Glycerol electro-oxidation on bismuth-modified platinum single crystals

Journal of Catalysis

Volumn 346, Issue , 2017, Pages 117-124

  Garcia, Amanda C ^a,b   Birdja, Yuvraj Y ^a   Tremiliosi Filho, Germano ^b   Koper, Marc T M ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Bismuth; Electrocatalysis; Glycerol oxidation; Platinum; Selectivity promoter

Indexed keywords

ADATOMS; BISMUTH; CARBON MONOXIDE; ELECTROCATALYSIS; ELECTRODES; ELECTROOXIDATION; GLYCEROL; ISOMERIZATION; ISOMERS; OXIDATION; PLATINUM; REACTION INTERMEDIATES;

ADSORBED INTERMEDIATES; ENEDIOL INTERMEDIATES; GLYCEROL ELECTRO OXIDATIONS; GLYCEROL OXIDATION; ISOMERIZATION REACTION; OXIDATION OF GLYCEROL; PLATINUM SINGLE CRYSTAL; PLATINUM SINGLE CRYSTAL ELECTRODES;

SINGLE CRYSTALS;

EID: 85008602006     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2016.12.013     Document Type: Article

References (49)

1. [1] Simões, M., Baranton, S., Coutanceau, C., Electro-oxidation of glycerol at Pd based nano-catalysts for an application in alkaline fuel cells for chemicals and energy cogeneration. Appl. Catal. B Environ. 93 (2010), 354–362, 10.1016/j.apcatb.2009.10.008.
2. [2] Pagliaro, M., Ciriminna, R., Kimura, H., Rossi, M., Della Pina, C., From glycerol to value-added products. Angew. Chem. Int. Ed., 2007, 4434–4440, 10.1002/anie.200604694.
3. [3] Zhou, C.-H., Beltramini, J.N., Fan, Y.-X., Lu, G.Q., Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals. Chem. Soc. Rev. 37 (2008), 527–549, 10.1039/b707343g.
4. [4] Katryniok, B., Kimura, H., Skrzynska, E., Girardon, J-S., Fongarland, P., Capron, M., Ducoumlombier, R., Mimura, N., Paul, S., Dumeignil, F., Selective catalytic oxidation of glycerol: perspectives for high value chemicals. Green Chem. 13 (2011), 1960–1979, 10.1039/c1gc15320j.
5. [5] Kwon, Y., Birdja, Y., Spanos, I., Rodriguez, P., Koper, M.T.M., Highly selective electro-oxidation of glycerol to dihydroxyacetone on platinum in the presence of bismuth. ACS Catal. 2 (2012), 759–764, 10.1021/cs200599g.
6. [6] Garcia, A.C., Kolb, M.J., Van Nierop, C., Sanchez, Y., Vos, J., Birdja, Y.Y., Kwon, Y., et al. Strong impact of platinum surface structure on primary and secondary alcohol oxidation during electro-oxidation of glycerol. ACS Catal. 6 (2016), 4491–4500, 10.1021/acscatal.6b00709.
7. [7] Kimura, H., Selective oxidation of glycerol on a platinum-bismuth catalyst by using a fixed bed reactor. Appl. Catal. A Gen. 105 (1993), 147–158, 10.1016/0926-860X(93)80245-L.
8. [8] Demirel, S., Lehnert, K., Lucas, M., Claus, P., Use of renewables for the production of chemicals: glycerol oxidation over carbon supported gold catalysts. Appl. Catal. B Environ. 70 (2007), 637–643, 10.1016/j.apcatb.2005.11.036.
9. [9] Brandner, A., Claus, P., Platinum - Bismuth-Catalyzed Oxidation of Glycerol: Kinetics and the Origin of Selective Deactivation. J. Phys. Chem., 2010, 1164–1172.
10. [10] Painter, R.M., Pearson, D.M., Waymouth, R.M., Selective catalytic oxidation of glycerol to dihydroxyacetone. Angew. Chem. – Int. Ed. 49 (2010), 9456–9459, 10.1002/anie.201004063.
11. [11] Climent, V., Garcia-Araez, N., Feliu, J.M., Clues for the molecular level understanding of electrocatalysis on single-crystal platinum surfaces modified by p-bolck adatoms. Koper, M.T.M., (eds.) Fuel Cell Catal. A Surf. Sci. Approach, 2009, Wiley, Hoboken, New Jersey, 209–244.
12. [12] Motoo, S., Watanabe, M., Electrocatalysis by ad-atoms: part IV. Enhancement of the oxidation of formic acid on Pt-Au(subs) and Au-Pt(subs) electrodes by bismuth adatoms. J. Electroanal. Chem. Interfacial Electrochem. 98 (1979), 203–211, 10.1016/S0022-0728(79)80260-0.
13. [13] Fernandez-Vega, A., Feliu, J.M., Aldaz, A., Clavilier, J., Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsobed adatoms. Part {II}. Formic acid oxidation on the Pt(100) Bi system. J. Electroanal. Chem., 258, 1989, 101, 10.1016/0022-0728(89)87130-X.
14. [14] Clavilier, J., Feliu, J.M., Fernandez-Vega, A., Aldaz, A., Electrochemical behaviour of irreversibly adsorbed bismuth on Pt (100) with different degrees of crystalline surface order. J. Electroanal. Chem. Interfacial Electrochem. 269 (1989), 175–189, 10.1016/0022-0728(89)80111-1.
15. [15] Herrero, E., Feliu, J.M., Aldaz, A., Poison formation reaction from formic acid on Pt(100) electrodes modified by irreversibly adsorbed bismuth and antimony. J. Electroanal. Chem. 368 (1994), 101–108, 10.1016/0022-0728(93)03032-K.
16. [16] Herrero, E., Llorca, M.J., Feliu, J.M., Aldaz, A., Oxidation of formic acid on Pt(100) electrodes modified by irreversibly adsorbed tellurium. J. Electroanal. Chem. 383 (1995), 145–154, 10.1016/0022-0728(94)03721-E.
17. [17] Herrero, E., Feliu, J.M., Aldaz, A., CO adsorption and oxidation on Pt(111) electrodes modified by irreversibly adsorbed bismuth in sulfuric acid medium. J. Catal. 152 (1995), 264–274, 10.1006/jcat.1995.1081.
18. [18] Know, Y., Hersbach, T.J.P., Koper, M.T.M., Electro-oxidation of glycerol on platinum modified by adatoms: activity and selectivity effects. Top. Catal. 57 (2014), 1272–1276, 10.1007/s11244-014-0292-6.
19. [19] Kwon, Y., Schouten, K.J.P., Van Der Waal, J.C., De Jong, E., Koper, M.T.M., Electrocatalytic conversion of furanic compounds electrocatalytic conversion of furanic compounds. ACS Catal. 6 (2016), 6704–6717, 10.1021/acscatal.6b01861.
20. [20] Besson, M., Gallezot, P., Selective oxidation of alcohols and aldehydes on metal catalysts. Catal. Today 57 (2000), 127–141, 10.1016/S0920-5861(99)00315-6.
21. [21] Schmidt, T.J., Behm, R.J., Grgur, B.N., Markovic, N.M., Ross, P.N., Formic acid oxidation on pure and Bi-modified Pt(111): temperature effects. Langmuir 16 (2000), 8159–8166, 10.1021/la000339z.
22. [22] Christoffersen, E., Liu, P., Ruban, A., Skriver, H., Nørskov, J., Anode materials for low-temperature fuel cells: a density functional theory study. J. Catal. 199 (2001), 123–131, 10.1006/jcat.2000.3136.
23. [23] Lee, S., Mukerjee, S., Ticianelli, E., McBreen, J., Electrocatalysis of CO tolerance in hydrogen oxidation reaction in PEM fuel cells. Electrochim. Acta 44 (1999), 3283–3293, 10.1016/S0013-4686(99)00052-3.
24. [24] Clavilier, J., Faure, R., Guinet, G., Durand, R., Preparation of monocrystalline Pt microelectrodes and electrochemical study of the plane surfaces cut in the direction of the 111 and 110 planes. J. Electroanal. Chem. Interfacial Electrochem. 107 (1979), 205–209, 10.1016/S0022-0728(79)80022-4.
25. [25] Schmidt, T.J., Stamenkovic, V.R., Lucas, A., Nenad, M., Ross, P.N., Surface processes and electrocatalysis on the Pt (hkl)/Bi-solution interface. Phys. Chem. Chem. Phys. 3 (2001), 3879–3890, 10.1039/b102388h.
26. [26] Kwon, Y., Koper, M.T.M., Combining voltammetry with HPLC: application to electro-oxidation of glycerol. Anal. Chem. 82 (2010), 5420–5424, 10.1021/ac101058t.
27. [27] Wonders, A.H., Housmans, T.H.M., Rosca, V., Koper, M.T.M., On-line mass spectrometry system for measurements at single-crystal electrodes in hanging meniscus configuration. J. Appl. Electrochem. 36 (2006), 1215–1221, 10.1007/s10800-006-9173-4.
28. [28] Garcıa, G., Rodrıguez, P., Rosca, V., Koper, M.T.M., Fourier transform infrared spectroscopy study of CO electro-oxidation on Pt (111) in alkaline media. Langmuir 25 (2009), 13661–13666, 10.1021/la902251z.
29. [29] Rodes, A., Zamakhchari, M.A., El Achi, K., Clavilier, J., Electrochemical behaviour of Pt(100) in various acidic media. J. Electroanal. Chem. Interfacial Electrochem. 305 (1991), 115–129, 10.1016/0022-0728(91)85206-5.
30. [30] Clavilier, J., Albalat, R., Gomez, R., Orts, J.M., Feliu, J.M., Aldaz, A., Study of the charge displacement at constant potential during CO adsorption on Pt(110) and Pt(111) electrodes in contact with a perchloric acid solution. J. Electroanal. Chem. 330 (1992), 489–497, 10.1016/0022-0728(92)80326-Y.
31. [31] Huang, Y.-F., Kooyman, P.J., Koper, M.T.M., Intermediate stages of electrochemical oxidation of single-crystalline platinum revealed by in situ Raman spectroscopy. Nat. Commun., 7, 2016, 10.1038/ncomms12440.
32. [32] Clavilier, J., Feliu, J.M., Aldaz, A., An irreversible structure sensitive adsorption step in bismuth underpotential deposition at platinum electrodes. J. Electroanal. Chem. Interfacial Electrochem. 243 (1988), 419–433, 10.1016/0022-0728(88)80045-7.
33. [33] Kim, J., Rhee, C.K., Structural evolution of irreversibly adsorbed Bi on Pt(111) under potential excursion. J. Solid State Electrochem. 17 (2013), 3109–3114, 10.1007/s10008-013-2218-9.
34. [34] Fernandez-Vega, A., Feliu, J.M., Aldaz, A., Clavilier, J., Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsobed adatoms. Part {II}. Formic acid oxidation on the Pt(100) Bi system. J. Electroanal. Chem. 261 (1989), 113–125 0022-0728/89.
35. [35] Ferre-Vilaplana, A., Perales-Rondón, J.V., Feliu, J.M., Herrero, E., Understanding the effect of the adatoms in the formic acid oxidation mechanism on Pt(111) electrodes. ACS Catal. 5 (2015), 645–654, 10.1021/cs501729j.
36. [36] Cuesta, A., Couto, A., Rincón, A., Pérez, M.C., López-Cudero, A., Gutiérrez, C., Potential dependence of the saturation CO coverage of Pt electrodes: the origin of the pre-peak in CO-stripping voltammograms. Part 3: Pt(poly). J. Electroanal. Chem. 586 (2006), 184–195, 10.1016/j.jelechem.2005.10.006.
37. [37] Lebedeva, N.P., Koper, M.T.M., Feliu, J.M., Van Santen, R.A., Mechanism and kinetics of the electrochemical CO adlayer oxidation on Pt(111). J. Electroanal. Chem. 524 (2002), 242–251, 10.1016/S0022-0728(02)00669-1.
38. [38] Lebedeva, N.P., Rodes, A., Feliu, J.M., Koper, M.T.M., Van Santen, R.A., Role of crystalline defects in electrocatalysis: CO adsorption and oxidation on stepped platinum electrodes as studied by in situ infrared spectroscopy. J. Phys. Chem. B. 106 (2002), 9863–9872, 10.1021/jp0203806.
39. [39] Avramov-Ivic, M., Léger, J.-M., Beden, B., Hahn, F., Lamy, C., Adsorption of glycerol on platinum in alkaline medium: effect of the electrode structure. J. Electroanal. Chem. 351 (1993), 285–297, 10.1016/0022-0728(93)80240-I.
40. [40] Jeffery, D.Z., Camara, G.A., The formation of carbon dioxide during glycerol electrooxidation in alkaline media: first spectroscopic evidences. Electrochem. Commun. 12 (2010), 1129–1132, 10.1016/j.elecom.2010.06.001.
41. [41] Chang, S.-C., Ho, Y., Weaver, M.J., Applications of real-time infrared spectroscopy to electrocatalysis at bimetallic surfaces. I. Electrooxidation of formic acid and methanol on bismuth-modified Pt(111) and Pt(100). Surf. Sci. 265 (1992), 81–94, 10.1016/0039-6028(92)90489-S.
42. [42] Sun, S.G., Clavilier, J., Bewick, A., The mechanism of electrocatalytic oxidation of formic acid on Pt(100) and Pt(111) in sulphuric acid solution: an EMIRS study. J. Electroanal. Chem. 240 (1988), 147–159.
43. [43] Chang, S.-C., Leung, L.-W.H., Weaver, M.J., Metal crystallinity effects in electrocatalysis as probed by real-time FTIR spectroscopy: electrooxidation of formic acid, methanol, and ethanol on ordered low-index platinum surfaces. J. Phys. Chem. 94 (1990), 6013–6021, 10.1021/j100378a072.
44. [44] Bott-Neto, J.L., Garcia, A.C., Oliveira, V.L., de Souza, N.E., Tremiliosi-Filho, G., Au/C catalysts prepared by a green method towards C3 alcohol electrooxidation: a cyclic voltammetry and in situ FTIR spectroscopy study. J. Electroanal. Chem. 735 (2014), 57–62, 10.1016/j.jelechem.2014.10.010.
45. [45] Kwon, Y., Schouten, K.J.P., Koper, M.T.M., Mechanism of the catalytic oxidation of glycerol on polycrystalline gold and platinum electrodes. Chemcatchem 3 (2011), 1176–1185, 10.1002/cctc.201100023.
46. [46] Clavilier, J., Sun, S.G., Electrochemical study of the chemisorbed species formed from formic-acid dissociation at platinum single-crystal electrodes. J. Electroanal. Chem. 199 (1986), 471–480, 10.1016/0022-0728(86)80021-3.
47. [47] Nagorski, R.W., Richard, J.P., Mechanistic imperatives for aldose - Ketose isomerization in water: specific, general base- and metal ion-catalyzed isomerization of glyceraldehyde with proton and hydride transfer. J. Am. Chem. Soc. 123 (2001), 794–802, 10.1021/ja003433a.
48. [48] Cheng, L., Doubleday, C., Breslow, R., Evidence for tunneling in base-catalyzed isomerization of glyceraldehyde to dihydroxyacetone by hydride shift under formose conditions. Proc. Natl. Acad. Sci. USA 112 (2015), 4218–4220, 10.1073/pnas.1503739112.
49. [49] Yudkin, M., Offord, R., A Guidebook to Biochemistry. 1980, Cambridge University Press.