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Volumn 9, Issue 1, 2018, Pages

Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; CARBON; GOLD; NITROGEN; PALLADIUM NANOPARTICLE; PHOSPHATE; PLATINUM;

EID: 85047228754     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/s41467-018-04213-9     Document Type: Article
Times cited : (692)

References (49)
  • 1
    • 84865120266 scopus 로고    scopus 로고
    • Opportunities and challenges for a sustainable energy future
    • Chu, S. & Majumdar, A. Opportunities and challenges for a sustainable energy future. Nature 488, 294-303 (2012).
    • (2012) Nature , vol.488 , pp. 294-303
    • Chu, S.1    Majumdar, A.2
  • 4
    • 38349190507 scopus 로고    scopus 로고
    • An Earth-system perspective of the global nitrogen cycle
    • Gruber, N. & Galloway, J. N. An Earth-system perspective of the global nitrogen cycle. Nature 451, 293-296 (2008).
    • (2008) Nature , vol.451 , pp. 293-296
    • Gruber, N.1    Galloway, J.N.2
  • 7
    • 84867872922 scopus 로고    scopus 로고
    • Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store
    • Kitano, M. et al. Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store. Nat. Chem. 4, 934-940 (2012).
    • (2012) Nat. Chem. , vol.4 , pp. 934-940
    • Kitano, M.1
  • 8
    • 84905897969 scopus 로고    scopus 로고
    • New recipe produces ammonia from air, water, and sunlight
    • Service, R. F. New recipe produces ammonia from air, water, and sunlight. Science 345, 610 (2014).
    • (2014) Science , vol.345 , pp. 610
    • Service, R.F.1
  • 9
    • 84904016262 scopus 로고    scopus 로고
    • Challenges in reduction of dinitrogen by proton and electron transfer
    • van der Ham, C. J. M., Koper, M. T. M. & Hetterscheid, D. G. H. Challenges in reduction of dinitrogen by proton and electron transfer. Chem. Soc. Rev. 43, 5183-5191 (2014).
    • (2014) Chem. Soc. Rev. , vol.43 , pp. 5183-5191
    • Van Der Ham, C.J.M.1    Koper, M.T.M.2    Hetterscheid, D.G.H.3
  • 10
    • 84964680270 scopus 로고    scopus 로고
    • Nanostructured photoelectrochemical solar cell for nitrogen reduction using plasmon-enhanced black silicon
    • Ali, M. et al. Nanostructured photoelectrochemical solar cell for nitrogen reduction using plasmon-enhanced black silicon. Nat. Commun. 7, 11335 (2016).
    • (2016) Nat. Commun. , vol.7 , pp. 11335
    • Ali, M.1
  • 11
    • 84964765886 scopus 로고    scopus 로고
    • Light-driven dinitrogen reduction catalyzed by a CdS: Nitrogenase MoFe protein biohybrid
    • Brown, K. A. et al. Light-driven dinitrogen reduction catalyzed by a CdS: nitrogenase MoFe protein biohybrid. Science 352, 448-450 (2016).
    • (2016) Science , vol.352 , pp. 448-450
    • Brown, K.A.1
  • 13
    • 84959497946 scopus 로고    scopus 로고
    • Electrochemical synthesis of ammonia: A low pressure, low temperature approach
    • Renner, J. N., Greenlee, L. F., Ayres, K. E. & Herring, A. M. Electrochemical synthesis of ammonia: A low pressure, low temperature approach. Electrochem. Soc. Interface 24, 51-57 (2015).
    • (2015) Electrochem. Soc. Interface , vol.24 , pp. 51-57
    • Renner, J.N.1    Greenlee, L.F.2    Ayres, K.E.3    Herring, A.M.4
  • 15
    • 84973541550 scopus 로고    scopus 로고
    • Recent progress towards the electrosynthesis of ammonia from sustainable resources
    • Shipman, M. A. & Symes, M. D. Recent progress towards the electrosynthesis of ammonia from sustainable resources. Catal. Today 286, 57-68 (2017).
    • (2017) Catal. Today , vol.286 , pp. 57-68
    • Shipman, M.A.1    Symes, M.D.2
  • 16
    • 50949083435 scopus 로고    scopus 로고
    • Using ammonia as a sustainable fuel
    • Zamfirescu, C. & Dincer, I. Using ammonia as a sustainable fuel. J. Power Sources 185, 459-465 (2008).
    • (2008) J. Power Sources , vol.185 , pp. 459-465
    • Zamfirescu, C.1    Dincer, I.2
  • 17
    • 47149108737 scopus 로고    scopus 로고
    • Ammonia for hydrogen storage: Challenges and opportunities
    • Klerke, A., Christensen, C. H., Nørskov, J. K. & Vegge, T. Ammonia for hydrogen storage: challenges and opportunities. J. Mater. Chem. 18, 2304-2310 (2008).
    • (2008) J. Mater. Chem. , vol.18 , pp. 2304-2310
    • Klerke, A.1    Christensen, C.H.2    Nørskov, J.K.3    Vegge, T.4
  • 19
    • 84905907953 scopus 로고    scopus 로고
    • Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3
    • Licht, S. et al. Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3. Science 345, 637-640 (2014).
    • (2014) Science , vol.345 , pp. 637-640
    • Licht, S.1
  • 20
    • 85000703006 scopus 로고    scopus 로고
    • Electrochemical reduction of N2 under ambient conditions for artificial N2 fixation and renewable energy storage using N2/NH3 Cycle
    • Bao, D. et al. Electrochemical reduction of N2 under ambient conditions for artificial N2 fixation and renewable energy storage using N2/NH3 Cycle. Adv. Mater. 29, 1604799 (2017).
    • (2017) Adv. Mater. , vol.29 , pp. 1604799
    • Bao, D.1
  • 21
    • 85013909389 scopus 로고    scopus 로고
    • Au sub-nanoclusters on TiO2 toward highly efficient and selective electrocatalyst for N2 conversion to NH3 at ambient conditions
    • Shi, M. M. et al. Au sub-nanoclusters on TiO2 toward highly efficient and selective electrocatalyst for N2 conversion to NH3 at ambient conditions. Adv. Mater. 29, 1606550 (2017).
    • (2017) Adv. Mater. , vol.29 , pp. 1606550
    • Shi, M.M.1
  • 22
    • 85021806480 scopus 로고    scopus 로고
    • Amorphizing of Au nanoparticles by CeOx-RGO hybrid support towards highly efficient electrocatalyst for N2 reduction under ambient conditions
    • Li, S. J. et al. Amorphizing of Au nanoparticles by CeOx-RGO hybrid support towards highly efficient electrocatalyst for N2 reduction under ambient conditions. Adv. Mater. 29, 1700001 (2017).
    • (2017) Adv. Mater. , vol.29 , pp. 1700001
    • Li, S.J.1
  • 23
    • 85017459857 scopus 로고    scopus 로고
    • Reversible nitrogen fixation based on a rechargeable lithium-nitrogen battery for energy storage
    • Ma, J. L., Bao, D., Shi, M. M., Yan, J. M. & Zhang, X. B. Reversible nitrogen fixation based on a rechargeable lithium-nitrogen battery for energy storage. Chem 2, 525-532 (2017).
    • (2017) Chem , vol.2 , pp. 525-532
    • Ma, J.L.1    Bao, D.2    Shi, M.M.3    Yan, J.M.4    Zhang, X.B.5
  • 24
    • 85024871752 scopus 로고    scopus 로고
    • Ammonia synthesis from N2 and H2O using a lithium cycling electrification strategy at atmospheric pressure
    • McEnaney, J. M. et al. Ammonia synthesis from N2 and H2O using a lithium cycling electrification strategy at atmospheric pressure. Energy Environ. Sci. 10, 1621-1630 (2017).
    • (2017) Energy Environ. Sci. , vol.10 , pp. 1621-1630
    • McEnaney, J.M.1
  • 25
    • 85026312662 scopus 로고    scopus 로고
    • Ammonia electrosynthesis with high selectivity under ambient conditions via a Li+ incorporation strategy
    • Chen, G. F. et al. Ammonia electrosynthesis with high selectivity under ambient conditions via a Li+ incorporation strategy. J. Am. Chem. Soc. 139, 9771-9774 (2017).
    • (2017) J. Am. Chem. Soc. , vol.139 , pp. 9771-9774
    • Chen, G.F.1
  • 26
    • 0034618509 scopus 로고    scopus 로고
    • Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell
    • Kordali, V., Kyriacou, G. & Lambrou, C. Electrochemical synthesis of ammonia at atmospheric pressure and low temperature in a solid polymer electrolyte cell. Chem. Commun. (https://doi. org/10. 1039/B004885M (2000).
    • (2000) Chem. Commun.
    • Kordali, V.1    Kyriacou, G.2    Lambrou, C.3
  • 27
    • 84886723139 scopus 로고    scopus 로고
    • Review of electrochemical ammonia production technologies and materials
    • Giddey, S., Badwal, S. P. S. & Kulkarni, A. Review of electrochemical ammonia production technologies and materials. Int. J. Hydrog. Energy 38, 14576-14594 (2013).
    • (2013) Int. J. Hydrog. Energy , vol.38 , pp. 14576-14594
    • Giddey, S.1    Badwal, S.P.S.2    Kulkarni, A.3
  • 28
    • 84879903862 scopus 로고    scopus 로고
    • Synthesis of ammonia directly from air and water at ambient temperature and pressure
    • Lan, R., Irvine, J. T. S. & Tao, S. Synthesis of ammonia directly from air and water at ambient temperature and pressure. Sci. Rep. 3, 1145 (2013).
    • (2013) Sci. Rep. , vol.3 , pp. 1145
    • Lan, R.1    Irvine, J.T.S.2    Tao, S.3
  • 29
    • 84964677918 scopus 로고    scopus 로고
    • Electrochemical reduction of nitrogen to ammonia in 2-propanol under ambient temperature and pressure
    • Kim, K. et al. Electrochemical reduction of nitrogen to ammonia in 2-propanol under ambient temperature and pressure. J. Electrochem. Soc. 163, F610-F612 (2016).
    • (2016) J. Electrochem. Soc. , vol.163 , pp. F610-F612
    • Kim, K.1
  • 30
    • 85011411858 scopus 로고    scopus 로고
    • Electrocatalytic synthesis of ammonia at room temperature and atmospheric pressure from water and nitrogen on a carbon-nanotube-based electrocatalyst
    • Chen, S. et al. Electrocatalytic synthesis of ammonia at room temperature and atmospheric pressure from water and nitrogen on a carbon-nanotube-based electrocatalyst. Angew. Chem. Int. Ed. 56, 2699-2703 (2017).
    • (2017) Angew. Chem. Int. Ed. , vol.56 , pp. 2699-2703
    • Chen, S.1
  • 31
    • 85040731325 scopus 로고    scopus 로고
    • Electrochemical nitrogen reduction reaction on noble metal catalysts in proton and hydroxide exchange membrane electrolyzers
    • Nash, J. et al. Electrochemical nitrogen reduction reaction on noble metal catalysts in proton and hydroxide exchange membrane electrolyzers. J. Electrochem. Soc. 164, F1712-F1716 (2017).
    • (2017) J. Electrochem. Soc. , vol.164 , pp. F1712-F1716
    • Nash, J.1
  • 32
    • 84936867394 scopus 로고    scopus 로고
    • The challenge of electrochemical ammonia synthesis: A new perspective on the role of nitrogen scaling relations
    • Montoya, J. H., Tsai, C., Vojvodic, A. & Nørskov, J. K. The challenge of electrochemical ammonia synthesis: A new perspective on the role of nitrogen scaling relations. ChemSusChem 8, 2180-2186 (2015).
    • (2015) ChemSusChem , vol.8 , pp. 2180-2186
    • Montoya, J.H.1    Tsai, C.2    Vojvodic, A.3    Nørskov, J.K.4
  • 33
    • 85019745142 scopus 로고    scopus 로고
    • Electrochemical ammonia synthesis-the selectivity challenge
    • Singh, A. R. et al. Electrochemical ammonia synthesis-the selectivity challenge. ACS Catal. 7, 706-709 (2017).
    • (2017) ACS Catal. , vol.7 , pp. 706-709
    • Singh, A.R.1
  • 34
    • 84883201244 scopus 로고    scopus 로고
    • Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction
    • Zhu, D., Zhang, L., Ruther, R. E. & Hamers, R. J. Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction. Nat. Mater. 12, 836-841 (2013).
    • (2013) Nat. Mater. , vol.12 , pp. 836-841
    • Zhu, D.1    Zhang, L.2    Ruther, R.E.3    Hamers, R.J.4
  • 35
    • 36749017436 scopus 로고    scopus 로고
    • Dinitrogen cleavage by a diniobium tetrahydride complex: Formation of a nitride and its conversion into imide species
    • Akagi, F., Matsuo, T. & Kawaguchi, H. Dinitrogen cleavage by a diniobium tetrahydride complex: formation of a nitride and its conversion into imide species. Angew. Chem. Int. Ed. 46, 8778-8781 (2007).
    • (2007) Angew. Chem. Int. Ed. , vol.46 , pp. 8778-8781
    • Akagi, F.1    Matsuo, T.2    Kawaguchi, H.3
  • 36
    • 84879655247 scopus 로고    scopus 로고
    • Dinitrogen cleavage and hydrogenation by a trinuclear titanium polyhydride complex
    • Shima, T. et al. Dinitrogen cleavage and hydrogenation by a trinuclear titanium polyhydride complex. Science 340, 1549-1552 (2013).
    • (2013) Science , vol.340 , pp. 1549-1552
    • Shima, T.1
  • 37
    • 85015235228 scopus 로고    scopus 로고
    • Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated nitrogen transfer and hydrogenation
    • Wang, P. et al. Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated nitrogen transfer and hydrogenation. Nat. Chem. 9, 64-70 (2017).
    • (2017) Nat. Chem. , vol.9 , pp. 64-70
    • Wang, P.1
  • 38
    • 37049093005 scopus 로고
    • The berthelot or indophenol reaction and its use in the analytical chemistry of nitrogen. A review
    • Searle, P. L. The berthelot or indophenol reaction and its use in the analytical chemistry of nitrogen. A review. Analyst 109, 549-568 (1984).
    • (1984) Analyst , vol.109 , pp. 549-568
    • Searle, P.L.1
  • 39
    • 33947455094 scopus 로고
    • A spectrophotometric method for the determination of hydrazine
    • Watt, G. W. & Chrisp, J. D. A spectrophotometric method for the determination of hydrazine. Anal. Chem. 24, 2006-2008 (1952).
    • (1952) Anal. Chem. , vol.24 , pp. 2006-2008
    • Watt, G.W.1    Chrisp, J.D.2
  • 41
    • 84937232466 scopus 로고    scopus 로고
    • Depth probing of the hydride formation process in thin Pd films by combined electrochemistry and fiber optics-based in situ UV/vis spectroscopy
    • Wickman, B. et al. Depth probing of the hydride formation process in thin Pd films by combined electrochemistry and fiber optics-based in situ UV/vis spectroscopy. Phys. Chem. Chem. Phys. 17, 18953-18960 (2015).
    • (2015) Phys. Chem. Chem. Phys. , vol.17 , pp. 18953-18960
    • Wickman, B.1
  • 42
    • 34247133536 scopus 로고    scopus 로고
    • Preparation and electrochemical characterization of palladium single crystal electrodes in 0. 1 M H2SO4 and HClO4: Part I. Low-index phases
    • Hara, M., Linke, U. & Wandlowski, T. Preparation and electrochemical characterization of palladium single crystal electrodes in 0. 1 M H2SO4 and HClO4: Part I. Low-index phases. Electrochim. Acta 52, 5733-5748 (2007).
    • (2007) Electrochim. Acta , vol.52 , pp. 5733-5748
    • Hara, M.1    Linke, U.2    Wandlowski, T.3
  • 43
    • 84927951052 scopus 로고    scopus 로고
    • Pd-catalyzed electrohydrogenation of carbon dioxide to formate: High mass activity at low overpotential and identification of the deactivation pathway
    • Min, X. & Kanan, M. W. Pd-catalyzed electrohydrogenation of carbon dioxide to formate: high mass activity at low overpotential and identification of the deactivation pathway. J. Am. Chem. Soc. 137, 4701-4708 (2015).
    • (2015) J. Am. Chem. Soc. , vol.137 , pp. 4701-4708
    • Min, X.1    Kanan, M.W.2
  • 44
    • 85001976280 scopus 로고    scopus 로고
    • Rational design of efficient palladium catalysts for electroreduction of carbon dioxide to formate
    • Klinkova, A. et al. Rational design of efficient palladium catalysts for electroreduction of carbon dioxide to formate. ACS Catal. 6, 8115-8120 (2016).
    • (2016) ACS Catal. , vol.6 , pp. 8115-8120
    • Klinkova, A.1
  • 45
    • 85017128460 scopus 로고    scopus 로고
    • Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles
    • Gao, D. F. et al. Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles. Nano Res. 10, 2181-2191 (2017).
    • (2017) Nano Res. , vol.10 , pp. 2181-2191
    • Gao, D.F.1
  • 46
    • 12844254253 scopus 로고    scopus 로고
    • Ammonia synthesis from first-principles calculations
    • Honkala, K. et al. Ammonia synthesis from first-principles calculations. Science 307, 555-558 (2005).
    • (2005) Science , vol.307 , pp. 555-558
    • Honkala, K.1
  • 47
    • 17644368513 scopus 로고    scopus 로고
    • Biomimetic hydrogen evolution: MoS2 nanoparticles as catalyst for hydrogen evolution
    • Hinnemann, B. et al. Biomimetic hydrogen evolution: MoS2 nanoparticles as catalyst for hydrogen evolution. J. Am. Chem. Soc. 127, 5308-5309 (2005).
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 5308-5309
    • Hinnemann, B.1
  • 48
    • 11744384413 scopus 로고
    • The Grotthuss mechanism
    • Agmon, N. The Grotthuss mechanism. Chem. Phys. Lett. 244, 456-462 (1995).
    • (1995) Chem. Phys. Lett. , vol.244 , pp. 456-462
    • Agmon, N.1


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