Hexafluorophosphate anion intercalation into graphite electrode from methyl propionate

Solid State Ionics

Volumn 300, Issue , 2017, Pages 169-174

  Fan, Hui ^a,b   Qi, Li ^a   Wang, Hongyu ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Dual ion cells; Graphite intercalation compounds; Hexafluorophosphate anion; Methyl propionate; Solvation co intercalation

Indexed keywords

ELECTROCHEMICAL ELECTRODES; ELECTRODES; GRAPHITE; INFRARED SPECTROSCOPY; INTERCALATION; INTERCALATION COMPOUNDS; IONS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLVATION; TEMPERATURE; X RAY DIFFRACTION;

CO-INTERCALATION; ELECTROCHEMICAL INTERCALATIONS; ELECTROCHEMICAL TECHNIQUES; ETHYL METHYL CARBONATE; HEXAFLUOROPHOSPHATES; IN-SITU RAMAN SPECTROSCOPY; METHYL PROPIONATES; REVERSIBLE SPECIFIC CAPACITY;

GRAPHITE ELECTRODES;

EID: 85007549072     PISSN: 01672738     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ssi.2016.12.032     Document Type: Article

References (27)

1. 6 into graphite. J. Electrochem. Soc. 147 (2000), 892–898.
2. [2] Xu, K., Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem. Rev. 104 (2004), 4303–4418.
3. [3] Xu, K., von Cresce, A., Interfacing electrolytes with electrodes in Li ion batteries. J. Mater. Chem. 21 (2011), 9849–9864.
4. − intercalation into graphite by small amounts of ethylene carbonate in activated carbon/graphite capacitors. Chem. Commun. 46 (2010), 1544–1546.
5. − intercalation behaviour at high potentials. Carbon 47 (2009), 2727–2732.
6. 6 in dimethyl carbonate (DMC) electrolyte. J. Electrochem. Soc. 163 (2016), A1206–A1213.
7. [7] Read, J.A., Cresce, A.V., Ervin, M.H., Xu, K., Dual-graphite chemistry enabled by a high voltage electrolyte. Energy Environ. Sci. 7 (2014), 617–620.
8. [8] Read, J.A., In-situ studies on the electrochemical intercalation of hexafluorophosphate anion in graphite with selective cointercalation of solvent. J. Phys. Chem. C 119 (2015), 8438–8446.
9. [9] Fan, H., Gao, J., Qi, L., Wang, H., Hexafluorophosphate anion intercalation into graphite electrode from sulfolane/ethylmethyl carbonate solutions. Electrochim. Acta 189 (2016), 9–15.
10. [10] Petibon, R., Harlow, J., Le, D.B., Dahn, J.R., The use of ethyl acetate and methyl propanoate in combination with vinylene carbonate as ethylene carbonate-free solvent blends for electrolytes in Li-ion batteries. Electrochim. Acta 154 (2015), 227–234.
11. [11] Petibon, R., Aiken, C.P., Ma, L., Xiong, D., Dahn, J.R., The use of ethyl acetate as a sole solvent in highly concentrated electrolyte for Li-ion batteries. Electrochim. Acta 154 (2015), 287–293.
12. [12] Petibon, R., Li, J., Sharma, N., Pang, W.K., Peterson, V.K., Dahn, J.R., The use of deuterated ethyl acetate in highly concentrated electrolyte as a low-cost solvent for in situ neutron diffraction measurements of Li-ion battery electrodes. Electrochim. Acta 174 (2015), 417–423.
13. [13] McEwen, A.B., McDevitt, S.F., Koch, V.R., Nonaqueous electrolytes for electrochemical capacitors: imidazolium cations and inorganic fluorides with organic carbonates. J. Electrochem. Soc. 144 (1997), L84–L86.
14. [14] Sastry, N.V., George, A., Jain, N.J., Bahadur, P., Densities, relative permittivities, excess volumes, and excess molar polarizations for alkyl ester (methyl propanoate, methyl butanoate, ethyl propanoate, and ethyl butanoate) + hydrocarbons (n-heptane, benzene, chlorobenzene, and 1,1,2,2-tetrachloroethane) at 308.15 K and 318.15 K. J. Chem. Eng. Data 44 (1999), 456–464.
15. [15] Besenhard, J.O., Fritz, H.P., The electrochemistry of black carbons. Angew. Chem. Int. Ed. Engl. 22 (1983), 950–975.
16. [16] Fromm, O., Meister, P., Qi, X., Rothermel, S., Huesker, J., Meyer, H.-W., Winter, M., Placke, T., Study of the electrochemical intercalation of different anions from non-aqueous electrolytes into a graphite-based cathode. ECS Trans. 58 (2014), 55–65.
17. [17] Solin, S.A., Caswell, N., Raman scattering from alkali graphite intercalation compounds. J. Raman Spectrosc. 10 (1981), 129–135.
18. [18] Alsmeyer, D.C., McCreery, R.L., In situ Raman monitoring of electrochemical graphite intercalation and lattice damage in mild aqueous acids. Anal. Chem. 64 (1992), 1528–1533.
19. [19] Zhang, X., Sukpirom, N., Lerner, M.M., Graphite intercalation of bis(trifluoro- methanesulfonyl)imide and other anions with perflouroalkanesulfonyl substituents. Mater. Res. Bull. 34 (1999), 363–372.
20. [20] Schroder, K.W., Dylla, A.G., Bishop, L.D.C., Kamilar, E.R., Saunders, J., Webb, L.J., Stevenson, K.J., Effects of solute-solvent hydrogen bonding on nonaqueous electrolyte structure. J. Phys. Chem. Lett. 6 (2015), 2888–2891.
21. [21] von W. Cresce, A., Gobet, M., Borodin, O., Peng, J., Russell, S.M., Wikner, E., Fu, A., Hu, L., Lee, H., Zhang, Z., Yang, X., Greenbaum, S., Amine, K., Xu, K., Anion solvation in carbonate-based electrolytes. J. Phys. Chem. C 119 (2015), 27255–27264.
22. [22] Erkabaev, A.M., Yaroslavtseva, T.V., Popov, S.E., Bushkova, O.V., IR spectroscopic and quantum-chemical investigation of perchlorate anion solvation in acetonitrile, Russian. J. Phys. Chem. A 89 (2015), 76–81.
23. 1 < n < 3. Chem. Phys. 310 (2005), 77–84.
24. [24] Gu, Y., Kar, T., Scheiner, S., Fundamental properties of the CH ⋯ O interaction: is it a true hydrogen bond?. J. Am. Chem. Soc. 121 (1999), 9411–9422.
25. [25] Gu, Y., Kar, T., Scheiner, S., Comparison of the CH ⋯ N and CH ⋯ O interactions involving substituted alkanes. J. Mol. Struct. 552 (2000), 17–31.
26. [26] Sivaraman, B., Nair, B.G., Lo, J.-I., Kundu, S., Davis, D., Prabhudesai, V., Sekhar, B.N.R., Mason, N.J., Cheng, B.-M., Krishnakumar, E., Vacuum ultraviolet and infrared spectra of condensed methyl acetate on cold astrochemical dust analogs. Astrophys. J. 778 (2013), 157–161.
27. [27] Joseph, J., Jemmis, E.D., Red-, blue-, or no-shift in hydrogen bonds: a unified explanation. J. Am. Chem. Soc. 129 (2007), 4620–4632.