Gas phase reactive collisions at very low temperature: Recent experimental advances and perspectives

Low Temperatures and Cold Molecules

Volumn , Issue , 2008, Pages 55-120

  Canosa, André ^a   Goulay, Fabien ^b   Sims, Ian R ^a   Rowe, Bertrand R ^a  

^a UNIVERSITÉ DE RENNES 1   (France)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GASPHASE; REACTIVE COLLISIONS; VERY LOW TEMPERATURES;

TEMPERATURE;

EID: 84967546655     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1142/9781848162105_0002     Document Type: Chapter

References (97)

1. Smith IWM. (2003) Laboratory studies of atmospheric reactions at low temperatures. Chem. Rev. 103: 4549-4564.
2. Smith IWM. (2002) The Liversidge Lecture 2001-2002. Chemistry amongst the stars: Reaction kinetics at a new frontier. Chem. Soc. Rev. 31: 137-146.
3. Smith IWM. (2006) Reactions at very low temperatures: Gas kinetics at a new frontier. Angew. Chem. Int. Ed. 45: 2842-2861.
4. Smith IWM, Rowe BR. (2000) Reaction kinetics at very low temperatures: Laboratory studies and interstellar chemistry. Acc. Chem. Res. 33: 261-268.
5. Smith IWM, Herbst E, Chang Q. (2004) Rapid neutral-neutral reactions at low temperatures: A new network and first results for TMC-1. Mon. Not. R. Astron. Soc. 350: 323-330.
6. Althorpe SC, Clary DC. (2003) Quantum scattering calculations on chemical reactions. Annu. Rev. Phys. Chem. 54: 493-529
7. 2 reaction system: SACM/CT calculations between 0 and 5000 K. J. Chem. Phys. 113: 11019-11034.
8. Troe J. (1996) Statistical adiabatic channel model for ion-molecule capture processes. 2. Analytical treatment of ion-dipole capture. J. Chem. Phys. 105: 6249-6262.
9. Su T, Chesnavich WJ. (1982) Parametrization of the ion-polar molecule collision rate-constant by trajectory calculations. J. Chem. Phys. 76: 5183-5185.
10. Troe J, Lorquet JC, Manz J, Marcus RA, Herman M. (1997) Recent advances in statistical adiabatic channel calculations of state-specific dissociation dynamics. Chemical Reactions and Their Control on the Femtosecond Time Scale XXth Solvay Conference on Chemistry, Vol. 101, pp. 819-851.
11. Maergoiz AI, Nikitin EE, Troe J. (1996) Adiabatic channel study of the capture of nitrogen and oxygen molecules by an ion: Effect of nuclear symmetry and spin-spin interaction. Z. Phys. D: At. Mol. Clusters. 36: 339-347.
12. Herbst E, Klemperer W. (1973) The formation and depletion of molecules in dense interstellar clouds. Astrophys. J. 185: 505-533.
13. Smith MA, Ng CY, Baer T, Powis I. (1994) Ion molecule reaction dynamics at very low temperatures. Unimolecular and Bimolecular Reaction Dynamics, pp. 183-251. John Wiley & Sons Ltd, New York.
14. Chutjian A, Garscadden A, Wadehra JM. (1996) Electron attachment to molecules at low electron energies. Phys. Rep. 264: 393-470.
15. Randeniya LK, Smith MA. (1990) A study of molecular supersonic flow using the generalized Boltzmann equation. J. Chem. Phys. 93: 661-673.
16. Dupeyrat G, Marquette JB, Rowe BR. (1985) Design and testing of axisym-metric nozzles for ion molecule reaction studies between 20 K and 160 K. Phys. Fluids. 28: 1273-1279.
17. 2 down to 26 K. J. Chem. Phys. 97: 8798-8800.
18. 2Π) and He at temperatures down to 15 K. Chem. Phys. Lett. 272: 412-418.
19. Daugey N, Caubet P, Retail B, Costes M, Bergeat A, Dorthe G. (2005) Kinetic measurements on methylidyne radical reactions with several hydrocarbons at low temperatures. Phys. Chem. Chem. Phys. 7: 2921-2927.
20. Atkinson DB, Smith MA. (1995) Design and characterization of pulsed uniform supersonic expansions for chemical applications. Rev. Sci. Instrum. 66: 4434-4446.
21. Lee S, Hoobler RJ, Leone SR. (2000) A pulsed Laval nozzle apparatus with laser ionization mass spectrometry for direct measurements of rate coefficients at low temperatures with condensable gases. Rev. Sci. Instrum. 71: 1816-1823.
22. Spangenberg T, Kohler S, Hansmann B, Wachsmuth U, Abel B, Smith MA. (2004) Low-temperature reactions of OH radicals with propene and isoprene in pulsed Laval nozzle expansions. J. Phys. Chem. A. 108: 7527-7534.
23. Bohringer H, Arnold F. (1983) Studies of ion molecule reactions, ion mobilities, and their temperature-dependence to very low-temperatures using a liquid-helium-cooled ion drift tube. Int. J. Mass Spectrom Ion Processes 49: 61-83.
24. 2 at 13 K. Phys. Rev. Lett. 52: 902-905.
25. Rowe BR, Marquette JB. (1987) CRESU Study of ion-molecule reactions. Int. J. Mass Spectrom Ion Processes 80: 239-254.
26. Hawley M, Mazely TL, Randeniya LK, Smith RS, Zeng XK, Smith MA. (1990) A free jet flow reactor for ion molecule reaction studies at very low energies. Int. J. Mass Spectrom Ion Processes 97: 55-86.
27. Smith MA, Hawley M. (1992) Ion chemistry at extremely low temperatures: a free Jet expansion approach. Adv. Gas Phase Ion Chem. 1: 167-202.
28. Gerlich D. (1993) Experimental investigations of ion-molecule reactions relevant to interstellar chemistry. J. Chem. Soc, Faraday Trans. 89: 2199-2208.
29. 6 determined between 200 K and 600 K using the FALP technique. J. Phys. B: At. Mol. Opt. Phys. 17: 461-472.
30. Balucani N, Capozza G, Leonori F, Segoloni E, Casavecchia P. (2006) Crossed molecular beam reactive scattering: from simple triatomic to multichannel polyatomic reactions. Int. Rev. Phys. Chem. 25: 109-163.
31. J). Chem. Phys. Lett. 310: 231-239.
32. 3Pj) atoms with O2 and NO. Phys. Chem. Chem. Phys. 2: 2873-2881.
33. 2: A key reaction in interstellar chemistry. J. Phys. Chem. A. 106: 5541-5552.
34. Bejan A. (1993) Heat Transfer. John Wiley & Sons, New York.
35. 2Π, v = 3) at temperatures down to 7K. Chem. Phys. Lett. 276: 423-429.
36. Goulay F, Rebrion-Rowe C, Biennier L, Le Picard SD, Canosa A, Rowe BR. (2006) The reaction of anthracene with CH radicals: An experimental study of the kinetics between 58 K and 470 K. J. Phys. Chem. A. 110: 3132-3137
37. Goulay F, Rebrion-Rowe C, Le Garrec JL, Le Picard SD, Canosa A, Rowe BR. (2005) The reaction of anthracene with OH radicals: an experimental study of the kinetics between 58 K and 470 K. J. Chem. Phys. 122: 104308.
38. Rowe BR, Marquette JB, Rebrion C. (1989) Mass selected ion-molecule reactions at very low temperatures: The CRESUS apparatus. J. Chem. Soc. Faraday Trans. II 85: 1631-1641.
39. Speck T, Mostefaoui T, Travers D, Rowe BR. (2001) Pulsed injection of ions into the CRESU experiment. Int. J. Mass Spectrom 208: 73-80.
40. 2. J. Chem. Phys. 107: 54-63.
41. Goulay F, Rebrion-Rowe C, Carles S, Le Garrec JL, Rowe BR. (2004) The electron attachment rate coefficient of HI and DI in uniform supersonic flow. J. Chem. Phys. 121: 1303-1308.
42. 2 at temperatures down to 99 K. Chem. Phys. Lett. 151: 481-484.
43. 3 down to 25 K. J. Chem. Phys. 100: 4229-4241.
44. -) radical reactions with NO, saturated, and unsaturated hydrocarbons studied in a pulsed supersonic Laval nozzle flow reactor between 53 and 188 K. J. Phys. Chem. A. 109: 1391-1399.
45. Mullen C, Smith MA. (2005) Temperature dependence and kinetic isotope effects for the OH + HBr reaction and H/D isotopic variants at low temperatures (53-135 K) measured using a pulsed supersonic Laval nozzle flow reactor. J. Phys. Chem. A 109: 3893-3902.
46. Hansmann B, Abel B. (2007) Kinetics in cold Laval nozzle expansions: From atmospheric chemistry to oxidation of biomolecules in the gas phase. Chemm. phys. chem. 8: 343-356.
47. Su T, Bowers MT. (1973) Theory of ion-polar molecule collisions. Comparison with experimental charge transfer reactions of rare gas ions to geometric isomers of difluorobenzene and dichloroethylene. J. Chem. Phys. 58: 3027-3037.
48. Georgievskii Y, Klippenstein SJ. (2005) Long-range transition state theory. J. Chem. Phys. 122: 194103.
49. Clary DC. (1990) Fast chemical reactions - Theory challenges experiment. Annu. Rev. Phys. Chem. 41: 61-90.
50. Troe J. (1985) Statistical Adiabatic Channel Model of ion neutral dipole capture rate constants. Chem. Phys. Lett. 122: 425-430.
51. Clary DC. (1987) Rate constants for the reactions of ions with dipolar polyatomic-molecules. J. Chem. Soc, Faraday Trans. II 83: 139-148.
52. Rowe BR, Canosa A, Le Page V. (1995) FALP and CRESU studies of ionic reactions. Int. J. Mass Spectrom Ion Processes 149/150: 573-596.
53. Rowe BR, Rebrion C. (1991) Recent Laboratory works toward Astrochemistry. Trends. Chem. Phys. 1: 367-389.
54. 4 + M reaction. Phys. Chem. Chem. Phys. 7: 1560-1567.
55. Troe J. (1979) Predictive possibilities of unimolecular rate theory. J. Phys. Chem. 83: 114-126.
56. Speck T, Le Garrec JL, Le Picard S, Canosa A, Mitchell JBA, Rowe BR. (2001) Electron attachment in HBr and HCl. J. Chem. Phys. 114: 8303-8309.
57. Moustefaoui T, Rebrion-Rowe C, Le Garrec JL, Rowe BR, Mitchell JBA. (1998) Low temperature electron attachment to polycyclic aromatic hydrocarbons. Faraday Discuss 109: 71-82.
58. 3I. J. Phys. B. 33: 3575-3582.
59. Yung YL, Allen M, Pinto JP. (1984) Photochemistry of the atmosphere of Titan - Comparison between model and observations. Astrophys. J. Suppl. Ser. 55: 465-506.
60. Wilson EH, Atreya SK. (2003) Chemical sources of haze formation in Titan’s atmosphere. Planet Space Sci. 51: 1017-1033.
61. 8 Icarus 194: 746-757.
62. 4: Experimental results down to 15 K. J. Chem. Phys. 115: 6495-6503.
63. 2 reaction: a fast source of SiO at very low temperature; CRESU measurements and interstellar consequences. Astron. Astrophys. 372: 1064-1070.
64. 2 at temperatures down 15 K. Astron. Astrophys. 365: 241-247.
65. 3 in the 104-294 K temperature range. J. Phys. Chem. A. 108: 3766-3771.
66. Vohringer-Martínez E, Hansmann B, Hernandez H, Francisco JS, Troe J, Abel B. (2007) Water catalysis of a radical-molecule gas-phase reaction. Science 315: 497-501.
67. 2 at 90 K and 120 K using a pulsed Laval nozzle apparatus. Chem. Phys. Lett. 329: 443-449.
68. 2 J. Chem. Phys. 106: 7662-7677
69. Le Picard SD, Canosa A, Rowe BR, Brownsword RA, Smith IWM. (1998) Determination of the limiting low pressure rate constants of the association reactions of CH with N2 and CO: A CRESU measurement at 53 K. J. Che. Soc, Faraday Trans. 94: 2889-2893.
70. 2 +H, at Temperatures down to 39 K. J. Phys. Chem. A. 110: 3101-3109.
71. Larsson B, Liseau R, Pagani L, Bergman P, Bernath P, Biver N, Black JH, Booth RS, Buat V, Crovisier J, et al. (2007) Molecular oxygen in the rho Ophiuchi cloud. Astron. Astrophys. 466: 999-U158.
72. Viti S, Roueff E, Hartquist TW, des Forets GP, Williams D. (2001) Interstellar oxygen chemistry. Astron. Astrophys. 370: 557-569.
73. g) reaction on an improved ab initio potential energy surface and implications for the interstellar oxygen problem. J. Che. Phys. 127: 024304.
74. 2 reactions. J. Phys. Chem. A. 110: 1534-1540.
75. Dalgarno A. (2006) Introductory lecture: The growth of molecular complexity in the Universe. Faraday Discuss 133: 9-25.
76. Schuetz CA, Frenklach M. (2002) Nucleation of soot: Molecular dynamics simulations of pyrene dimerization. Proc. Combust. Inst. 29: 2307-2314.
77. Ricca A, Bauschlicher CW. (2000) The reactions of polycyclic aromatic hydrocarbons with OH. Chem. Phys. Lett. 328: 396-402.
78. Atkinson R. (1986) Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic-compounds under atmospheric conditions. Chem. Rev. 86: 69-201.
79. Smith IWM, Sage AM, Donahue NM, Herbst E, Quan D. (2006) The temperature-dependence of rapid low temperature reactions: experiment, understanding and prediction. Faraday Discuss 133: 137-156.
80. Sims IR, Queffelec JL, Travers D, Rowe BR, Herbert LB, Karthauser J, Smith IWM. (1993) Rate constants for the reactions of CN with hydrocarbons at low and ultra-low temperature. Chem. Phys. Lett. 211: 461-468.
81. 6 + CN reaction explained. J. Phys. Chem. A 111: 3802-3811.
82. 4. J. Phys. Chem. A. 109: 6031-6044.
83. Donahue NM. (2003) Reaction barriers: Origin and evolution. Chem. Rev. 103: 4593-4604.
84. Sabbah H, Biennier L, Sims IR, Georgievskii Y, Klippenstein SJ, Smith IWM. (2007) Understanding reactivity at very low temperatures: The reactions of oxygen atoms with alkenes. Science 317: 102-105.
85. 3P) with unsaturated-hydrocarbons. J. Phys. Chem. Ref. Data 16: 261-326.
86. Abraham FF. (1974) Homogeneous nucleation theory: The pretransition theory of vapor condensation, supplement I Academic Press, New York.
87. Hamon S, Le Picard SD, Canosa A, Rowe BR, Smith IWM. (2000) Low temperature measurements of the rate of association to benzene dimers in helium. J. Chem. Phys. 112: 4506-4516.
88. 4. Chem. Phys. Lett. 384: 68-72.
89. 8 (transbutene): Overall rate constants and atomic hydrogen branching ratios. Phys. Chem. Chem. Phys. 6: 5396-5401.
90. Taatjes CA, Hershberger JF. (2001) Recent progress in infrared absorption techniques for elementary gas-phase reaction kinetics. Annu. Rev. Phys. Chem. 52: 41-70.
91. 2). Phys. Chem. Chem. Phys. 9: 4291-4300.
92. 2 → AlO + O. Chem. Phys. Lett. 191: 269-272.
93. 2 in the range -295 < T/K < 700K. Int. J. Chem. Kinet. 24: 791-802.
94. 6 and but-1-ene studied between 23 and 295 K with a CRESU apparatus. Astron. Astrophys. 323: 644-651.
95. 6 down to 15 K. Faraday Discuss 109: 165-181
96. 2H radical reactions with ethene, propene and 1-butene measured in a pulsed Laval nozzle apparatus at T=103 and 296 K. Chemm. Phys. Lett. 348: 21-26.
97. 8) over the temperature range 24-300 K. Implications for the atmospheres of Titan and the Giant Planets. Icarus 187: 558-568.