Reactivity of stabilized Criegee intermediates (sCIs) from isoprene and monoterpene ozonolysis toward SO2 and organic acids

Atmospheric Chemistry and Physics

Volumn 14, Issue 22, 2014, Pages 12143-12153

  Sipila M ^a   Jokinen, T ^a,b   Berndt, T ^b   Richters, S ^b   Makkonen, R ^a,c   Donahue, N M ^d   Mauldin, R L ^a,e   Kurten T ^a   Paasonen, P ^a   Sarnela, N ^a   Ehn, M ^a   Junninen, H ^a   Rissanen, M P ^a   Thornton, J ^a   Stratmann, F ^b   Herrmann, H ^a,f,g   Worsnop, D R ^a   Kulmala, M ^a   Kerminen, V M ^a   Petaja T ^a  

^a UNIVERSITY OF HELSINKI   (Finland)

^b LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

^c UNIVERSITY OF OSLO   (Norway)

^d CARNEGIE MELLON UNIVERSITY   (United States)

^e UNIVERSITY OF COLORADO   (United States)

^f UNIVERSITY OF EASTERN FINLAND   (Finland)

^g AERODYNE RESEARCH INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; ATMOSPHERIC PRESSURE; ISOPRENE; MONOTERPENE; ORGANIC ACID; SULFUR DIOXIDE; SULFURIC ACID;

EID: 85006985210     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-14-12143-2014     Document Type: Article

References (46)

1. Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmosph. Env., 34, 2063-2101, 2000
2. Berndt, T., Böge, O., Stratmann, F., Heintzenberg, J., and Kulmala, M.: Rapid Formation of Sulfuric Acid Particles at Near- Atmospheric Conditions, Science, 307, 698-700, 2005
3. Berndt, T., Jokinen, T., Mauldin III, R. L., Petäjä, T., Herrmann, H., Junninen, H., Paasonen, P., Worsnop, D. R., and Sipilä, M.: Gas- Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO2, J. Phys. Chem. Lett. 3, 2892-2896, 2012
4. Berndt, T., Jokinen, T., Sipilä, M, Mauldin, III, R. L., Herrmann, H., Stratmann, F., Junninen, H., and Kulmala, M.: H2SO4 formation from the gas-phase reaction of stabilized Criegee Intermediates with SO2: Influence of water vapour content and temperature, Atmos. Environ., 89, 603-612, 2014a.
5. Berndt, T., Voigtländer, J., Stratmann, F., Junninen, H., Mauldin III, R. L., Sipilä, M., Kulmala, M., and Herrmann, H.: Competing atmospheric reactions of CH2OO with SO2 and water vapour, Phys. Chem. Chem. Phys., 16, 19130-19136, doi:10.1039/c4cp02345e, 2014b.
6. Boy, M., Mogensen, D., Smolander, S., Zhou, L., Nieminen, T., Paasonen, P., Plass-Dülmer, C., Sipilä, M., Petäjä, T., Mauldin, L., Berresheim, H., and Kulmala, M.: Oxidation of SO2 by stabilized Criegee intermediate (sCI) radicals as a crucial source for atmospheric sulfuric acid concentrations, Atmos. Chem. Phys., 13, 3865-3879, doi:10.5194/acp-13-3865-2013, 2013
7. Calvert, J. G., Atkinson, R., Kerr, J. A., Madronich, S., Moortgat, G. K., Wallington, T. J., and Yarwood, G.: The Mechanism of Atmospheric Oxidation of the Alkenes, Oxford University Press, New York, USA, 552 pp., 2000
8. Criegee, R., Mechanism of Ozonolysis, Angew. Chem., Int. Ed., 14, 745 - 752, 1975
9. DeMore, W. B., Sander, S. P., Golden, D. M., Hampson, R. F., Kurylo, M. J., Howard, C. J., Ravishankara, A. R., Kolb, C. E., and Molina, M. J.: Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling, Evaluation Number 12, Jet Propulsion Laboratory (JPL) Publication 97-4, Pasadena, California, 1997
10. Di Carlo, P., Brune, W. H., Martinez, M., Harder, H., Lesher, R., Ren, X., Thornberry, T., Carroll, M. A., Young, V., Shepson, P. B., Riemer, D., Apel, E., and Campbell, C.: Missing OH reactivity in a forest: Evidence for unknown reactive biogenic VOCs, Science, 304, 722-724, 2004
11. Drozd, G. T. and Donahue, N. M.: Pressure Dependence of Stabilized Criegee Intermediate Formation from a Sequence of Alkenes. J. Phys. Chem. A, 115, 4381-4387, 2011
12. Ehn, M., Thornton, J. A., Kleist, E., Sipilä, M., Junninen, H., Pullinen, I., Springer, M., Rubach, F., Tillmann, R., Lee, B., Lopez- Hilfiker, F., Andres, S., Acir, I.-H., Rissanen, M., Jokinen, T., Schobesberger, S., Kangasluoma, J., Kontkanen, J., Nieminen, T., Kurtén, T., Nielsen, L. B., Jørgensen, S., Kjaergaard, H. G., Canagaratna, M., Dal Maso, M., Berndt, T., Petäjä, T., Wahner, A., Kerminen, V., Kulmala, M., Worsnop, D. R., Wildt, J, and Mentel, T. F.: A large source of low-volatility secondary organic aerosol, Nature, 506, 476-479, doi:10.1038/nature13032, 2014
13. Eisele, F. L. and Tanner, D. J.: Measurement of the gas phase concentration of H2SO4 and methane sulfonic acid and estimates of H2SO4 production and loss in the atmosphere, J. Geophys. Res. 98, 9001-9010, 1993
14. Fenske, J. D., Hasson, A. S., Ho, A. W., and Paulson, S. E.: Measurement of absolute unimolecular and bimolecular rate constants for CH3CHOO generated by the trans-2-butene reaction with ozone in the gas phase, J. Phys. Chem. A, 104, 9921-9932, 2000
15. Hasson, A. S., Orzechowska, G., and Paulson, S. E.: Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes 1. Ethene, trans-2-butene, and 2,3- dimethyl-2-butene, J. Geophys. Res., 106, 34131-34142, 2001a
16. Hasson, A. S., Ho, A.W., Kuwata, K. T., and Paulson, S. E.: Production of stabilized criegee intermediates and peroxides in the gas phase ozonolysis of alkenes 2. Asymmetric and biogenic alkenes, J. Geophys. Res., 106, 34143-34153, 2001b
17. Hasson, A., Chung, M., Kuwata, K., Converse, A., Krohn, D., and Paulson, S.: Reaction of Criegee intermediates with water vapor - An additional source of OH radicals in alkene ozonolysis?, J. Phys. Chem. A, 107, 6176-6182, 2003
18. Hofzumahaus, A., Rohrer, F. Lu, K., Bohn, B., Brauers, T., Chang, C-C., Fuchs, H., Holland, F., Kita, K., Kondo, Y., Li, X., Lou, S., Shao, M., Zeng, L., Wahner, A., and Zhang, Y. Amplified Trace Gas Removal in the Troposphere, Science, 324, 1702-1704, 2009
19. Johnson, D., Lewin, A. G., and Marston, G.: The Effect of Criegee- Intermediate Scavengers on the OH Yield from the Reaction of Ozone with 2-Methyl-2-butene., J. Phys. Chem. A, 105, 2933-2935, 2001
20. Jokinen, T., Sipilä, M., Junninen, H., Ehn, M., Lönn, G., Hakala, J., Petäjä, T., Mauldin III, R. L., Kulmala, M., and Worsnop, D. R.: Atmospheric sulphuric acid and neutral cluster measurements using CI-APi-TOF, Atmos. Chem. Phys., 12, 4117-4125, doi:10.5194/acp-12-4117-2012, 2012
21. Junninen, H., Ehn, M., Petäja, T., Luosujärvi, L., Kotiaho, T., Kostiainen, R., Rohner, U., Gonin, M., Fuhrer, K., Kulmala, M., and Worsnop, D. R.: A high-resolution mass spectrometer to measure atmospheric ion composition, Atmos. Meas. Tech., 3, 1039-1053, doi:10.5194/amt-3-1039-2010, 2010
22. Kerminen, V.-M., Petäjä, T., Manninen, H. E., Paasonen, P., Nieminen, T., Sipilä, M., Junninen, H., Ehn, M., Gagné, S., Laakso, L., Riipinen, I., Vehkamäki, H., Kurtén, T., Ortega, I. K., Dal Maso, M., Brus, D., Hyvärinen, A., Lihavainen, H., Leppä, J., Lehtinen, K. E. J., Mirme, A., Mirme, S., Hrrak, U., Berndt, T., Stratmann, F., Birmili, W., Wiedensohler, A., Metzger, A., Dommen, J., Baltensperger, U., Kiendler-Scharr, A., Mentel, T. F., Wildt, J.,Winkler, P. M., Wagner, P. E., Petzold, A., Minikin, A., Plass-Dülmer, C., Pöschl, U., Laaksonen, A., and Kulmala, M.: Atmospheric nucleation: Highlights of the EUCAARI project and future directions, Atmos. Chem. Phys., 10, 10829-10848, doi:10.5194/acp-10-10829-2010, 2010
23. Kroll, J. H., Sahay, S. R., Anderson, J. G., Demerjian, K. L., and Donahue, N. M.: Mechanism of HOx formation in the gas-phase ozone-alkene reaction. 2. Prompt versus thermal dissociation of carbonyl oxides to form OH, J. Phys. Chem. A, 105, 4446-4457, 2001
24. Kulmala, M., Toivonen, A., Mäkelä, J. M., and Laaksonen, A.: Analysis of the growth of nucleation mode particles observed in Boreal forest, Tellus, 50B, 449-462, 1998
25. Kulmala, M., Vehkamäki, H., Petäjä, T., Dal Maso, M., Lauri, A., Kerminen, V.-M., Birmili, W., and McMurry, P. H.: Formation and growth rates of ultrafine atmospheric particles: A review of observations. J. Aerosol Sci., 35, 143-176, 2004
26. Kurtén, T., Lane, J. R., Jørgensen, S., and Kjaergaard, H. G.: A computational study of the oxidation of SO2 to SO3 by gas-phase organic oxidants, J. Phys. Chem. A, 115, 8669-8681, 2011
27. Lelieveld, J., Butler, T. M., Crowley, J. N., Dillon, T. J., Fischer, H., Ganzeveld, L., Harder, H., Lawrence, M. G., Martinez, M., Taraborrelli, D., and Williams, J.: Atmospheric oxidation capacity sustained by a tropical forest, Nature, 452, 737-740, 2008
28. Lindinger, W., Hansel, A., and Jordan, A.: On-line monitoring of volatile organic compounds at ppt levels by means of Proton- Transfer Reaction Mass Spectrometry (PTR-MS) Medical application, food control and environmental research, Int. J. Mass Spectrom. Ion Proc., 173, 191-241, 1998
29. Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C.C., Fuchs, H., Häseler, R., Kita, K., Kondo, Y., Li, X., Shao, M., Zeng, L., Wahner, A., Zhang, Y., Wang, W., and Hofzumahaus, A.: Atmospheric OH reactivities in the Pearl River Delta - China in summer 2006: Measurement and model results, Atmos. Chem. Phys., 10, 11243-11260, doi:10.5194/acp-10-11243-2010, 2010
30. Mauldin III, R. L., Berndt, T., Sipilä, M., Paasonen, P., Petäjä, T., Kim, S., Kurtén, T., Stratmann, F., Kerminen, V.-M., and Kulmala, M.: A new atmospherically relevant oxidant, Nature, 488, 193-196, doi:10.1038/nature11278, 2012
31. Neeb, P., Horie, O., and Moortgat, G. K.: The nature of the transitory product in the gas-phase ozonolysis of ethene, Chem. Phys. Lett., 246, 150-156, 1995.
32. Neeb, P., Horie, O., and Moortgat, G. K.: Gas-phase ozonolysis of ethene in the presence of hydroxylic compounds, Int. J. Chem. Kinet., 28, 721-730, 1996
33. Neeb, P., Sauer, F., Horie, O., and Moortgat, G. K.: Formation of hydroxymethyl hydroperoxide and formic acid in alkene ozonolysis in the presence of water vapour, Atmos. Environ., 31, 1417-1423 1997
34. Nölscher, A. C., Williams, J., Sinha, V., Custer, T., Song, W., Johnson, A. M., Axinte, R., Bozem, H., Fischer, H., Pouvesle, N., Phillips, G., Crowley, J. N., Rantala, P., Rinne, J., Kulmala, M., Gonzales, D., Valverde-Canossa, J., Vogel, A., Hoffmann, T., Ouwesloot, H. G., Vila-Guerau de Arellano, J., and Lelieveld, J.: Summertime total OH reactivity measurements from boreal forest during HUMPPA-COPEC 2010, Atmos. Chem. Phys., 12, 8257-8270, doi:10.5194/acp-12-8257-2012, 2012
35. Petäjä, T., Mauldin, III, R. L., Kosciuch, E., McGrath, J., Nieminen, T., Paasonen, P., Boy, M., Adamov, A., Kotiaho, T., and Kulmala, M.: Sulfuric acid and OH concentrations in a boreal forest site, Atmos. Chem. Phys., 9, 7435-7448, doi:10.5194/acp- 9-7435-2009, 2009
36. Pierce, J. R., Evans, M. J., Scott, C. E., D'Andrea, S. D., Farmer, D. K., Swietlicki, E., and Spracklen, D. V.: Weak global sensitivity of cloud condensation nuclei and the aerosol indirect effect to CriegeeCSO2 chemistry, Atmos. Chem. Phys., 13, 3163-3176, doi:10.5194/acp-13-3163-2013, 2013
37. Riipinen, I., Sihto, S.-L., Kulmala, M., Arnold, F., Dal Maso, M., Birmili, W., Saarnio, K., Teinilä, K., Kerminen, V.-M., Laaksonen, A., and Lehtinen, K. E. J.: Connections between atmospheric sulphuric acid and new particle formation during QUEST III-IV campaigns in Heidelberg and Hyytiälä, Atmos. Chem. Phys., 7, 1899-1914, doi:10.5194/acp-7-1899-2007, 2007
38. Riipinen, I., Pierce, J. R., Yli-Juuti, T., Nieminen, T., Häkkinen, S., Ehn, M., Junninen, H., Lehtipalo, K., Petäjä, T., Slowik, J., Chang, R., Shantz, N. C., Abbatt, J., Leaitch, W. R., Kerminen, V.-M., Worsnop, D. R., Pandis, S. N., Donahue, N. M., and Kulmala, M.: Organic condensation: A vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations, Atmos. Chem. Phys., 11, 3865-3878, doi:10.5194/acp-11-3865- 2011, 2011
39. Sipilä, M., Berndt, T., Petäjä, T., Brus, D., Vanhanen, J., Stratmann, F., Patokoski, J., Mauldin, R. L., Hyvärinen, A.-P., Lihavainen, H., and Kulmala, M.: The role of sulfuric acid in atmospheric nucleation, Science, 327, 1243-1246, 2010
40. Taatjes, C. A., Welz O., Eskola, A. J., Savee, J. D., Osborn, D. L., Lee, E. P., Dyke, J. M., Mok, D. W., Shallcross, D. E., and Percival, C. J.: Direct measurement of Criegee intermediate (CH2OO) reactions with acetone, acetaldehyde, and hexafluoroacetone, Phys. Chem. Chem. Phys., 14, 10391-10400, 2012
41. Taatjes, C. A., Welz, O., Eskola, A. J., Savee, J. D., Scheer, A. M., Shallcross, D. E., Rotavera, B., Lee, E. P. F., Dyke, J. M., Mok, D. K. W., Osborn, D. L., and Percival, C. J.: Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO, Science, 340, 177-180, 2013
42. Taraborrelli, D., Lawrence, M. G., Crowley, J. N., Dillon, T. J., Gromov, S., Groß, C., Vereecken, L., and Lelieveld, J.: Hydroxyl radical buffered by isoprene oxidation over tropical forests, Nature Geosci., 5, 190-193, 2012
43. Thamm, J., Wolff, S., Turner, W. V., Gäb, S., Thomas, W., Zabel, F., Fink, E. H., and Becker, K. H.: Proof of the formation of hydroperoxymethyl formate in the ozonolysis of ethene: Synthesis and ft-ir spectra of the authentic compound, Chem. Phys. Lett., 258, 155-158, 1996
44. Vereecken, L., Harder, H., and Novelli, A.: The reaction of Criegee intermediates with NO, RO2, and SO2, and their fate in the atmosphere, Phys. Chem. Chem. Phys., 14, 14682-14695, 2012
45. Welz, O., Savee, J. D., Osborn, D. L., Vasu, S. S., Percival, C. J., Shallcross, D. E., and Taatjes, C. A.: Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2, Science, 335, 204-207, doi:10.1126/science.1213229, 2012
46. Welz, O., Eskola, A. J., Sheps, L., Rotavera, B., Savee, J. D., Scheer, A. M., Osborn, D. L., Lowe, D., Murray Booth, A., Xiao, P., Anwar H., Khan, M., Percival, C. J., Shallcross, D. E., and Taatjes, C. A.: Rate coefficients of C(1) and C(2) Criegee intermediate reactions with formic and acetic Acid near the collision limit: Direct kinetics measurements and atmospheric implications, Angew. Chem. Int. Ed. Engl., 53, 4547-4750. doi:10.1002/anie.201400964, 2014