Electrochemical conversion of CO2 to formic acid utilizing Sustainion™ membranes

Journal of CO2 Utilization

Volumn 20, Issue , 2017, Pages 208-217

  Yang, Hongzhou ^a   Kaczur, Jerry J ^a   Sajjad, Syed Dawar ^a   Masel, Richard I ^a  

^a DIOXIDE MATERIALS   (United States)

Author keywords

Anion exchange membrane; CO2 reduction; CO2 utilization; Electrochemical; Formic acid

Indexed keywords

CELLS; CYTOLOGY; ELECTROCATALYSTS; ELECTROCHEMICAL CELLS; ELECTROLYTIC REDUCTION; FORMIC ACID; HYDROGEN STORAGE; ION EXCHANGE MEMBRANES; REDUCTION;

ANION EXCHANGE MEMBRANE; CONCENTRATION RANGES; ELECTROCHEMICAL; ELECTROCHEMICAL CELL PERFORMANCE; ELECTROCHEMICAL CONVERSION; ELECTROCHEMICAL REDUCTIONS; HIGH CURRENT DENSITIES; RENEWABLE CHEMICALS;

CARBON DIOXIDE;

EID: 85020272680     PISSN: 22129820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcou.2017.04.011     Document Type: Article

References (70)

1. 2 into Useful Products 1993 CRC Press Boca Raton, FL 67 127
2. M. Aresta Carbon Dioxide as Chemical Feedstock 2010 Wiley-VCH Weinheim 1 13 ISBN-13 9783527324750
3. 2 as a chemical feedstock: opportunities and challenges Dalton Trans. 28 2007 2975 2992
4. 2 utilization via direct heterogeneous electrochemical reduction J. Phys. Chem. Lett. 1 2010 3451 3458
5. E.A. Quadrelli, G. Centi, J.-L. Duplan, and S. Perathoner Carbon dioxide recycling: emerging large-scale technologies with industrial potential ChemSusChem 4 2011 1194 1215
6. S. Sankaranarayanan, and K. Srinivasan Carbon dioxide - a potential raw material for the production of fuel, fuel additives and bio-derived chemicals Indian J. Chem. 51A September-October 2012 1252 1262
7. 2 conversion to fuels and chemicals as an economically viable route to CCR Energy Procedia 63 2014 7959 7962
8. 2 conversion to chemicals with emphasis on using renewable energy/resources to drive the conversion S. Snyder, RSC Green Chemistry, No. 43, Commercializing Biobased Products: Opportunities, Challenges, Benefits, and Risks 2016 215 257 10.1039/9781782622444-00215 eISBN: 978-1-78262-244-4 (Chapter 10)
9. 2 conversion into chemicals and fuels: the distinctive contribution of chemical catalysis and biotechnology J. Catal. 343 2016 2 45
10. M. Scibioh, and B. Viswanathan Electrochemical reduction of carbon dioxide: a status report Proc. Indian Natl. Sci. Acad. 70 2004 407 462
11. 2 Util. 1 2013 18 27
12. X. Lu, D.Y.C. Leung, H. Wang, M.K.H. Leung, and J. Xuan Electrochemical reduction of carbon dioxide to formic acid ChemElectroChem 1 2014 836 849
13. D. Pletcher The cathodic reduction of carbon dioxide - what can it realistically achieve? A mini review Electrochem. Commun. 61 2015 97 101
14. 2 in aqueous solutions on metals with high and moderate hydrogen overvoltages J. Electroanal. Chem. 189 1985 271 294
15. H. Noda, S. Ikeda, Y. Oda, K. Imai, M. Maeda, and K. Ito Electrochemical reduction of carbon dioxide at various metal electrodes in aqueous potassium hydrogen carbonate solution Bull. Chem. Soc. Jpn. 63 1990 2459 2462
16. 3 solution J. Electroanal. Chem. 394 1995 199 203
17. 3 media J. Electrochem. Soc. 137 1990 1772 1776
18. 2 at metal electrodes in aqueous media Electrochim. Acta 39 1994 1833 1839
19. M. Jitaru, D.A. Lowy, M. Toma, B.C. Toma, and L. Oniciu Electrochemical reduction of carbon dioxide on flat metallic cathodes J. Appl. Electrochem. 27 1997 875 889
20. M. Jitaru Electrochemical carbon dioxide reduction - fundamental and applied topics (review) J. Univ. Chem. Tech. Metall. 42 4 2007 333 344
21. 2 reduction on metal electrodes Mod. Asp. Electrochem. 42 2008 89 189
22. H. Li, and C. Oloman Development of a continuous reactor for the electro-reduction of carbon dioxide to formate. Part 1. Process variables J. Appl. Electrochem. 36 2006 1105 1115
23. C. Oloman, and H. Li Electrochemical processing of carbon dioxide ChemSusChem 1 2008 385 391
24. H. Li, and C. Oloman Development of a continuous reactor for the electro-reduction of carbon dioxide to formate. Part 2. Scaleup J. Appl. Electrochem. 37 2007 1107 1117
25. S.R. Narayanan, B. Haines, and T.I. Valdez Electrochemical conversion of carbon dioxide to formate in alkaline polymer electrolyte membrane cells J. Electrochem. Soc. 158 2 2011 A167 A173
26. M. Alvarez-Guerra, S. Quintanilla, and A. Irabien Conversion of carbon dioxide into formate using a continuous electrochemical reduction process in a lead cathode Chem. Eng. J. 207 2012 278 284
27. M. Alvarez-Guerra, A. Del Castillo, and A. Irabien Continuous electrochemical reduction of carbon dioxide into formate using a tin cathode: comparison with lead cathode Chem. Eng. Res. Des. 92 4 2014 692 701
28. B. Innocent, D. Liaigre, D. Pasquier, F. Ropital, J. Léger, and K.B. Kokoh Electro-reduction of carbon dioxide to formate on lead electrode in aqueous medium J. Appl. Electrochem. 39 2009 227 232
29. B. Innocent, D. Pasquier, F. Ropital, F. Hahn, J.M. Léger, and K.B. Kokoh FTIR spectroscopic study of the reduction of carbon dioxide on lead electrode in aqueous medium Appl. Catal. B: Environ. 94 2010 219 224
30. D.T. Whipple, E.C. Finke, and P.J.A. Kenis Microfluidic reactor for the electrochemical reduction of carbon dioxide: the effect of pH Electrochem. Solid-State Lett. 13 9 2010 B109 B111
31. Z.M. Detweiler, J.L. White, S.L. Bernasek, and A.B. Bocarsly Anodized indium metal electrodes for enhanced carbon dioxide reduction in aqueous electrolyte Langmuir 30 2014 7593 7600
32. 2 electroreduction using electrodeposited tin on GDE J. Mater. Chem. A 4 2016 13582 13588
33. A.S. Agarwal, Y. Zhai, D. Hill, and N. Sridhar The electrochemical reduction of carbon dioxide to formate/formic acid: engineering and economic feasibility ChemSusChem 4 2011 1301 1310
34. J. Wu, F.G. Risalvato, F.-S. Ke, P.J. Pellechia, and X.-D. Zhou Electrochemical reduction of carbon dioxide I. Effects of the electrolyte on the selectivity and activity with Sn electrode J. Electrochem. Soc. 159 7 2012 F353 F359
35. J. Wu, F.G. Risalvato, F.-S. Ke, P.J. Pellechia, and X.-D. Zhou Electrochemical reduction of carbon dioxide II. Design, assembly, and performance of low temperature full electrochemical cells J. Electrochem. Soc. 160 9 2012 F953 F957
36. L.R. Zhang, P. Gao, and L. Lei Studies on the Faradaic efficiency for electrochemical reduction of carbon dioxide to formate on tin electrode J. Power Sources 253 2014 276 281
37. S. Zhang, P. Kang, and T.J. Meyer Nanostructured tin catalysts for selective electrochemical reduction of carbon dioxide to formate J. Am. Chem. Soc. 136 2014 1734 1737
38. J. Wu, P.P. Sharma, B.H. Harris, and X.X. Zhou Electrochemical reduction of carbon dioxide: IV dependence of the Faradaic efficiency and current density on the microstructure and thickness of tin electrode J. Power Sources 258 2014 189 194
39. 2 Util. 7 2014 1 5
40. J. Qiao, Y. Liu, F. Hong, and J. Zhang A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Chem. Soc. Rev. 43 2014 631 675
41. 2 Electrochim. Acta 159 2015 242 251
42. 2 reduction to formate on nanoporous tin foam electrocatalysts ChemistrySelect 1 2016 1711 1715
43. M.N. Mahmood, D. Masheder, and C.J. Harty Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. I. Reduction at lead, indium- and tin-impregnated electrodes J. Appl. Electrochem. 17 1987 1159 1170
44. 2 to formate at high current density using gas diffusion electrodes J. Appl. Electrochem. 44 2014 1107 1116
45. S. Sen, B. Skinn, T. Hall, M. Inman, E.J. Taylor, and F.R. Brushett Pulsed electrodeposition of tin electrocatalysts onto gas diffusion layers for carbon dioxide reduction to formate MRS Adv. 2017 1 8 10.1557/adv.2016.652
46. 2 reduction at gas-diffusion electrodes J. Electroanal. Chem. 431 1997 39 41
47. E. Korngold Electrodialysis processes using ion exchange resins between membranes Desalination 16 1975 225 233
48. E. DeJean, E. Laktionov, J. Sandeaux, R. Sandeaux, G. Pourcelly, and C. Gavach Electrodeionization with ion-exchange textile for the production of high resistivity water: influence of the nature of the textile Desalination 114 1997 165 173
49. E. DeJean, J. Sandeaux, R. Sandeaux, and C. Gavach Water demineralization by electrodeionization with ion exchange textiles. Comparison with conventional electrodialysis Sep. Sci. Technol. 33 6 1998 801 818
50. A. Mahmoud, L. Muhr, G. Grévillot, G. Valetin, and F. Lapique Ohmic drops in the ion-exchange bed of cationic electrodeionisation cells J. Appl. Electrochem. 36 2006 277 285
51. D.V. Golubenko, J. Kŕivčik, and A.B. Yaroslavtsev Evaluating the effectiveness of ion exchangers for the electrodeionization process Pet. Chem. 55 10 2015 769 775
52. E. Korngold, L. Aronov, and O. Kedem Novel ion-exchange spacer for improving electrodialysis I. Reacted spacer J. Membr. Sci. 138 1998 165 170
53. K. Zhang, M. Wang, D. Wang, and C. Gao The energy-saving production of tartaric acid using ion exchange resin-filling bipolar membrane electrodialysis J. Membr. Sci. 341 2009 246 251
54. B. Zhang, H. Gao, and Y. Chen Enhanced ionic conductivity and power generation using ion-exchange resin beads in a reverse-electrodialysis stack Environ. Sci. Technol. 49 2015 14717 14724
55. J.J. Kaczur, D.W. Cawlfield. Electrochemical process for producing chlorine dioxide solutions from chlorites. U.S. Patent 5,092,970 (1992).
56. D.W. Cawlfield, J.J. Kaczur, H. Arabghani. Process for removing catalyst impurities from polyols. U.S. Patent 5,254,227 (1993).
57. R.I. Masel, B.A. Rosen. Catalyst Mixtures. U.S. Patent 8,956,990 (2014).
58. R.I. Masel, Q. Chen. Carbon Dioxide Conversion to Fuels and Chemicals. U.S. Patent 9,193,593 (2015).
59. R.I. Masel, Q. Chen, Z. Liu, R. Kutz. Ion-Conducting Membranes, U.S. Patent 9,370,773 (2016).
60. R.I. Masel, Q. Chen, Z. Liu, R. Kutz. Electrochemical Device for Converting Carbon Dioxide to a Reaction Product. U.S. Patent 9,481,939 (2016).
61. R.I. Masel, B.A. Rosen, W. Zhu. Devices and Processes for Carbon Dioxide Conversion into Useful Fuels and Chemicals. U.S. Patent 9,181,625 (2014).
62. R.I. Masel, A. Salahi-Khogin, B.A. Rosen. Catalysts for Electrochemical Conversion of Carbon Dioxide. U.S. Patent 9,012,345 (2015).
63. 2 to CO at low overpotentials Science 334 2011 643 644
64. 2 Util. 15 2015 50 56
65. 2 electrolysis Energy Technol. 2017 10.1002/ente.201600636
66. ® membranes J. Power Sources 117 2003 35 38
67. N. Akiya, and P.E. Savage Role of water in formic acid decomposition AIChE J. 44 2 1998 405 415
68. M. Tsuji, M. Hattori, and D. Shimamoto Hydrogen production from formic acid decomposition at room temperature Chim. Oggi - Chem. Today 34 3 2016 55 58
69. G.W.C. Kaye, and T.H. Laby Tables of Physical and Chemical Constants and Some Mathematical Functions 15th ed. 1986 Longmans, Green, Co. NY, USA ISBN-13: 978-0582463547, 219
70. J.J. Kaczur, H. Yang, S.D. Sajjad, R.I. Masel. Method and System For Electrochemical Production of Formic Acid from Carbon Dioxide. U.S. Patent Application 2017/0037522 (2017).