Terminal Titanyl Complexes of Tri- and Tetrametaphosphate: Synthesis, Structures, and Reactivity with Hydrogen Peroxide

Inorganic Chemistry

Volumn 56, Issue 5, 2017, Pages 3022-3029

  Stauber, Julia M ^a   Cummins, Christopher C ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 85014534813     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/acs.inorgchem.6b03149     Document Type: Article

References (64)

1. Collins, T. J. TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems Acc. Chem. Res. 2002, 35, 782-790 10.1021/ar010079s
2. Nam, W. High-Valent Iron(IV)-Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions Acc. Chem. Res. 2007, 40, 522-531 10.1021/ar700027f
3. Sheldon, R. A.; Wallau, M.; Arends, I. W. C. E.; Schuchardt, U. Heterogeneous Catalysts for Liquid-Phase Oxidations: Philosophers’ Stones or Trojan Horses? Acc. Chem. Res. 1998, 31, 485-493 10.1021/ar9700163
4. Arends, I.; Sheldon, R. Activities and Stabilities of Heterogeneous Catalysts in Selective Liquid Phase Oxidations: Recent Developments Appl. Catal., A 2001, 212, 175-187 10.1016/S0926-860X(00)00855-3
5. Wilson, S. L.; Jones, C. W. Solid Solutions for Cleaning up Chemical Processes Using Hydrogen Peroxide. In Proceedings of the 3rd World Congress on Oxidation Catalysis; Grasselli, R. K.; Oyama, S. T.; Lyons, J., Eds.; Elsevier: Amsterdam, 1997; Vol. 110, pp 603-613.
6. Sheldon, R. A. In Organic Peroxygen Chemistry; Herrmann, W. A., Ed.; Springer: Berlin, Heidelberg, 1993; pp 21-43.
7. Notari, B. Titanium Silicalites Catal. Today 1993, 18, 163-172 10.1016/0920-5861(93)85029-Y
8. Taramasso, M.; Perego, G.; Notari, B. U.S. Patent 4,410,501, 1983.
9. Clerici, M. G. In Titanium Silicalite-1; Wiley-VCH: Weinheim, Germany, 2009; pp 705-754.
10. Clerici, M. The Activity of Titanium Silicalite-1 (TS-1): Some Considerations on its Origin Kinet. Catal. 2015, 56, 450-455 10.1134/S0023158415040059
11. 2O Solutions Investigated by Ab Initio Cluster and Periodic Approaches Combined with Experimental XANES and EXAFS Data: A Review and New Highlights Phys. Chem. Chem. Phys. 2007, 9, 4854-4878 10.1039/b706637f
12. Corma, A. State of the Art and Future Challenges of Zeolites as Catalysts J. Catal. 2003, 216, 298-312 10.1016/S0021-9517(02)00132-X
13. 2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest Inorg. Chem. 2015, 54, 10530-10532 10.1021/acs.inorgchem.5b01863
14. 2 Activation Eur. J. Inorg. Chem. 2009, 5134-5141 10.1002/ejic.200900608
15. 2 by Ti-and Other TM-Containing Polyoxometalates: Role of the Metal Nature and Coordination Environment J. Am. Chem. Soc. 2010, 132, 7488-7497 10.1021/ja1023157
16. 2- and Acidic Methyl Ester, and Conversion to Tetrametaphosphate Metal Complexes via Protonolysis J. Am. Chem. Soc. 2014, 136, 11894-11897 10.1021/ja5058339
17. Chakarawet, K.; Knopf, I.; Nava, M.; Jiang, Y.; Stauber, J. M.; Cummins, C. C. Crystalline Metaphosphate Acid Salts: Synthesis in Organic Media, Structures, Hydrogen-Bonding Capability, and Implication of Superacidity Inorg. Chem. 2016, 55, 6178-6185 10.1021/acs.inorgchem.6b00749
18. Yamamoto, A.; Kambara, S. Structures of the Reaction Products of Tetraalkoxytitanium with Acetylacetone and Ethyl Acetoacetate J. Am. Chem. Soc. 1957, 79, 4344-4348 10.1021/ja01573a028
19. 2 Inorg. Chem. 1972, 11, 2989-2993 10.1021/ic50118a024
20. 2+) in Acidic Aqueous Solutions Inorg. Chem. 1985, 24, 2320-2321 10.1021/ic00208a041
21. Hill, J. E.; Fanwick, P. E.; Rothwell, I. P. Isolation and Characterization of Bis(2,6-diisopropylphenoxo)bis(4-pyrrolidinopyridine)oxotitanium: A Mononuclear Aryloxide Compound Containing a Terminal Titanium(IV)-oxo Group Inorg. Chem. 1989, 28, 3602-3604 10.1021/ic00317a041
22. Housmekerides, C. E.; Ramage, D. L.; Kretz, C. M.; Shontz, J. T.; Pilato, R. S.; Geoffroy, G. L.; Rheingold, A. L.; Haggerty, B. S. Addition and Cycloaddition Reactions of the Nucleophilic Oxo and Sulfido Complexes [tmtaa]Ti = X (X = O, S; tmtaa = Dianion of 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine) Inorg. Chem. 1992, 31, 4453-4468 10.1021/ic00048a006
23. Dwyer, P. N.; Puppe, L.; Buchler, J. W.; Scheidt, W. R. Molecular Stereochemistry of (α,γ-dimethyl-α,γ-dihydrooctaethylporphinato)oxotitanium(IV) Inorg. Chem. 1975, 14, 1782-1785 10.1021/ic50150a008
24. 6) Inorg. Chem. 1992, 31, 3737-3748 10.1021/ic00044a015
25. Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. In Advanced Inorganic Chemistry; Wiley-Interscience: New York, 1988; p 656.
26. Kamimura, S.; Matsunaga, T.; Kuwata, S.; Iwasaki, M.; Ishii, Y. Synthesis, Structures, and Solution Behavior of Di-and Trinuclear Titanium(IV)-Cyclophosphato Complexes Inorg. Chem. 2004, 43, 6127-6129 10.1021/ic049206h
27. Mendiratta, A.; Figueroa, J. S.; Cummins, C. C. Synthesis of a Four-coordinate Titanium(IV) Oxoanion via Deprotonation and Decarbonylation of Complexed Formate Chem. Commun. 2005, 3403-3405 10.1039/b504492h
28. Liu, Q.-X.; Zhou, Z.-H. Monomeric Peroxo Titanate Coordinated with Cyclohexanediaminetetraacetate: Towards the Active Oxygen Species of the Ti(IV) Site Hosted in the Titanium Silicalite Catalyst TS-1 Polyhedron 2012, 35, 1-6 10.1016/j.poly.2011.12.037
29. Mayer, J. M. Metal-Oxygen Multiple Bond Lengths: A Statistical Study Inorg. Chem. 1988, 27, 3899-3903 10.1021/ic00295a006
30. Pyykkö, P.; Atsumi, M. Molecular Double-Bond Covalent Radii for Elements Li-E112 Chem.-Eur. J. 2009, 15, 12770-12779 10.1002/chem.200901472
31. Ballhausen, C. J.; Gray, H. B. The Electronic Structure of the Vanadyl Ion Inorg. Chem. 1962, 1, 111-122 10.1021/ic50001a022
32. Winkler, J. R.; Gray, H. B. In Electronic Structures of Oxo-Metal Ions; Springer: Berlin, Heidelberg, 2012; pp 17-28.
33. Spek, A. L. Structure Validation in Chemical Crystallography Acta Crystallogr., Sect. D: Biol. Crystallogr. 2009, 65, 148-155 10.1107/S090744490804362X
34. Garner, C. D. The Early Transition Metals. In Inorganic Chemistry of the Transition Elements; Johnson, B. F. G., Ed.; The Royal Society of Chemistry: London, 1972; Vol. 1, pp 1-122.
35. Wong, E. H.; Sun, X.; Gabe, E. J.; Lee, F. L.; Charland, J. P. Coordination Complexes Derived from Tri-, Tetra-, and Pentaphosphoxane Rings Organometallics 1991, 10, 3010-3020 10.1021/om00055a011
36. 17O NMR Study of Oxo Metalloporphyrin Complexes: Correlation with Electronic Structure of MO Moiety J. Inorg. Biochem. 2006, 100, 533-541 10.1016/j.jinorgbio.2006.01.009
37. Comba, P.; Merbach, A. The Titanyl Question Revisited Inorg. Chem. 1987, 26, 1315-1323 10.1021/ic00255a024
38. 17O NMR Spectroscopic Detection and Characterization of Titanium(IV) Alkylperoxo Complex J. Mol. Catal. A: Chem. 1996, 105, 131-136 10.1016/1381-1169(95)00243-X
39. Blanchard, J.; Ribot, F.; Sanchez, C.; Bellot, P.-V.; Trokiner, A. Structural Characterization of Titanium-oxo-polymers Synthesized in the Presence of Protons or Complexing Ligands as Inhibitors J. Non-Cryst. Solids 2000, 265, 83-97 10.1016/S0022-3093(99)00885-6
40. 2, and Synthesis and Reactivity of its Peroxo, Disulphido, and Pyrocatecholato Derivatives J. Chem. Soc., Chem. Commun. 1982, 142-144 10.1039/c39820000142
41. 8taa]ME (M = Ti, V; E = Se, Te) J. Am. Chem. Soc. 1997, 119, 7609-7610 10.1021/ja971043r
42. -1 Adv. Mater. 2013, 25, 1165-1169 10.1002/adma.201204233
43. Seikel, E.; Grau, M.; Käsmarker, R.; Oelkers, B.; Sundermeyer, J. Synthesis and Crystal Structure of Novel, Soluble Titanyl Phthalocyanines Inorg. Chim. Acta 2011, 374, 119-126 10.1016/j.ica.2011.01.099
44. Konarev, D. V.; Kuzmin, A. V.; Faraonov, M. A.; Ishikawa, M.; Khasanov, S. S.; Nakano, Y.; Otsuka, A.; Yamochi, H.; Saito, G.; Lyubovskaya, R. N. Synthesis, Structures, and Properties of Crystalline Salts with Radical Anions of Metal-Containing and Metal-Free Phthalocyanines Chem.-Eur. J. 2015, 21, 1014-1028 10.1002/chem.201404925
45. x (x = 1-3) Structural Units Inorg. Chem. 1994, 33, 2462-2471 10.1021/ic00089a025
46. 2] (acac = acetylacetonate) J. Chem. Soc., Dalton Trans. 1997, 1309-1314 10.1039/a608140a
47. 2O Z. Naturforsch., B: Chem. Sci. 1997, 52, 1291-1295
48. 2O Inorg. Chim. Acta 1990, 175, 105-110 10.1016/S0020-1693(00)83203-X
49. Schwarzenbach, G.; Muehlebach, J.; Mueller, K. Peroxo Complexes of Titanium Inorg. Chem. 1970, 9, 2381-2390 10.1021/ic50093a001
50. Mimoun, H.; Postel, M.; Casabianca, F.; Fischer, J.; Mitschler, A. Novel Unusually Stable Peroxotitanium(IV) Compounds. Molecular and Crystal Structure of Peroxobis(picolinato) (hexamethylphosphoric triamide)titanium(IV) Inorg. Chem. 1982, 21, 1303-1306 10.1021/ic00134a004
51. Wang, G.-C.; Sung, H. H. Y.; Williams, I. D.; Leung, W.-H. Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand Inorg. Chem. 2012, 51, 3640-3647 10.1021/ic202564h
52. Guilard, R.; Latour, J. M.; Lecomte, C.; Marchon, J. C.; Protas, J.; Ripoll, D. Peroxotitanium(IV) Porphyrins. Synthesis, Stereochemistry, and Properties Inorg. Chem. 1978, 17, 1228-1237 10.1021/ic50183a027
53. Clerici, M. G. Oxidation of Saturated Hydrocarbons with Hydrogen Peroxide, Catalysed by Titanium Silicalite Appl. Catal. 1991, 68, 249-261 10.1016/S0166-9834(00)84106-8
54. Hulea, V.; Moreau, P.; Di Renzo, F. Thioether Oxidation by Hydrogen Peroxide Using Titanium-containing Zeolites as Catalysts J. Mol. Catal. A: Chem. 1996, 111, 325-332 10.1016/1381-1169(96)00203-8
55. Clerici, M.; Bellussi, G.; Romano, U. Synthesis of Propylene Oxide from Propylene and Hydrogen Peroxide Catalyzed by Titanium Silicalite J. Catal. 1991, 129, 159-167 10.1016/0021-9517(91)90019-Z
56. Xu, M.; Bunes, B. R.; Zang, L. Paper-Based Vapor Detection of Hydrogen Peroxide: Colorimetric Sensing with Tunable Interface ACS Appl. Mater. Interfaces 2011, 3, 642-647 10.1021/am1012535
57. Dakanali, M.; Kefalas, E. T.; Raptopoulou, C. P.; Terzis, A.; Voyiatzis, G.; Kyrikou, I.; Mavromoustakos, T.; Salifoglou, A. A New Dinuclear Ti(IV)-Peroxo-Citrate Complex from Aqueous Solutions. Synthetic, Structural, and Spectroscopic Studies in Relevance to Aqueous Titanium-Peroxo-Citrate Speciation Inorg. Chem. 2003, 42, 4632-4639 10.1021/ic0343051
58. Kholdeeva, O. A.; Trubitsina, T. A.; Maksimovskaya, R. I.; Golovin, A. V.; Neiwert, W. A.; Kolesov, B. A.; López, X.; Poblet, J. M. First Isolated Active Titanium Peroxo Complex: Characterization and Theoretical Study Inorg. Chem. 2004, 43, 2284-2292 10.1021/ic0354466
59. Wang, G.-C.; Sung, H. H. Y.; Williams, I. D.; Leung, W.-H. Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand Inorg. Chem. 2012, 51, 3640-3647 10.1021/ic202564h
60. Rohe, M.; Merz, K. Active Peroxo Titanium Complexes: Syntheses, Characterization and their Potential in the Photooxidation of 2-Propanol Chem. Commun. 2008, 862-864 10.1039/B716199A
61. Notari, B. Microporous Crystalline Titanium Silicates Adv. Catal. 1996, 41, 253-334 10.1016/S0360-0564(08)60042-5
62. Busch, D. H.; Yin, G.; Lee, H.-J. In Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis; Oyama, S. T., Ed.; Elsevier: Amsterdam, 2008; pp 119-153.
63. Boro, B. J.; Lansing, R.; Goldberg, K. I.; Kemp, R. A. Reaction of a Monomeric Titanium Hydride with Dioxygen does not Produce a Stable Titanium Hydroperoxide Inorg. Chem. Commun. 2011, 14, 531-533 10.1016/j.inoche.2011.01.014
64. 2 to a Vanadium(III) Trisanilide Complex To Form a Non-Vanadyl Vanadium(V) Peroxo Complex J. Am. Chem. Soc. 2012, 134, 18249-18252 10.1021/ja309621h