Tinned graphite felt cathodes for scale-up of electrochemical reduction of aqueous CO2

Electrochimica Acta

Volumn 159, Issue , 2015, Pages 242-251

  Bumroongsakulsawat, P ^a,b   Kelsall, G H ^a  

^a IMPERIAL COLLEGE LONDON   (United Kingdom)

^b CHULALONGKORN UNIVERSITY   (Thailand)

Author keywords

CO2 electrochemical reduction; Sn formate bubble

Indexed keywords

CARBON DIOXIDE; CURRENT DENSITY; DROPS; ELECTRODES; ELECTROLYTES; ELECTROLYTIC REDUCTION; FELT; FELTS; FLOW RATE; GRAPHITE; REACTION RATES; REDUCTION; SOLUTIONS; TIN; TINNING;

CONDUCTING PHASE; EFFECTIVE CONDUCTIVITY; ELECTROCHEMICAL REDUCTIONS; ELECTRODE POTENTIALS; ELECTROLYTE SOLUTIONS; INCREASING SOLUTIONS; MASS TRANSPORT RATE; SOLUTION FLOW RATE;

CATHODES;

EID: 84922934033     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2015.01.209     Document Type: Article

References (40)

1. 2 at metal electrodes in aqueous media Electrochimica Acta 39 1994 1833 1839
2. K.P. Kuhl, E.R. Cave, D.N. Abram, and T.F. Jaramillo New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Energy Environ. Sci. 5 2012 7050 7059
3. W. Paik, T.N. Andersen, and H. Eyring Kinetic studies of the electrolytic reduction of carbon dioxide on the mercury electrode Electrochim. Acta 14 1969 1217 1232
4. J. Ryu, T.N. Andersen, and H. Eyring Electrode reduction kinetics of carbon dioxide in aqueous solution J. Phys. Chem. 76 1972 3278 3286
5. Y. Hori, and S. Suzuki Electrolytic reduction of bicarbonate ion at a mercury electrode J. Electrochem. Soc. 130 1983 2387 2390
6. B. Innocent, D. Liaigre, D. Pasquier, F. Ropital, J.M. Leger, and K.B. Kokoh Electro-reduction of carbon dioxide to formate on lead electrode in aqueous medium J. Appl. Electrochem. 39 2009 227 232
7. H. Li, and C. Oloman The Electro-Reduction of Carbon Dioxide in a Continuous Reactor J. Appl. Electrochem. 35 2005 955 965
8. H. Li, and C. Oloman Development of a continuous reactor for the electro-reduction of carbon dioxide to formate-Part 1: Process variables J. Appl. Electrochem. 36 2006 1105 1115
9. H. Li, and C. Oloman Development of a continuous reactor for the electro-reduction of carbon dioxide to formate - Part 2: Scale-up J. Appl. Electrochem. 37 2007 1107 1117
10. 2 to HCOOH on a gallium oxide cathode Electrochem. Commun. 43 2014 95 97
11. 2 at three-phase (gas £ liquid £ solid) and two-phase (liquid £ solid) interfaces on Ag electrodes J. Electroanal. Chem. 533 2002 113 118
12. 2 reduction to CO in aqueous electrolytes I. kinetic study on planar silver and gold electrodes J. Electrochem. Soc. 157 2010 B1902 B1910
13. V. Lates, A. Falch, A. Jordaan, R. Peach, and R.J. Kriek An electrochemical study of carbon dioxide electroreduction on gold-based nanoparticle catalysts Electrochim. Acta 128 2014 75 84
14. P.G. Russell, N. Kovac, S. Srinivasan, and M. Steinberg The electrochemical reduction of carbon dioxide formic Acid, and formaldehyde J. Electrochem. Soc. 124 1977 1329 1338
15. 2 storage Energy Fuels 18 2004 285 286
16. A. Schizodimou, and G. Kyriacou Acceleration of the reduction of carbon dioxide in the presence of multivalent cations Electrochim. Acta 78 2012 171 176
17. 2 at Sn cathodes Electrochim. Acta 141 2014 216 225
18. 2 at metal electrodes in aqueous media Electrochim. Acta 39 1994 1833 1839
19. K.J.P. Schouten, Y. Kwon, d.H. van, Z. Qin, and M.T.M. Koper A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes Chem. Sci. 2 2011 1902 1909
20. Y. Hori, A. Murata, and R. Takahashi Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution J. Chem. Soc. Faraday Trans. 85 1989 2309 2326
21. 2 electroreduction J. Appl. Electrochem. 23 1993 483 486
22. K.J.P. Schouten, Z. Qin, E.P. Gallent, and M.T.M. Koper Two pathways for the formation of ethylene in CO reduction on single-crystal copper electrodes J. Am. Chem. Soc. 134 2012 9864 9867
23. 2 to C2 hydrocarbons using different ex situ copper electrodeposits Electrochim. Acta 102 2013 388 392
24. 2 Electrochim. Acta 50 2005 5354 5369
25. L.M. Chiacchiarelli, Y. Zhai, G.S. Frankel, A.S. Agarwal, and N. Sridhar Cathodic degradation mechanisms of pure Sn electrocatalyst in a nitrogen atmosphere J. Appl. Electrochem. 42 2012 21 29
26. 3 media J. Appl. Electrochem. 33 2003 447 450
27. S.R. Narayanan, B. Haines, J. Soler, and T.I. Valdez Electrochemical conversion of carbon dioxide to formate in alkaline polymer electrolyte membrane cells J. Electrochem. Soc. 158 2011 A167 A173
28. E. Dufek, T. Lister, and M. McIlwain Bench-scale electrochemical system for generation of CO and syn-gas J. Appl. Electrochem. 41 2011 623 631
29. 2O reduction at room temperature J. Electrochem. Soc. 155 2008 B42 B49
30. M. Maeda, Y. Kitaguchi, S. Ikeda, and K. Ito Reduction of carbon dioxide on partially-immersed Au plate electrode and Au-SPE electrode J Electroanal Chem 238 1987 247 258
31. 2 reduction to hydrocarbons at solid polymer electrolyte cells J. Electrochem. Soc. 135 1988 1470 1471
32. 2 Electrochim. Acta 40 1995 745 753
33. Y. Hori, H. Ito, K. Okano, K. Nagasu, and S. Sato Silver-coated ion exchange membrane electrode applied to electrochemical reduction of carbon dioxide Electrochim. Acta 48 2003 2651 2657
34. M.N. Mahmood, D. Masheder, and C.J. Harty Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide.1. reduction at lead, indium-impregnated and tin-impregnated electrodes J. Appl. Electrochem. 17 1987 1159 1170
35. J.A. Trainham, and J. Newman The effect of electrode placement and finite matrix conductivity on the performance of flow-through porous electrodes J. Electrochem. Soc. 125 1978 58 68
36. J.A. Trainham, and J. Newman A flow-through porous electrode model: application to metal-ion removal from dilute streams J. Electrochem. Soc. 124 1977 1528 1540
37. Y. Zhang Modern electroplating M. Schlesinger, M. Paunovic, 2000 John Wiley & Sons, Inc. New York
38. B. Delanghe, S. Tellier, and M. Astruc Mass transfer to a carbon or graphite felt electrode Electrochim. Acta 35 1990 1369 1376
39. A.J. Appleby, M. Chemla, H. Kita, G. Bronoel, Vol. IX, Marcel Dekker, New York, 1982.
40. B.G. Ateya, and M. El-Shakre Applications of porous flow-through electrodes. III. Effect of gas evolution on the pore electrolyte resistance J. Appl. Electrochem. 14 1984 367 371