry II (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, U. K., 1995, vol. 8, chapter 2, p. 138-158.
27. A. G. Orpen, L. Brammer, F. H. Allen, O. Kennard, D. G. Watson, R. Taylor in Structure Correlation (Eds.: H.-B. Bürgi, J. D. Dunitz), VCH, Weinheim, Germany, 1994, vol. 2, p. 751 -857.
28. A. Togni in: Organic Synthesis via Organometallics [OSM5] (Eds.: G. Helmchen, J. Dibo, D. Flubacher, B. Wiese), Vieweg, Braunschweig, 1997, p. 185-208.
29. A. Togni, F. Spindler, G. Rihs, N. Zanetti, M. C. Soares, T. Gerfin, V. Gramlich, Inorg. Chim. Acta 1984, 222, 213.
30. ABM spin system. Data obtained from computer simulation using the program g NMR ver. 4.1.0, IvorySoft, Cherwell Scientific Publishing, 1995-1999.
31. H. Allen, O. Hill, D. G. Tew, "Dioxygen, Superoxide and Peroxide", in: Comprehensive Coordination Chemistry (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon Press, Oxford, England, 1987, vol. 2, p. 315.
32. L. Vaska, Acc. Chem. Res. 1976, 9, 175.
33. M. H. Gubelmann, A. F. Williams, Struct. Bonding [Berlin] 1983, 55, 1.
34. Oxygen Complexes and Oxygen Activation by Transition Metal (Eds.: A. E. Martell, D. T Sawyer), Plenum Press, New York, 1988.
35. H. Mimoun, "Metal Complexes in Oxidation" in: Comprehensive Organometallic Chemistry (Eds.: G. Wilkinson, F. G. A. Stone, E. W Abel), Pergamon Press, Oxford, England, 1982, vol. 6.
36. J. S. Valentine, Chem. Rev. 1973, 73, 235.
37. M. Laing, M. J. Nolte, E. Singleton, J. Chem. Soc., Chem. Commun. 1975, 660.
38. A. Nakamura, Y. Tatsuno, M. Yamamoto, S. Otsuka, J. Am. Chem. Soc. 1971, 93, 6052.
39. P. S. Pregosin, L. M. Venanzi, Chem. Ber. 1978, 14, 276.
40. C. Eaborn, N. Farrell, J. L. Murphy, A. Pidcock, J. Chem. Soc., Dalton Trans. 1976, 58.
41. T. H. Brown, P. J. Green, J. Am. Chem. Soc. 1970, 92, 2359.
42. C. A. Ghilardi, S. Midollini, S. Moneti, A. Orlandini, G. Scapacci, J. Chem. Soc., Dalton Trans. 1992, 3371.
43. T. E. Nappier, Jr., D. W. Meek, J. Am. Chem. Soc. 1972, 94, 306.
44. T. J. Mazanec, PhD Dissertation, The Ohio State University, Columbus, OH, Dec. 1978.
45. J. A. McGinnety, N. C. Payne, J. A. Ibers, J Am. Chem. Soc. 1969, 91, 6301.
46. C. Bianchini, A. Meli, M. Peruzzini, F. Vizza, J. Am. Chem. Soc. 1990, 112, 6726.
47. M. J. Nolte, E. Singleton, M. Laing, J Am. Chem. Soc. 1975, 97, 6396.
48. P. Barbaro, C. Bianchini, F. Laschi, S. Midollini, S. Moneti, G. Scapacci, P. Zanello, Inorg. Chem. 1994, 33, 1622.
49. S. Sakaki, K. Hori, A. Ohyoshi, Inorg. Chem. 1978, 17, 3183.
50. C. Yang, S. M. Socol, D. J. Kountz, D. W. Meek, R. Glaser, Inorg. Chim. Acta 1986, 114, 119.
51. T. Hayashi, T Mise, M. Fukushima, M. Kagotani, N. Nagashima, Y. Hamada, A. Matsumoto, S. Kawakami, M. Konishi, K. Yamamoto, M. Kumada, Bull. Chem. Soc. Jpn. 1980, 53, 1138.
52. G. Giordano, R. H. Crabtree, Inorg. Synth. 1990, 28, 88.
53. R. Cramer, Inorg. Synth. 1990, 28, 86.
54. A. McCleverty, G. Wilkinson, Inorg. Synth. 1990, 28, 84.
55. A. Van der Ent, A. L. Onderderlinden, Inorg. Synth. 1990, 28, 92.
56. M. F. Summers, L. G. Marzilli, A. Bax, J. Am. Chem. Soc. 1986, 108, 4285.
57. [44a] V. Sklener, H. Miyashiro, G. Zon, H. T. Miles, A. Bax, FEBS Lett. 1986, 208, 94.
58. [44b] J. Jeener, B. H. Meier, P. Bachqmann, R. R. Ernst, J. Chem. Phys. 1979, 71, 4546.