Electro-Oxidation of Glycerol on Platinum Modified by Adatoms: Activity and Selectivity Effects

Topics in Catalysis

Volumn 57, Issue 14-16, 2014, Pages 1272-1276

  Kwon, Youngkook ^a   Hersbach, Thomas J P ^a   Koper, Marc T M ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

Author keywords

Antimony; Dihydroxyacetone; Electrocatalysis; Glycerol; Platinum

Indexed keywords

EID: 84924955483     PISSN: 10225528     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11244-014-0292-6     Document Type: Article

References (25)

1. Zhou CH, Beltramini JN, Fan YX, Lu GQ (2008) Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals. Chem Soc Rev 37:527-549
2. Behr A, Eilting J, Irawadi K, Leschinski J, Lindner F (2008) Improved utilisation of renewable resources: New important derivatives of glycerol. Green Chem 10:13-30
3. Katryniok B, Kimura H, Skrzynska E, Girardon JS, Fongarland P, Capron M, Ducoulombier R, Mimura N, Paul S, Dumeignil F (2011) Selective catalytic oxidation of glycerol: perspectives for high value chemicals. Green Chem 13:1960-1979
4. Woerz N, Brandner A, Claus P (2010) Platinum-bismuth-catalyzed oxidation of glycerol: kinetics and the origin of selective deactivation. J Phys Chem C 114:1164-1172
5. Painter RM, Pearson DM, Waymouth RM (2010) Selective catalytic oxidation of glycerol to dihydroxyacetone. Angew Chem Int Ed 49:9456-9459
6. Simoes M, Baranton S, Coutanceau C (2012) Electrochemical valorisation of glycerol. ChemSusChem 5:2106-2124
7. Svitel J, Sturdik E (1994) Product yield and by-product formation in glycerol conversion to dihydroxyacetone by gluconobacter-oxydans. J Ferment Bioeng 78:351-355
8. Carrettin S, McMorn P, Johnston P, Griffin K, Kiely CJ, Hutchings GJ (2003) Oxidation of glycerol using supported Pt, Pd and Au catalysts. Phys Chem Chem Phys 5:1329-1336
9. Demirel S, Lehnert K, Lucas M, Claus P (2007) Use of renewables for the production of chemicals: glycerol oxidation over carbon supported gold catalysts. Appl Catal B 70:637-643
10. Hu W, Knight D, Lowry B, Varma A (2010) Selective oxidation of glycerol to dihydroxyacetone over Pt-Bi/C catalyst: optimization of catalyst and reaction conditions. Ind Eng Chem Res 49:10876-10882
11. Kimura H (1993) Selective oxidation of glycerol on a platinum-bismuth catalyst by using a fixed-bed reactor. Appl Catal A 105:147-158
12. Kimura H, Tsuto K, Wakisaka T, Kazumi Y, Inaya Y (1993) Selective oxidation of glycerol on a platinum bismuth catalyst. Appl Catal A 96:217-228
13. Xin L, Zhang Z, Wang Z, Li W (2012) Simultaneous generation of mesoxalic acid and electricity from glycerol on a gold anode catalyst in anion-exchange membrane fuel cells. ChemCatChem 4:1105-1114
14. Zhang Z, Xin L, Li W (2012) Electrocatalytic oxidation of glycerol on Pt/C in anion-exchange membrane fuel cell: cogeneration of electricity and valuable chemicals. Appl Catal B 119:40-48
15. Zhang Z, Xin L, Qi J, Chadderdon DJ, Li W (2013) Supported Pt, Pd and Au nanoparticle anode catalysts for anion-exchange membrane fuel cells with glycerol and crude glycerol fuels. Appl Catal B 136:29-39
16. Zhang Z, Xin L, Qi J, Wang Z, Li W (2012) Selective electro-conversion of glycerol to glycolate on carbon nanotube supported gold catalyst. Green Chem 14:2150-2152
17. Gomes JF, Gasparotto LHS, Tremiliosi-Filho G (2013) Glycerol electro-oxidation over glassy-carbon-supported Au nanoparticles: direct influence of the carbon support on the electrode catalytic activity. Phys Chem Chem Phys 15:10339-10349
18. Gomes JF, Martins CA, Janete Giz M, Tremiliosi-Filho G, Camara GA (2013) Insights into the adsorption and electro-oxidation of glycerol: self-inhibition and concentration effects. J Catal 301:154-161
19. Kwon Y, Birdja Y, Spanos I, Rodriguez P, Koper MTM (2012) Highly selective electro-oxidation of glycerol to dihydroxyacetone on platinum in the presence of bismuth. ACS Catal 2:759-764
20. Kwon Y, Schouten KJP, Koper MTM (2011) Mechanism of the catalytic oxidation of glycerol on polycrystalline gold and platinum electrodes. ChemCatChem 3:1176-1185
21. Kwon Y, Koper MTM (2010) Combining voltammetry with HPLC: application to electro-oxidation of glycerol. Anal Chem 82:5420-5424
22. Rodriguez P, Solla-Gullon J, Vidal-Iglesias FJ, Herrero E, Aldaz A, Feliu JM (2005) Determination of (111) ordered domains on platinum electrodes by irreversible adsorption of bismuth. Anal Chem 77:5317-5323
23. Kwon Y, Raaijman SJ, Koper MTM (2014) Role of peroxide in the catalytic activity of gold for oxidation reactions in aqueous media: an electrochemical study. ChemCatChem 6:79-81. doi: 10.1002/cctc.201300460
24. Climent V, Herrero E, Feliu JM (1998) Electrocatalysis of formic acid and CO oxidation on antimony-modified Pt(111) electrodes. Electrochim Acta 44:1403-1414
25. Herrero E, Feliu JM, Aldaz A (1994) Poison formation reaction from formic acid on Pt(100) electrodes modified by irreversibly adsorbed bismuth and antimony. J Electroanal Chem 368:101-108