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see ref.[1]
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For recent examples of ionic and cross-coupling methods, see:
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For recent examples of ionic and cross-coupling methods, see:.
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For recent examples of carbene-mediated methods see:
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For recent examples of carbene-mediated methods see:.
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39
-
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85130089247
-
-
There are multiple conflicting reports for the reduction potential of both Selectfluor and NFSI. We selected the most recently reported values (see ref.[16]). See also:
-
There are multiple conflicting reports for the reduction potential of both Selectfluor and NFSI. We selected the most recently reported values (see ref.[16]). See also:.
-
-
-
-
40
-
-
0000508147
-
-
62
-
Gilicinski, A.G., Pez, G.P., Syvret, R.G., Lal, G.S., J. Fluorine Chem., 59, 1992, 157 62.
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-
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Lal, G.S.4
-
44
-
-
85130084224
-
-
NFSI absorbs at 270 nm with a shoulder at 277 nm. For an absorbance spectrum, see the Supporting Information.
-
NFSI absorbs at 270 nm with a shoulder at 277 nm. For an absorbance spectrum, see the Supporting Information.
-
-
-
-
45
-
-
85130083376
-
-
The absorption maxima for acetone occurs at 270 nm and tails to 330 nm. See: Tables of Physical & Chemical Constants, 16th ed., 1995, chapter 3.8.7. Kaye & Laby Online, version 1.0 (retrieved April 15, 2013).
-
The absorption maxima for acetone occurs at 270 nm and tails to 330 nm. See: Tables of Physical & Chemical Constants, 16th ed., 1995, chapter 3.8.7. Kaye & Laby Online, version 1.0, 2005: www.kayelaby.npl.co.uk (retrieved April 15, 2013).
-
(2005)
-
-
-
46
-
-
85130084946
-
-
With the exception of substrate 1g, which was originally reported in a previous Selectfluor reactivity study (ref.[8]), all compounds are new. See the Supporting Information for experimental details.
-
With the exception of substrate 1g, which was originally reported in a previous Selectfluor reactivity study (ref.[8]), all compounds are new. See the Supporting Information for experimental details.
-
-
-
-
47
-
-
85130089544
-
-
Substrates 2g, 2h, and 2i could be synthesized by using our photoredox catalysis method (ref.[9]) owing to the lower energy light that was utilized.
-
Substrates 2g, 2h, and 2i could be synthesized by using our photoredox catalysis method (ref.[9]) owing to the lower energy light that was utilized.
-
-
-
-
48
-
-
85130083414
-
-
The remaining mass balance contained fluorinated products from nonselective reactions.
-
The remaining mass balance contained fluorinated products from nonselective reactions.
-
-
-
-
49
-
-
85130087924
-
-
see:
-
For reviews on photoinduced electron transfer (PET), see:.
-
-
-
-
55
-
-
85130089439
-
-
The identity of the base is not clear as there are three possible candidates: B8, 16, and bis(phenylsulfonyl)amide.
-
The identity of the base is not clear as there are three possible candidates: B8, 16, and bis(phenylsulfonyl)amide.
-
-
-
-
58
-
-
85130086462
-
-
As product 14 is relatively unstable, we primarily focused on the decarboxylation rather than the appearance of specific radical products.
-
As product 14 is relatively unstable, we primarily focused on the decarboxylation rather than the appearance of specific radical products.
-
-
-
-
59
-
-
85130086831
-
-
Whereas B7 and B8 are not mechanistically necessary as bases, in: sensitized photofluorodecarboxylations, the addition of these pyridine bases leads to the formation of fewer fluorinated byproducts with select substrates. See the Supporting Information for additional details.
-
Whereas B7 and B8 are not mechanistically necessary as bases, in: sensitized photofluorodecarboxylations, the addition of these pyridine bases leads to the formation of fewer fluorinated byproducts with select substrates. See the Supporting Information for additional details.
-
-
-
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