Aromaticity in All-Metal Rings

Atoms, Molecules, and Clusters Structure, Reactivity, and Dynamics: Aromaticity and Metal Clusters

Volumn , Issue , 2010, Pages 323-337

  Mercero, Jose M ^a,b   Infante, Ivan ^a,b   Ugalde, Jesus M ^a,b  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b DONOSTIA INTERNATIONAL PHYSICS CENTER DIPC   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 85137891709     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1201/EBK1439813348-21     Document Type: Chapter

References (46)

1. Boldyrev, A. I. and L.-S. Wang. All-metal aromaticity and antiaromaticity. Chem. Rev., 105:3716, 2005.
2. David, L. T. and R. Hoffmann. Delocalization in metallocycles. Nouv. J. Chim., 3:39, 1979.
3. Bleeke, J. R. Metallabenzenes. Chem. Rev., 101:1205, 2001.
4. Bleeke, J. R. Aromatic iridacycles. Acc. Chem. Res., 40:1035, 2007.
5. Wright, L. J. Metallabenzenes and metallabenzenoids. Dalton Trans., 1821, 2006.
6. Christopher, W. L. and M. M. Haley. Recent advances in metallabenzene chemistry. Angew. Chem. Int. Ed., 45:3914, 2006.
7. Fernández, I. and G. Frenking. Aromaticity in metallabenzenes. Chem. Eur. J., 13:5873, 2007.
8. 2): A structural and theoretical examination. Organometallics, 15:3798, 1996.
9. Robinson, G. H. Gallanes, gallenes, cyclogallenes and gallynes: Organometallic chemistry about the gallium-gallium bond. Acc. Chem. Res., 32:773, 1999.
10. Wang, Y. and G. H. Robinson. Organometallics of the group 13 M-M bond (M = Al, Ga, In) and the concept of metalloaromaticity. Organometallics, 26:2, 2007.
11. 3] (M = Li, Na, K) aromatic? J. Am. Chem. Soc., 118:10635, 1996.
12. Brown, I. D., D. B. Crump, and R. J. Gillespie. Crystal structure of tetrase-lenium bis(hydrogen disulfate). Inorg. Chem., 10:2319, 1971.
13. Gillespie, R. J. and J. Passmore. Polycations of group vi. Acc. Chem. Res., 4:413, 1971.
14. Gillespie, R. J. and G. P. Pez. Fluorosulfuric acid solvent system. vii. The behavior of some extremely weak bases in the superacid system fluorosulfuric acid-antimony pentafluoride- sulfur trioxide. Inorg. Chem., 8:1229, 1969.
15. (3-) anion. J. Am. Chem. Soc., 98:7234, 1976.
16. Cisar, A. and J. D. Corbett. Polybismuth anions. Synthesis and crystal structure of a salt of the tetrabismuthide(2-) ion, Bi42-. A basis for the interpretation of the structure of some complex intermetallic phases. Inorg. Chem., 16:2482, 1977.
17. 3-. Inorg. Chem., 23:770, 1984.
18. Tiznado, W., N. Perez-Peralta, R. Islas, A. Toro-Labbe, J. M. Ugalde, and G. Merino. Designing 3-D molecular starts. J. Am. Chem. Soc., 131:9426, 2009.
19. 5)]MoCp. J. Am. Chem. Soc., 104:4727-4729, 1982.
20. Scherer, O. J. Complexes with substituent-free acyclic and cyclic phosphorus, arsenic, antimony, and bismuth ligands. Angew. Chem. Int. Ed., 29:1104-1122, 1990.
21. Todorov, I. and S. C. Sevov. Heavy-metal aromatic rings: Cyclopentadienyl anion analogues Sn and Pb 565-6-in the Zintl phases Na8BaPb6, Na8BaSn6, and Na8EuSn6. Inorg. Chem., 43:6490, 1984.
22. Huang, X., H. J. Zhai, B. Kiran, and L. S. Wang. Observation of d-orbital aromaticity. Angew. Chem. Int. Ed., 44:7215, 2005.
23. Wannere, C. S., C. Corminboeuf, Z.-X. Wang, M. D. Wodrich, R. B. King, and P. v. R. Schleyer. Evidence of d orbital aromaticity in square planar coinage metal clusters. J. Am. Chem. Soc., 127:5701, 2005.
24. Zubarev, D. Yu., B. B. Averkiev, H.-J. Zhai, L.-S. Wang, and A. I. Boldyrev. Aromaticity and antiaromaticity in transition-metal systems. Phys. Chem. Chem. Phys., 10:257, 2008.
25. Chen, Z. and R. B. King. Spherical aromaticity: Recent work on fullerenes, polyhedral boranes, and related structures. Chem. Rev., 105:3613-3642, 2005.
26. Reiher, M. and A. Hirsch. Closed shell pseudo atoms. Spherical aromaticity. Chem. Eur. J., 9:5442, 2003.
27. Hanley, L., J. L. Whitten, and S. L. Anderson. Collision-induced dissociation and ab initio studies of boron cluster ions: Determination of structures and stabilities. J. Phys. Chem., 92:5803-5812, 1988. ibid: 94:2218, 1990.
28. Ricca, A. and C. W. Bauschlicher, Jr. The structure and stability of Bn clusters. Chem. Phys., 208:233, 1996.
29. Fowler, J. E. and J. M. Ugalde. The curiously stable B13 cluster and its neutral and anionic counterparts: The advantages on planarity. J. Phys. Chem. A., 104:397, 2000.
30. Boustani. I. A comparative study of ab initio SCF-CI and DFT. Example of small boron clusters. Chem. Phys. Lett., 233:273, 1995.
31. 13+ is highly aromatic. J. Phys. Chem. A, 105:5486-5489, 2001.
32. Alexandrova, A. N., A. I. Boldyrev, H.-J. Zhai, and L.-S. Wang. All-boron aromatic clusters as potential new inorganic ligands and building blocks in chemistry. Coord. Chem. Rev., 250:2811, 2006.
33. Bunker, P. R. and P. Jensen. Fundamentals of Molecular Symmetry. Series in Chemical Physics. Institute of Physics Publishing, Bristol, UK, 2005.
34. 2- structure. J. Am. Chem. Soc., 124:14795, 2002.
35. Li, X., A. E. Kuznetsov, H.-F. Zhang, A. I. Boldyrev, and L.-S. Wang. Observation of all-metal aromatic molecules. Science, 291:859, 2001.
36. Rao, B. K. and P. Jena. Evolution of the electronic structure and properties of neutral and charged aluminum clusters: A comprehensive analysis. J. Chem. Phys., 111:1890-1904, 1999.
37. Alonso, J. A. Structure and Properties of Atomic Nanoclusters. Imperial College Press, Singapore, 2005.
38. Tsipis, A. C. and C. A. Tsipis. Hydrometal analogues of aromatic hydrocarbons: A new class of cyclic hydrocoppers(I). J. Am. Chem. Soc., 125:1136-1137, 2003.
39. Tsipis, C. A., E. E. Karagiannis, P. F. Kladou, and A. C. Tsipis. Aromatic gold and silver ‘rings’: Hydrosilver(I) and hydrogold(I) analogues of aromatic hydrocarbons. J. Am. Chem. Soc., 126:12916-12929, 2004.
40. Jarvis, J. A. J., B. T. Kilbourn, R. Pearce, and M. F. Lappert. Crystal structure (at -40°) of tetrakis[trimethylsilylmethylcopper(i)], an alkyl bridged, square planar, tetranuclear copper(i) cluster. J. Chem. Soc., Chem Commun., 475-476, 1973.
41. Lin, Y.-C., D. Sundholm, J. Juselius, L.-F. Cui, X. Li, H.-J. Zhai, and L.-S. Wang. Experimental and computational studies of alkali-metal coinage-metal clusters. J. Phys. Chem. A., 110:4244-4250, 2006.
42. Chen, Z., C. S. Wannere, C. Corminboeuf, R. Puchta, and P. von Ragué Schleyer. NICS as an aromaticity criterion. Chem. Rev., 105:3842, 2005.
43. 3h, 1A1 ′ state. J. Phys. Chem. A., 111:12864, 2007.
44. Wang, H., Z. Hu, H. Haouari, R. Craig, Y. Liu, J. R. Lombardi, and D. M. Lindsay. Absorption, resonance raman, and raman excitation spectra of hafnium trimers. J. Chem. Phys., 106:8339, 1997.
45. Bauschlicher Jr. C. W. Clusters of hafnium, Hfn n = 2-8. Chem. Phys. Lett., 462:183-187, 2008.
46. Dolg, M. Effective Core Potentials, Vol. 1 of NIC Series. John Neumann Institute for Computing, Jiilich, Germany, 2000, 479-508.