Electronic structure and chemistry of the heaviest elements

Challenges and Advances in Computational Chemistry and Physics

Volumn 10, Issue , 2010, Pages 451-520

  Pershina, V ^a  

^a GSI HELMHOLTZZENTRUM FÜR SCHWERIONENFORSCHUNG GMBH   (Germany)

Author keywords

Chemical properties; Complex formation; Electronic structure; Heaviest elements; Relativistic effects; Volatility

Indexed keywords

EID: 85073148079     PISSN: 25424491     EISSN: 25424483     Source Type: Book Series    
DOI: 10.1007/978-1-4020-9975-5_11     Document Type: Chapter

References (221)

1. Schädel, M. (ed.).: The Chemistry of the Superheavy Elements. Dordrecht, The Netherlands/Boston, MA/London (2003)
2. Proceedings of “The Robert A. Welch Foundation Conference on Chemical Research XXXIV. Fifty Years with Transuranium Elements”, Houston, TX, 22–23 October 1990, pp. 255–276 (1990)
3. Greiner, W., Gupta, R.K. (eds.).: Heavy Elements and Related New Phenomena. World Scientific, Singapore (1999)
4. Wilson, S., Kaldor, U. (eds.).: Theoretical Chemistry and Physics of Heavy and Superheavy Elements, pp. 55–114. Kluwer, Dordrecht (2003)
5. Fricke, B.: Struct. Bond. 21, 89 (1975)
6. Schwerdtfeger, P., Seth, M.: Relativistic effects on the superheavy elements. In: Encyclopedia on Calculational Chemistry, vol. 4, pp. 2480–2499. Wiley, New York (1998)
7. Pershina, V.: The chemistry of the superheavy elements and relativistic effects. In: P. Schwerdtfeger (ed.) Relativistic Electronic Structure Theory, Part II, pp. 1–80. Elsevier, Amsterdam (2002)
8. Hoffman, D.C., Lee, D.M., Pershina, V.: Transactinide elements and future elements. In: L.R. Morss, N.M. Edelstein, J. Fuger (eds.) The Chemistry of the Actinide and Transactinide Elements, 3rd edn, Ch. 14, pp. 1652–1752. Springer, Dordrecht (2006)
9. Pershina, V., Kratz, J.V.: Experimental and theoretical studies of the chemistry of the heaviest elements. In: B.A. Hess (ed.) Relativistic Effects in Heavy-Element Chemistry and Physics, pp. 219–244. Wiley, New York (1997)
10. Pershina, V.: Chem. Rev. 96, 1977 (1996)
11. Barber, R.C., Greenwood, N.N., Hrynkiewicz, A.Z., Jeannin, Y.P., Lefort, M., Sakai, M., Ulehla, I., Wapstra, A.H., Wilkinson, D.H.: Prog. Part. Nucl. Phys. 29, 453 (1992)
12. Flerov, G.N., Ter-Akopian, G.M.: Rep. Prog. Phys. 46, 817 (1983)
13. Seaborg, G.T., Loveland, W.D.: The Elements Beyond Uranium. Wiley, New York (1990)
14. Münzenberg, G., Hofmann, S.: Discovery of the heaviest elements. In.: W. Greiner, R.K. Gupta (eds.) Heavy Elements and Related New Phenomena, pp. 9–42. World Scientific, Singapore (1999)
15. Hofmann, S., Münzenberg, G.: Rev. Mod. Phys. 72, 733 (2000)
16. Morita, K., Morimoto, K., Kaji, D., Akiyama, T., Goto, S., Haba, H., Ideguchi, E., Katori, K., Koura, H., Kikunaga, H., Kudo, H., Ohnishi, T., Ozawa, A., Sato, N., Suda, T., Sieki, K., Tokanai, F., Yamaguchi, T., Yoneda, A., Yoshida, A.: J. Phys. Soc. Jpn. 76, 045001 (2007)
17. Oganessian, Yu.: J. Phys. G: Nucl. Part. Phys. 34 R165 (2007)
18. Commission on nomenclature of inorganic chemistry. Pure & Appl. Chem. 69, 2471; www.iupac.org (1997)
19. Möller, P., Nix, J.R.: J. Phys. G., Nucl. Part. Phys. 20, 1681 (1994)
20. Myers, W.D., Swiatecki, W.J.: Nucl. Phys. A 601, 141 (1996); Liran, S., Marinov, V., Zeldes, N.: Phys.Rev.C63, 017302–1 (2000)
21. Heenen, P.H., Nazarewicz, W.: Europhys. News, Febr. 2002, p. 5; Bender, M., Nazarewicz, W., Reinhard, P.-G.: Phys. Lett. B 515, 42 (2001); Bender, M., Rutz, K., Reinhard, P.-G., Maruhn, J.A., Greiner, W.: Phys. Rev. C 60, 034304 (1999)
22. Kruppa, A.T., Bender, M., Nazarewicz, W., Reinhard, P.G., Vertse, T., Cwiok, S.: Phys. Rev. C 61, 034313–1 (2000); Cwiok, S., Dobaczewski, J., Heenen, P.H., Magierski, P., Nazarewicz, W.: Nucl. Phys. A 611, 211 (1996)
23. Adloff, J.P., Guillaumont, R.: Fundamentals of Radiochemistry, pp. 327–52. CRC Press, Boca Raton, FL (1993)
24. Hübener, S., Zvara, I.: Radiochim. Acta 31, 89 (1982)
25. Zvara, I., Eichler, B., Belov, V.Z., Zvarova, T.S., Korotkin, Yu.S., Shalaevsky, M.R., Shegolev, V.A., Hussonnois, M.: Sov. Radiochem. 16, 709 (1974)
26. Düllmann, Ch.E., Brüchle, W., Dressler, R., Eberhardt, K., Eichler, B., Eichler, R., Gäggeler, H.W., Ginter, T.N., Glaus, F., Gregorich, K., Hoffman, D.C., Jäger, E., Jost, D.T., Kirbach, U.W., Lee, D.E., Nitsche, H., Patin, J.B., Pershina, V., Piguet, D., Qin, Z., Schädel, M., Schausten, B., Schimpf, E., Schött, H.J., Soverna, S., Sudowe, R., Thörle, P., Timokhin, S.N., Trautmann, N., Türler, A., Vahle, A., Wirth, G., Yakushev, A.B., Zielinski, P.M.: Nature 418, 859 (2002)
27. Eichler, R., Aksenov, N.V., Belozerov, A.V., Bozhikov, G.A., Vhepigin, V.I., Dmitriev, S.N., Dressler, R., Gäggeler, H.W., Gorshkov, V.A., Haenssler, F., Itkis, M.G., Laube, A., Lebedev, V.Ya., Malyshev, O.N., Oganessian, Yu.Ts., Petrushkin, O.V., Piguet, D., Rasmussen, P., Shishkin, S.V., Shutov, S.V., Svirikhin, A.I., Tereshatov, E.E., Vostokin, G.K., Wegrzecki, M., Yeremin, A.V.: Nature Lett. 447, 72 (2007)
28. Kadkhodayan, B., Türler, A., Gregorich, K.E., Baisden, P.A., Czerwinski, K.R., Eichler, B., Gäggeler, H.W., Hamilton, T.M., Jost, D.T., Kacher, C.D., Kovacs, A., Kreek, S.A., Lane, M.R., Mohar, M.F., Neu, M.P., Stoyer, N.J., Sylwester, E.R., Lee, D.M., Nurmia, M.J., Seaborg, G.T., Hoffman, D.C.: Radiochim. Acta 72, 169 (1996)
29. Türler, A.: Radiochim. Acta 72, 7 (1996)
30. Schädel, M., Brüchle, W., Dressler, R., Eichler, B., Gäggeler, H.W., Günther, R., Gregorich, K.E., Hoffman, D.C., Hübener, S., Jost, D.T., Kratz, J.V., Paulus, W., Schumann, D., Timokhin, S., Trautmann, N., Türler, A., Wirth, G., Yakushev, A.B.: Nature (Lett.) 388, 55 (1997); Türler, A., Brüchle, W., Dressler, R., Eichler, B., Eichler, R., Gäggeler, H.W., Gärtner, M., Glatz, J.-P., Gregorich, K.E., Hübener, S., Jost, D.T., Lebedev, V.Ya., Pershina, V., Schädel, M., Taut, S., Timokhin, N., Trautmann, N., Vahle, A., Yakushev, A.B.: Angew. Chem. Int. Ed. Engl. 38, 2212 (1999)
31. Eichler, R., Brüchle, W., Dressler, R., Düllman, Ch.E., Eichler, B., Gäggeler, H.W., Gregorich, K.E., Hoffman, D.C., Hübener, S., Jost, D.T., Kirbach, U.W., Laue, C.A., Lavanchy, V.M., Nitsche, H., Patin, J.B., Piguet, D., Schädel, M., Shaughnessy, D.A., Strellis, D.A., Taut, S., Tobler, L., Tsyganov, Y.S., Türler, A., Vahle, A., Wilk, P.A., Yakushev, A.B.: Nature 407, 63 (2000)
32. Gäggeler, H.W., Türler, A.: Gas-phase chemistry. In: Ref. 1, pp. 237–290; Türler, A., Gregorich, K.E. (eds.).: Experimental techniques, ibid., pp. 117–158
33. Hoffman, D.C.: Chem. Eng. News May 24 (1994); Hoffman, D.C.: J. Chem. Ed. 76, 331 (1999)
34. Kratz, J.V.: Liquid-phase chemistry. In: Ref. 1, pp. 159–104
35. Kratz, J.: Chemistry of transactinides. In: S. Nagy, Z. Klencsar (eds.) Handbook of Nuclear Chemistry, pp. 323–396. Kluwer, Norwell, MA (2003)
36. Schädel, M.: Angew. Chem. Int. Ed. Engl. 45, 368 (2006)
37. Penneman, R.A., Mann, J.B., Jørgensen, C.K.: Chem. Phys. Lett. 8, 321 (1971)
38. Jørgensen, C.K.: Angew. Chem. Int. Ed. Engl. 12, 12 (1973)
39. Haissinski, M.: Radiochem. Radioanal. Lett. 8, 107 (1971)
40. Seaborg, G.T., Keller, O.L.: In: J.J. Katz, G.T. Seaborg, L.R. Morss (eds.) The Chemistry of the Actinides, 2nd edn., vol. 2, p. 1629. Chapman & Hall, New York (1986)
41. Bonchev, D., Kamenska, V.: J. Phys. Chem. 85, 1177 (1981)
42. Cotton, S.A.: Chem. Soc. Rev. 219 (1996)
43. Pershina, V.: Theoretical chemistry of the heaviest elements. In: Ref. 1, pp. 31–94
44. Pyykkö, P.: Chem. Rev. 88, 563 (1988)
45. Desclaux, J.P.: Atom. Data Nucl. Data 12, 311 (1973)
46. Pershina, V., Bastug, T.: Chem. Phys. 311, 139 (2005)
47. Eliav, E., Shmulyian, S., Kaldor, U., Ishikawa, Y.: J. Chem. Phys. 109, 3954 (1998)
48. Gaston, N., Schwerdtfeger, P., Nazarewicz, W.: Phys. Rev. A 66, 062505 (2002)
49. Lindgren, I.: Int. J. Quantum Chem. 57, 683 (1996)
50. Pyykkö, P., Tokman, M., Labzowsky, L.N.: Phys. Rev. A 57, R689 (1998)
51. Goidenko, I., Labsowsky, L., Eliav, E., Kaldor, U., Pyykkö, P.: Phys. Rev. A 67, 020102(R) (2003)
52. Schwerdfeger, P. (ed.).: Relativistic Electronic Structure Theory, Parts I and 2. Elsevier, Amsterdam (2002)
53. Kaldor, U., Eliav, E., Landau, A.: Accurate relativistic Fock-Space calculations for many-electron atoms. In: Ref. 52, vol. 2, pp. 81–119
54. Eliav, E., Kaldor, U., Ishikawa, Y.: Phys. Rev. Lett. 74, 1079 (1995)
55. Glebov, V.A., Kasztura, L., Nefedov, V.S., Zhuikov, B.L.: Radiochim. Acta 46, 117 (1989)
56. Johnson, E., Fricke, B., Keller, Jr. O.L., Nestor, Jr. C.W., Ticker, T.C.: J. Chem. Phys. 93, 8041 (1990)
57. Eliav, E., Landau, A., Ishikawa, Y., Kaldor, U.: J. Phys. B35, 1693 (2002)
58. DIRAC Package. Dirac, a relativistic ab initio electronic structure program, Release DIRAC04.0 (2004)”, written by Jensen, H.J.Aa., Saue, T., Visscher, L. with contributions from Bakken, V., Eliav, E., Enevoldsen, T., Fleig, T., Fossgaard, O., Helgaker, T., Laerdahl, J., Larsen, C.V., Norman, P., Olsen, J., Pernpointner, M., Pedersen, J.K., Ruud, K., Salek, P., van Stralen, J.N.P., Thyssen, J., Visser, O., Winther, T. (http://dirac.chem.sdu.dk) (2004)
59. Malli, G., Da Silva, A.B.F., Ishikawa, Y.: J. Chem. Phys. 101, 6829 (1994)
60. Visscher, L., Aerts, P.J.C., Visser, O., Nieuwpoort, W.C.: Int. J. Quantum Chem. 25, 131 (1991)
61. Faegri, K.: Theor. Chem. Acta 105, 252 (2001); Faegri, K., Dyall, K.G.: Basis sets for relativistic calculations. In: Ref. 52, pp. 259–290
62. de Macedo, L.G.M., Borin, A.C., da Silva, A.B.F.: Atom. Data Nucl. Data 93, 931 (2007)
63. Desclaux, J.P.: Comput. Phys. Commun. 9, 31 (1975)
64. Grant,I.P.:J.Phys.B19, 3187 (1986)
65. Fricke, B., Johnson, E., Rivera, G.M.: Radiochim. Acta 62, 17 (1993)
66. Johnson, E., Pershina, V., Fricke, B.: J. Phys. Chem. 103, 8458 (1999)
67. Johnson, E., Fricke, B., Jacob, T., Dong, C.Z., Fritzsche, S., Pershina, V.: J. Phys. Chem. 116, 1862 (2002)
68. Yu, Y.J., Li, J.G., Dong, C.Z., Ding, X.B., Fritsche, S., Fricke, B.: Eur. Phys. J. D 44, 51 (2007)
69. Yu, Y.J., Dong, C.Z., Li, J.G., Fricke, B.: J. Chem. Phys. 128 124316 (2008)
70. Balasubramanian, K.: Chem. Phys. Lett. 341, 601 (2001); ibid, 351, 161 (2002)
71. Fricke, B., Greiner, W., Waber, J.T.: Theor. Chim. Acta (Berlin) 21, 235 (1971)
72. Visscher, L.: Post-Dirac-Fock methods. In: Ref. 52, Part 1, pp. 291–331; Saue, T.: Post Dirack Fock-methods-properties, ibid., pp. 332–400
73. Wood, C.P., Pyper, N.C.: Chem. Phys. Lett. 84, 614 (1981)
74. Saue, T., Faegri, K., Gropen, O.: Chem. Phys. Lett. 263, 360 (1996)
75. Seth, M., Schwerdtfeger, P., Dolg, M., Faegri, K., Hess, B.A., Kaldor, U.: Chem. Phys. Lett. 250, 461 (1996); Seth, M., Schwerdtfeger, P.: Chem. Phys. Lett. 318, 314 (2000)
76. Faegri, K., Saue, T.: J. Chem. Phys. 115, 2456 (2001)
77. Seth, M., Faegri, K., Schwerdtfeger, P.: Angew. Chem. Int. Ed. Engl. 37, 2493 (1998); Schwerdtfeger, P., Seth, M.: J. Nucl. Radiochem. Sci. 3, 133 (2002)
78. Seth, M., Schwerdtfeger, P., Faegri, K.: J. Chem. Phys. 111, 6422 (1999)
79. Malli, G.L., Styszynski, J.: J. Chem. Phys. 109, 4448 (1998); Malli, G.: J. Chem. Phys. 116, 5476 (2002)
80. Malli, G.: J. Chem. Phys. 117, 10441 (2002)
81. Pyykkö, P., Desclaux, J.P.: Chem. Phys. Lett. 50, 503 (1977); Nature 226, 336 (1977); Chem. Phys. 34, 261 (1978)
82. Dolg, M.: Relativistic effective core potentials. In: Ref. 52, Part 1, pp. 793–862
83. Lee, Y.S.: Two-component relativistic effective core potential calculations for molecules. In: Ref. 52, Part 2, pp. 352–416
84. Seth, M.: The chemistry of superheavy elements. Thesis, University of Auckland (1998)
85. Seth, M., Dolg, M., Fulde, P., Schwerdtfeger, P.: J. Am. Chem. Soc. 17, 6597 (1995)
86. Seth, M., Schwerdtfeger, P., Dolg, M.: J. Chem. Phys. 106, 3623 (1997)
87. Seth, M., Cooke, F., Schwerdtfeger, P., Heully, J.L., Pelissier, M.: J. Chem. Phys. 109, 3935 (1998)
88. Han, Y.K., Son, S.K., Choi, Y.J., Lee, Y.S.: J. Phys. Chem. A 103, 9109 (1999)
89. Han, Y.K., Lee, Y.S.: J. Phys. Chem. A 103, 1104 (1999)
90. Han, Y.K., Bae, C., Lee, Y.S.: J. Chem. Phys. 110, 8986 (1999)
91. Han, Y.K., Bae, C., Son, S.K., Lee, Y.S.: J. Chem. Phys. 112, 2684 (2000)
92. Choi, Y.J., Han, Y.K., Lee, Y.S.: J. Chem. Phys. 115, 3448 (2001)
93. Nash, C.S., Bursten, B.E.: J. Phys. Chem. A103, 632 (1999)
94. Nash, C.S., Bursten, B.E.: 103, 402 (1999); Nash, C.S., Bursten, B.E.: Angew. Chem. Int. Ed. Engl. 38, 151 (1999)
95. Nash, C.S.: J. Phys. Chem. A 109, 3493 (2005)
96. Nash, C.S., Crockett, W.W.: J. Phys. Chem. A 110, 4619 (2006)
97. Balasubramanian, K.: Chem. Phys. Lett. 361, 397 (2002)
98. Nash, C.S., Bursten, B.E., Ermler, W.C.: J. Chem. Phys. 106, 5153 (1997)
99. Mosyagin, N.S., Petrov, A.N., Titov, A.V., Tupitsyn, I.I.: In: J.-P. Julien et al. (eds.) Recent Advances in the Theory of Chemical and Physical Systems, pp. 229–251. Springer, The Netherlands (2006)
100. Kohn, W., Becke, A.D., Parr, R.G.: J. Phys. Chem. 100, 12974 (1996)
101. Engel, E.: Relativistic density functional theory: Foundations and basic formalism. In: Ref. 52, Part 1, pp. 523–621
102. Rosen, A., Ellis, D.E.: J. Chem. Phys. 62, 3039 (1975); Rosen, A.: Adv. Quantum Chem. 29, 1 (1997)
103. Bastug, T., Sepp, W.D., Kolb, D., Fricke, B., te Velde, G., Baerends, E.J.: J. Phys. B 28, 2325 (1995)
104. Anton, J., Fricke, B., Engel, E.: Phys. Rev. A 69, 012505 (2004)
105. Becke, A.D.: Phys. Rev. A 38, 3098 (1988)
106. Perdew, J.P.: Phys. Rev. B 33, 1822 (1986); ibid 34, 7406 (1986)
107. Jacob, T., Geschke, D., Fritzsche, S., Sepp, W.D., Fricke, B., Anton, J., Varga, S.: Surf. Sci. 486, 194 (2001)
108. van Wüllen, C.: Relativistic density functional calculations on small molecules. In: Ref. 52, Part 2, pp. 598–655
109. Liu, W., Hong, G., Dai, D., Li, L., Dolg, M.: Theor. Chem. Acc. 96, 75 (1997)
110. Liu, W., van Wüllen, Ch.: J. Chem. Phys. 110, 3730 (1999)
111. Liu, W., van Wüllen, W.Ch., Han, Y.K., Choi, Y.J., Lee, Y.S.: Adv. Quantum Chem. 39, 325 (2001)
112. Mayer, M., Krüger, S., Rösch, N.: J. Chem. Phys. 115, 4411 (2001)
113. van Lenthe, E., Ehlers, A., Baerends, E.J.: J. Chem. Phys. 110, 8943 (1999); te Velde, G., Baerends, E.J.: J. Comput. Phys. 99, 84 (1992)
114. Hess, B.A.: Phys. Rev. A 33, 3742 (1986)
115. Eliav, E., Kaldor, U., Ishikawa, Y.: Phys. Rev. A 52, 291 (1995)
116. Desclaux, J.P., Fricke, B.: J. Phys. 41, 943 (1980)
117. Umemoto, K., Saito, S.: J. Phys. Soc. Jpn. 65, 3175 (1996)
118. Pyper, N.C., Grant, I.P.: Proc. R. Soc. Lond., Ser A 376, 483 (1981)
119. Eliav, E., Kaldor, U., Schwerdtfeger, P., Hess, B.A., Ishikawa, Y.: Phys. Rev. Lett. 73, 3203 (1994)
120. Eliav, E., Kaldor, U., Ishikawa, Y.: Phys. Rev. A 52, 2765 (1995)
121. Eliav, E., Kaldor, U., Ishikawa, Y., Seth, M., Pyykkö, P.: Phys. Rev. A 53, 3926 (1996)
122. Landau, A., Eliav, E., Ishikawa, Y., Kaldor, U.: J. Chem. Phys. 114, 2977 (2001)
123. Eliav, E., Kaldor, U., Ishikawa, Y.: Mol. Phys. 94, 181 (1998)
124. Moore, C.E.: Atomic Energy Levels. Natl. Stand. Ref. Data Ser., Natl. Bur. Stand., Washington, DC (1971)
125. Eliav, E., Kaldor, U., Ishikawa, Y., Pyykkö, P.: Phys. Rev. Lett. 77, 5350 (1996)
126. Pershina, V., Borschevsky, A., Eliav, E., Kaldor, U.: J. Chem. Phys. 129, 144106 (1–9) (2008)
127. Lim, I., Pernpointer, M., Seth, M., Schwerdtfeger, P.: Phys. Rev. A 60, 2822 (1999); Lim, I.S., Schwerdtfeger, P., Metz, B., Stoll, H.: J. Chem. Phys. 122, 194103 (2005)
128. Landau, A., Eliav, E., Ishikava, Y., Kaldor, U.: J. Chem. Phys. 115, 2389 (2001)
129. Thierfeld, C., Schwerdtfeger, P., Hessberger, F.P., Hofmann, S.: Eur. Phys. J. A 36, 227 (2008)
130. Shannon, R.D.: Acta Crystallogr., Sect. A 32, 751 (1976)
131. Pyykkö, P., Atsumi, M.: Chem. Eur. J. 15, 186 (2009)
132. Pyykkö, P., Riedel, S., Patzsche, M.: Chem. Eur. J. 11, 3511 (2005)
133. Fricke, B., Waber, J.T.: J. Chem. Phys. 56, 3246 (1972)
134. Pershina, V., Borschevsky, A., Eliav, E., Kaldor, U.: J. Chem. Phys. 128, 024707 (2008)
135. Pershina, V., Borschevsky, A., Eliav, E., Kaldor, U.: J. Phys. Chem. A 112, 13712 (2008)
136. Borschevsky, A., Pershina, V., Eliav, E., Kaldor, U.: Chem. Phys. Lett. 480, 49 (2009)
137. CRC Handbook of Chemistry and Physics, 86th edn., by D.R. Lide (ed.). CRC Press, Boca Raton, FL (2005); Goeben, D., Hohm, U.: J. Phys. Chem. 100, 7710 (1996)
138. Pershina, V., Fricke, B.: J. Chem. Phys. 99, 9720 (1993)
139. Pershina, V., Fricke, B.: Electronic structure and chemistry of the heaviest elements. In: Ref. 3, pp. 194–262
140. Pershina, V., Fricke, B.: J. Phys. Chem. 99, 144 (1995); Pershina, V., Fricke, B.: ibid. 100, 8748 (1996)
141. Nash, C.S., Bursten, B.E.: New J. Chem. 19, 669 (1995)
142. Varga, S., Fricke, B., Hirata, M., Bastug, T., Pershina, V., Fritzsche, S.: J. Phys. Chem. 104, 6495 (2000)
143. Pershina, V., Bastug, T.: J. Chem. Phys. 113, 1441 (2000)
144. Pershina, V., Bastug, T., Fricke, B., Varga, S.: J. Chem. Phys. 115, 1 (2001)
145. Pershina, V., Bastug, T., Fricke, B.: J. Chem. Phys. 122, 124301 (2005)
146. Pershina, V., Anton, J., Jacob, T.: Phys. Rev. A 78, 032518 (2008)
147. Burroughs, P., Evans, S., Hamnett, A., Orchard, A.F., Richardson, N.V.: J. Chem. Soc., Faraday Trans. 2 70, 1895 (1974)
148. Krebs, B., Hasse, K.D.: Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 32, 1334 (1976); Müller, A., Krebs, B.: J. Mol. Spectrosc. 24, 180 (1967)
149. Filatov, M., Cremer, D.: J. Chem. Phys. 119, 1412 (2003)
150. Seto, J.Y., Morbi, Z., Charron, F., Lee, S.K., Bernath, P.F., Le Roy, P.J.: J. Chem. Phys. 110, 11756 (1999)
151. Dolg, M., Stoll, H., Seth, M., Schwerdtfeger, P.: Chem. Phys. Lett. 345, 490 (2001)
152. Han, Y.K., Hirao, K.: Chem. Phys. Lett. 328, 453 (2000)
153. Anton, J., Fricke, B., Schwerdtfeger, P.: Chem. Phys. 311, 97 (2005)
154. Pitzer, K.S.: J. Chem. Phys. 63, 1032 (1975)
155. Eichler, B.: Kernenergie 10, 307 (1976)
156. Liu, W., Dolg, M., Schwerdtfeger, P.: unpublished
157. Pyykkö, P.: Chem. Rev. 97, 597 (1997)
158. Zee, R.D., Blankespoor, S.C., Zweier, T.S.: J. Chem. Phys. 88, 4650 (1988)
159. Huber, K.P., Herzberg, G.: Constants of Diatomic Molecules. Reinhold, New York (1979)
160. Schwerdtfeger, P., Li, J., Pyykkö, P.: Theor. Chim. Acta 87, 313 (1994); Dolg, M., Flad, H.J.: J. Phys. Chem. 100, 6147 (1996)
161. Gaston, N., Opahle, I., Gäggeler, H.W., Schwerdtfeger, P.: Angew. Chem. Int. Ed. Engl. 46, 1663 (2007)
162. Soverna, S.: Doctoral Thesis, Universität Bern (2004); Soverna, S., Dressler, R., Düllmann, C.E., Eichler, B., Eichler, R., Gäggeler, H.W., Haenssler, F., Niklaus, J.P., Piguet, D., Qin, Z., Türler, A., Yakushev, A.: Radiochim. Acta 93, 1 (2005)
163. Pershina, V., Bastug, T., Fricke, B., Jacob, T., Varga, S.: Chem. Phys. Lett. 365, 176 (2002)
164. Sarpe-Tudoran, C., Pershina, V., Fricke, B., Anton, J., Sepp, W.D., Jacob, T.: Eur. Phys. J. D 24, 65 (2003); Pershina, V., Bastug, T., Sarpe-Tudoran, C., Anton, J., Fricke, B.: Nucl. Phys. A 734, 200 (2004)
165. Sarpe-Tudoran, C., Fricke, B., Anton, J., Pershina, V.: J. Chem. Phys. 126, 174702 (2007)
166. Niklaus, J.P., Eichler, R., Soverna, S., Gäggeler, H.W., Tobler, L.: PSI Annual Report, p. 8. (2000)
167. Boisvert, G., Lewis, L.J., Puska, M.J., Nieminen, R.M.: Phys. Rev. B 52, 9078 (1995)
168. Pershina, V., Anton, J., Jacob, T.: J. Chem. Phys. 131, 084713 (2009)
169. Yakushev, A.B., Buklanov, G.V., Chelnokov, M.L., Chepigin, V.I., Dmitriev, S.N., Gorshkov, V.A., Hübener, S., Lebedev, Y.Ya., Malyshev, O.N., Popeko, A.G., Sokol, E.A., Timokhin, S.N., Türler, A., Vasko, V.M., Yeremin, A.V., Zvara, I.: Radiochim. Acta 89, 743 (2001)
170. Eichler, R., Aksenov, N.V., Belozerov, A.V., Bozhikov, G.A., Chepigin, V.I., Dmitriev, S.N., Dressler, R., Gäggeler, H.W., Gorshkov, A.V., Itkis, M.G., Haenssler, F., Laube, A., Lebedev, V.Ya., Malyshev, O.N., Oganessian, Y.Ts., Petrushkin, O.V., Piguet, D., Popeko, A.G., Rasmussen, P., Shishkin, S.V., Serov, A.A., Shutov, A.V., Svirikhin, A.I., Tereshatov, E.E., Vostokin, G.K., Wegrzecki, M., Yeremin, A.V.: Angew. Chem. Int. Ed. Engl. 47(17), 3262 (2008)
171. Rykova, E.A., Zeitsevskii, A., Mosyagin, N.S., Isaev, T.A., Titov, A.V.: J. Chem. Phys. 125, 241102 (2006); Zaitsevskii, A., Rykova, E.A., Mosyagin, N.S., Titov, A.V.: Cent. Eur. J. Phys. 4, 448 (2006)
172. Mosyagin, N.S., Isaev, T.A., Titov, A.V.: J. Chem. Phys. 124, 224302 (2006)
173. Nakajima, T., Hirao, K.: Chem. Phys. Lett. 329, 511 (2000)
174. Kaupp, M., von Schering, H.G.: Angew. Chem. Int. Ed. Engl. 32, 861 (1993); Kaupp, M., Dolg, M., Stoll, H., von Schnering, H.G.: Inorg. Chem. 33, 2122 (1994)
175. König, S., Gäggeler, H.W., Eichler, R., Haenssler, F., Soverna, S., Dressler, R., Friedrich, S., Piguet, D., Tobler, L.: PSI Annual Report (http://lch.web.psi.ch/pdf/anrep05/03.pdf) (2005)
176. Liu, W., van Wüllen, C., Wang, F., Li, L.: J. Chem. Phys. 116, 3626 (2002)
177. Wood, C.P., Pyper, N.C.: Chem. Phys. Lett. 84, 614 (1981)
178. Schwerdtfeger, P.: J. Phys. Chem. 100, 2968 (1996)
179. Keller, Jr. O.L., Burmett, J.L., Carlson, T.A., Nestor, Jr. C.W.: J. Phys. Chem. 74, 1127 (1970)
180. Thierfelder, C., Assadollahzadeh, B., Schwerdtfeger, P., Schäfer, S., Schäfer, R.: Phys. Rev. A 78, 052506 (2008)
181. Pershina, V., Anton, J., Fricke, B.: J. Chem. Phys. 127, 134310 (2007)
182. Pitzer, K.S., Balasubramanian, K.: J. Phys. Chem. 86, 3068 (1982)
183. Heaven, M.C., Miller, T.A., Bondybey, V.E.: J. Phys. Chem. 87, 2071 (1983)
184. Haenssler, F., Eichler, R., Gäggeler, H.W., Soverna, S., Dressler, R., Piguet, D., Schippering, M.: PSI Annal Report, p. 3 (2004); Eichler, R.: Private communication
185. Houdart, R., Schamps, J.: J. Phys. B 6, 2478 (1873)
186. Rossbach, H., Eichler, B.: Akademie der Wissenschaft der DDR, Report No. ZFK-527 (1984)
187. Balasubramanian, K.: J. Chem. Phys. 117, 7426 (2002)
188. Grant, I.P., Pyper, N.C.: Nature 265, 715 (1977)
189. Keller, Jr. O.L., Nestor, Jr. C.W., Fricke, B.: J. Phys. Chem. 78, 1945 (1974)
190. Visscher, L., Dyall, K.G.: J. Chem. Phys. 104, 9040 (1996)
191. Malli, G.L.: In: Relativistic and Electron Correlation Effects in Molecules and Solids, NATO ASI Series, vol. 318. Plenum, New York (1994)
192. Eichler, B.: Private communication
193. Graham, A.P., Toennies, J.P.: J. Chem. Phys. 118, 2879 (2003)
194. Nash, C.S., Bursten, B.E.: Angew. Chem. Int. Ed. Engl. 38, 151 (1999)
195. Malli, G.L.: J. Chem. Phys. 124, 071102 (2006); Malli, G.: Theor. Chem. Acc. 118, 473 (2007)
196. Seaborg, G.T.: J. Chem. Soc., Dalton Trans. 760 (1996)
197. Pershina, V., Sepp, W.D., Bastug, T., Fricke, B., Ionova, G.V.: J. Chem. Phys. 97, 1123 (1992)
198. Ionova, G.V., Pershina, V., Johnson, E., Fricke, B., Schädel, M.: J. Phys. Chem. 96, 11096 (1992)
199. Pershina, V., Fricke, B.: J. Phys. Chem.98, 6468 (1994)
200. Pershina, V., Johnson, E., Fricke, B.: J. Phys. Chem. A 103, 8463 (1999)
201. Bratsch, S.G.: J. Phys. Chem. Ref. Data 18, 1 (1989)
202. Czerwinski, K.R.: Studies of fundamental properties of Rutherfordium (Element 104) using organic complexing agents. Doctoral Thesis, LBL Berkeley, CA (1992)
203. Strub, E., Kratz, J.V., Kronenberg, A., Nähler, A., Thörle, P., Zauner, S., Brüchle, W., Jäger, E., Schädel, M., Schausten, B., Schimpf, E., Zongwei, L., Kirbach, U., Schumann, D., Jost, D., Türler, A., Asai, M., Nagame, Y., Sakara, M., Tsukada, K., Gäggeler, H.W., Glanz, J.P.: Radiochim. Acta 88, 265 (2000)
204. Ishii, A., Toyoshima, A., Tsukada, K., Asai, M., Toume, H., Nishinaka, I., Nagame, Y., Miyashita, S., Mori, T., Suganuma, H., Haba, H., Sakamaki, M., Goto, M.S., Kudo, H., Akiyama, K., Oura, Y., Nakahara, H., Tashiro, Y., Shinohara, A., Schädel, M., Brüchle, W., Pershina, V., Kratz, J.V.: Chem. Lett. 37, 288 (2008)
205. Trubert, D., Le Naour, C., Hussonois, M., Brillard, L., Montroy Gutman, F., Le Du, J.F., Constantinescu, O., Barci, V., Weiss, B., Gasparro, J., Ardisson, G.: In: Abstracts of the 1st International Conference on Chemistry and Physics of the Transactinides, Seeheim, September 26–30 (1999)
206. Haba, H., Tsukada, K., Asai, M., Goto, S., Toyoshima, A., Nishinaka, I., Akiyama, K., Hirata, M., Ichikawa, S., Nagame, Y., Shoji, Y., Shigekawa, M., Koike, T., Iwasaki, M., Shinohara, A., Kaneko, T., Matuyama, T., Ono, S., Kudo, H., Qura, Y., Sueki, K., Nakahara, H., Sakama, M., Yokoyama, A., Kratz, J.V., Schädel, M., Brüchle, W.: J. Nucl. Radiochem. Sci. 3, 143 (2002)
207. Omtwedt, J.P., Polyakova, D., Alstad, J., Bjornstad, T., Düllmann, C.E., Folden, C.M. III, Garcia, M.A., Gates, J., Gregorich, K.E., Hoffman, D.C., Nelson, S.L., Nitsche, H., Omtwedt, L., Pershina, V., Samadani, F., Skarnemark, G., Stavsetra, L., Sudove, R., Wilson, R.E., Zheng, L., Zielinski, P.M.: Radiochim. Acta (to be submitted)
208. Baes, Jr. C.F., Mesmer, R.E.: The Hydrolysis of Cations. Wiley, New York (1976)
209. Paulus, W., Kratz, J.V., Strub, E., Zauner, S., Brüchle, W., Pershina, V., Schädel, M., Schausten, B., Adams, J.L., Gregorich, K.E., Hoffman, D.C., Caption Lane, M.R., Laue, C., Lee, D.M., McGrath, C.A., Shaughnessy, D.K., Strellis, D.A., Sylwester, E.R.: Radiochim. Acta 84, 69 (1999)
210. Schädel, M., Brüchle, W., Jäger, E., Schausten, B., Wirth, G., Paulus, W., Günther, R., Eberhardt, K., Kratz, J.V., Seibert, A., Strub, E., Thörle, P., Trautmann, N., Waldek, W., Zauner, S., Schumann, D., Kirbach, U., Kubica, B., Misiak, R., Nagame, Y., Gregorich, K.E.: Radiochim. Acta 83, 163 (1998)
211. von Zweidorf, A., Angert, R., Brüchle, W., Bürger, S., Eberhartdt, K., Eichler, R., Hummrich, H., Jäger, E., Kling, H.O., Kratz, J.V., Kuczewski, B., Langrock, G., Mendel, M., Rieth, U., Schädel, M., Schausten, B., Schimpf, E., Thörle, P., Trautmann, N., Tsukada, K., Wiehl, N., Wirth, G.: Radiochim. Acta 92, 855 (2004)
212. Pershina, V., Trubert, D., Le Naour, C., Kratz, J.V.: Radiochim. Acta90, 869 (2002)
213. Pershina, V., Polakova, D., Omtvedt, J.P.: Radiochim. Acta 94, 407 (2006)
214. Pershina, V.: Radiochim. Acta 80, 65 (1998)
215. Pershina, V.: Radiochim. Acta 80, 75 (1998)
216. Pershina, V., Bastug, T.: Radiochim. Acta 84, 79 (1999)
217. Pershina, V., Kratz, J.V.: Inorg. Chem.40, 776 (2001)
218. Pershina, V.: Radiochim. Acta 92, 455 (2004)
219. Pershina, V.: Radiochim. Acta 93, 373 (2005)
220. Kassiakoff, A., Harker, D.: J. Am. Chem. Soc. 60, 2047 (1938)
221. Kronenberg, A., Mohapatra, P.K., Kratz, J.V., Pfrepper, G., Pfrepper, R.: Radiochim. Acta 92, 395 (2004)