Core@Double-Shell Structured Nanocomposites: A Route to High Dielectric Constant and Low Loss Material

ACS Applied Materials and Interfaces

Volumn 8, Issue 38, 2016, Pages 25496-25507

  Huang, Yanhui ^a,b   Huang, Xingyi ^a   Schadler, Linda S ^b   He, Jinliang ^c   Jiang, Pingkai ^a  

^a SHANGHAI JIAO TONG UNIVERSITY   (China)

^b RENSSELAER POLYTECHNIC INSTITUTE   (United States)

^c TSINGHUA UNIVERSITY   (China)

Author keywords

ATRP; BaTiO3; core@double shell; high dielectric constant; low loss; nanocomposites

Indexed keywords

ACRYLIC MONOMERS; ATOM TRANSFER RADICAL POLYMERIZATION; BARIUM COMPOUNDS; BLOCK COPOLYMERS; DIELECTRIC LOSSES; DIELECTRIC PROPERTIES; DIELECTRIC PROPERTIES OF SOLIDS; ESTERS; FINITE ELEMENT METHOD; FREE RADICAL POLYMERIZATION; FREE RADICAL REACTIONS; GRAFTING (CHEMICAL); NANOCOMPOSITES; NANOSTRUCTURES; POLYACRYLATES; SHELLS (STRUCTURES); TRANSFER MATRIX METHOD;

BATIO; DOUBLE SHELLS; ELECTRICAL ENERGY STORAGES; HIGH DIELECTRIC CONSTANTS; HIGH ELECTRICAL CONDUCTIVITY; LOW-LOSS; POLYMER NANOCOMPOSITE; SURFACE INITIATED-ATOM TRANSFER RADICAL POLYMERIZATION;

POLYMER MATRIX COMPOSITES;

EID: 84989177898     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.6b06650     Document Type: Article

References (43)

1. 3 and a Ferroelectric Polymer ACS Nano 2009, 3 (9) 2581-2592 10.1021/nn9006412
2. 3 Hybrid Nanodielectrics Prepared by in Situ Raft Polymerization: A Route to High Dielectric Constant and Low Loss Materials with Weak Frequency Dependence Macromol. Rapid Commun. 2012, 33 (22) 1921-1926 10.1002/marc.201200361
3. Arbatti, M.; Shan, X.; Cheng, Z. Y. Ceramic-Polymer Composites with High Dielectric Constant Adv. Mater. 2007, 19 (10) 1369-1372 10.1002/adma.200601996
4. Calebrese, C.; Hui, L.; Schadler, L. S.; Nelson, J. K. A Review on the Importance of Nanocomposite Processing to Enhance Electrical Insulation IEEE Trans. Dielectr. Electr. Insul. 2011, 18 (4) 938-945 10.1109/TDEI.2011.5976079
5. Kremer, F.; Schönhals, A. Broadband Dielectric Spectroscopy; Springer: Berlin Heidelberg, 2003; pp 81.
6. Natarajan, B.; Li, Y.; Deng, H.; Brinson, L. C.; Schadler, L. S. Effect of Interfacial Energetics on Dispersion and Glass Transition Temperature in Polymer Nanocomposites Macromolecules 2013, 46 (7) 2833-2841 10.1021/ma302281b
7. Kim, P.; Jones, S. C.; Hotchkiss, P. J.; Haddock, J. N.; Kippelen, B.; Marder, S. R.; Perry, J. W. Phosphonic Acid-Modified Barium Titanate Polymer Nanocomposites with High Permittivity and Dielectric Strength Adv. Mater. 2007, 19 (7) 1001-1005 10.1002/adma.200602422
8. Li, Y.; Tao, P.; Viswanath, A.; Benicewicz, B. C.; Schadler, L. S. Bimodal Surface Ligand Engineering: The Key to Tunable Nanocomposites Langmuir 2013, 29 (4) 1211-1220 10.1021/la3036192
9. 2/Silicone Nanocomposites with Improved Dielectric Properties, Electrical Insulation Conference (EIC), Seattle, USA; IEEE, 2015; pp 325-328.
10. 3 Hybrid Nanoparticles Prepared via Raft Polymerization: Toward Ferroelectric Polymer Nanocomposites with High Dielectric Constant and Low Dielectric Loss for Energy Storage Application Chem. Mater. 2013, 25 (11) 2327-2338 10.1021/cm4010486
11. Qiao, Y.; Yin, X.; Wang, L.; Islam, M. S.; Benicewicz, B. C.; Ploehn, H. J.; Tang, C. Bimodal Polymer Brush Core-Shell Barium Titanate Nanoparticles: A Strategy for High-Permittivity Polymer Nanocomposites Macromolecules 2015, 48 (24) 8998-9006 10.1021/acs.macromol.5b02018
12. Wang, J.; Guan, F.; Cui, L.; Pan, J.; Wang, Q.; Zhu, L. Achieving High Electric Energy Storage in a Polymer Nanocomposite at Low Filling Ratios Using a Highly Polarizable Phthalocyanine Interphase J. Polym. Sci., Part B: Polym. Phys. 2014, 52 (24) 1669-1680 10.1002/polb.23554
13. 3 Nanoparticles: Understanding the Role of Polymer Shells in the Interfacial Regions ACS Appl. Mater. Interfaces 2014, 6 (22) 19644-19654 10.1021/am504428u
14. 3 Nanocomposites Prepared by in Situ Atom Transfer Radical Polymerization: A Route to High Dielectric Constant Materials with the Inherent Low Loss of the Base Polymer J. Mater. Chem. 2011, 21 (16) 5897-5906 10.1039/c0jm04574h
15. Huang, X. Y.; Jiang, P. K. Core-Shell Structured High-K Polymer Nanocomposites for Energy Storage and Dielectric Applications Adv. Mater. 2015, 27 (3) 546-554 10.1002/adma.201401310
16. Nalwa, H. S. Ferroelectric Polymers: Chemistry: Physics, and Applications; CRC Press: New York, 1995; pp 1-69.
17. Hardy, C. G.; Islam, M. S.; Gonzalez-Delozier, D.; Morgan, J. E.; Cash, B.; Benicewicz, B. C.; Ploehn, H. J.; Tang, C. Converting an Electrical Insulator into a Dielectric Capacitor: End-Capping Polystyrene with Oligoaniline Chem. Mater. 2013, 25 (5) 799-807 10.1021/cm304057f
18. 3-Polymer Nanocomposites with High Dielectric Constant and Low Dielectric Loss for Energy Storage Application J. Phys. Chem. C 2013, 117 (44) 22525-22537 10.1021/jp407340n
19. 3-Based Ceramics for Mlcc Application RSC Adv. 2015, 5 (12) 8868-8876 10.1039/C4RA13367F
20. 3 Perovskite Solid Solutions J. Am. Ceram. Soc. 2011, 94 (10) 3412-3417 10.1111/j.1551-2916.2011.04519.x
21. Matyjaszewski, K. Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives Macromolecules 2012, 45 (10) 4015-4039 10.1021/ma3001719
22. Li, D.; Cui, Y.; Wang, K.; He, Q.; Yan, X.; Li, J. Thermosensitive Nanostructures Comprising Gold Nanoparticles Grafted with Block Copolymers Adv. Funct. Mater. 2007, 17 (16) 3134-3140 10.1002/adfm.200700427
23. Kim, J.-B.; Huang, W.; Bruening, M. L.; Baker, G. L. Synthesis of Triblock Copolymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization Macromolecules 2002, 35 (14) 5410-5416 10.1021/ma011736z
24. Arlt, G.; Hennings, D.; de With, G. Dielectric Properties of Fine-Grained Barium Titanate Ceramics J. Appl. Phys. 1985, 58 (4) 1619-1625 10.1063/1.336051
25. Huang, Y. H.; Krentz, T. M.; Nelson, J. K.; Schadler, L. S.; Li, Y.; Zhao, H.; Brinson, L. C.; Bell, M.; Benicewicz, B.; Wu, K.; Breneman, C. M. In Prediction of Interface Dielectric Relaxations in Bimodal Brush Functionalized Epoxy Nanodielectrics by Finite Element Analysis Method, IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP), 2014 Des Moines, USA; IEEE, 2014; pp 748-751.
26. Heywang, W. Resistivity Anomaly in Doped Barium Titanate J. Am. Ceram. Soc. 1964, 47 (10) 484-490 10.1111/j.1151-2916.1964.tb13795.x
27. Wang, X.-S.; Jackson, R.; Armes, S. Facile Synthesis of Acidic Copolymers via Atom Transfer Radical Polymerization in Aqueous Media at Ambient Temperature Macromolecules 2000, 33 (2) 255-257 10.1021/ma991612a
28. Tang, W.; Kwak, Y.; Braunecker, W.; Tsarevsky, N. V.; Coote, M. L.; Matyjaszewski, K. Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants J. Am. Chem. Soc. 2008, 130 (32) 10702-10713 10.1021/ja802290a
29. 2 Nanoparticles Via Surface Thiol-Lactam Initiated Radical Polymerization J. Appl. Polym. Sci. 2013, 127 (1) 261-269 10.1002/app.37879
30. Xie, L. Y.; Huang, X. Y.; Wu, C.; Jiang, P. K. Core-Shell Structured Poly(Methyl Methacrylate)/Batio3 Nanocomposites Prepared by in Situ Atom Transfer Radical Polymerization: A Route to High Dielectric Constant Materials with the Inherent Low Loss of the Base Polymer J. Mater. Chem. 2011, 21 (16) 5897-5906 10.1039/c0jm04574h
31. Dean, J. A. Lange's Handbook of Chemistry, 15 th ed; McGraw-Hill: New York, 1985; Vol. 7, pp 52.
32. Ou, R.; Gupta, S.; Parker, C. A.; Gerhardt, R. A. Fabrication and Electrical Conductivity of Poly(Methyl Methacrylate) (PMMA)/Carbon Black (Cb) Composites: Comparison between an Ordered Carbon Black Nanowire-Like Segregated Structure and a Randomly Dispersed Carbon Black Nanostructure J. Phys. Chem. B 2006, 110 (45) 22365-22373 10.1021/jp064498o
33. Coelho, R. On the Static Permittivity of Dipolar and Conductive Media-an Educational Approach J. Non-Cryst. Solids 1991, 131-133, 1136-1139 10.1016/0022-3093(91)90740-W
34. Dukes, D.; Li, Y.; Lewis, S.; Benicewicz, B.; Schadler, L.; Kumar, S. K. Conformational Transitions of Spherical Polymer Brushes: Synthesis, Characterization, and Theory Macromolecules 2010, 43 (3) 1564-1570 10.1021/ma901228t
35. Natarajan, B.; Neely, T.; Rungta, A.; Benicewicz, B. C.; Schadler, L. S. Thermomechanical Properties of Bimodal Brush Modified Nanoparticle Composites Macromolecules 2013, 46 (12) 4909-4918 10.1021/ma400553c
36. Sillars, R. W. Electrical Insulating Materials and Their Application; Peter Peregrinus Ltd. for the Institution of Electrical Engineers: Stevenage, 1973; pp 56.
37. 3 Hybrid Filler for Poly(Vinylidene Fluoride-Trifluoroethylene-Chlorofluoroethylene) Nanocomposites with the Dielectric Constant Comparable to That of Percolative Composites ACS Appl. Mater. Interfaces 2013, 5 (5) 1747-1756 10.1021/am302959n
38. Bartnikas, R. In Dielectrlc Loss in Solids; Bartnikas, R.; Eichhorn, R. M., Eds.; Engineering Dielectris Vol. IIA: Electrical Properties of Solid Insulating Materials: Molecular Structure and Eletrical Behavior; American Society for Testing and Materials: Philadephia, 1983; pp 61-66.
39. Stoyanov, H.; Kollosche, M.; McCarthy, D. N.; Kofod, G. Molecular Composites with Enhanced Energy Density for Electroactive Polymers J. Mater. Chem. 2010, 20 (35) 7558-7564 10.1039/c0jm00519c
40. Klein, R. J.; Zhang, S.; Dou, S.; Jones, B. H.; Colby, R. H.; Runt, J. Modeling Electrode Polarization in Dielectric Spectroscopy: Ion Mobility and Mobile Ion Concentration of Single-Ion Polymer Electrolytes J. Chem. Phys. 2006, 124 (14) 144903 10.1063/1.2186638
41. Wu, S.; Li, W.; Lin, M.; Burlingame, Q.; Chen, Q.; Payzant, A.; Xiao, K.; Zhang, Q. M. Aromatic Polythiourea Dielectrics with Ultrahigh Breakdown Field Strength, Low Dielectric Loss, and High Electric Energy Density Adv. Mater. 2013, 25 (12) 1734-1738 10.1002/adma.201204072
42. Heeger, A. J. Semiconducting Polymers: The Third Generation Chem. Soc. Rev. 2010, 39 (7) 2354-2371 10.1039/b914956m
43. Heeger, A. J.; Sariciftci, N. S.; Namdas, E. B. Semiconducting and Metallic Polymers; Oxford University Press: Oxford, U.K., 2010; pp 1-288.