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Volumn 59, Issue 15, 1999, Pages 10099-10104

Phonon density of states of silicon clathrates: Characteristic width narrowing effect with respect to the diamond phase

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EID: 85044188558     PISSN: 01631829     EISSN: None     Source Type: Journal    
DOI: 10.1103/physrevb.59.10099     Document Type: Article
Times cited : (66)

References (25)
  • 2
    • 0005032380 scopus 로고
    • R. Moret, Phys. Rev. B 48, 17 619 (1993), and references therein.
    • (1993) Phys. Rev. B , vol.48 , pp. 17619
    • Moret, R.1
  • 12
    • 85045291000 scopus 로고    scopus 로고
    • 8@Si-46.
  • 14
    • 85045290843 scopus 로고    scopus 로고
    • We used the terms "optical" and "acoustic" modes for convenience. In fact, optical and acoustic modes are strictly defined for specific wave vectors. Moreover, owing to the frustration in the clathrate lattice, the optic modes cannot be established. Nevertheless, the labeled "optic" and "acoustic" bands allow a simple comparison between the clathrate and the diamond lattices.
  • 19
    • 0009005043 scopus 로고
    • M. Widom [Phys. Rev. B 34, 756 (1986)] has mentioned that the rigidity of the crystal is enhanced for quasicrystal (i.e., icosahedral symmetry) as compared to the fee lattice (i.e., diamond). Let us remember that the clathrate lattice has a relationship with an icosahedral structure containing a periodic array of disclination lines [J. F. Sadoc and R. Mosseri, J. Non-Cryst. Solids 61-62, 487 (1984)]. Thus, Widom has shown that soft modes at low-energy vanish in icosahedron lattice. Consequently, one might observe a shift towards high energy and a narrowing effect in the clathrate acoustic modes. If the introduction of alkali atoms within the cages suppresses the isotropy effect, such soft modes could appear.
    • (1986) Phys. Rev. B , vol.34 , pp. 756
    • Widom, M.1
  • 20
    • 0020496413 scopus 로고
    • M. Widom [Phys. Rev. B 34, 756 (1986)] has mentioned that the rigidity of the crystal is enhanced for quasicrystal (i.e., icosahedral symmetry) as compared to the fee lattice (i.e., diamond). Let us remember that the clathrate lattice has a relationship with an icosahedral structure containing a periodic array of disclination lines [J. F. Sadoc and R. Mosseri, J. Non-Cryst. Solids 61-62, 487 (1984)]. Thus, Widom has shown that soft modes at low-energy vanish in icosahedron lattice. Consequently, one might observe a shift towards high energy and a narrowing effect in the clathrate acoustic modes. If the introduction of alkali atoms within the cages suppresses the isotropy effect, such soft modes could appear.
    • (1984) J. Non-Cryst. Solids , vol.61-62 , pp. 487
    • Sadoc, J.F.1    Mosseri, R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.