Understanding reactivity at very low temperatures: The reactions of oxygen atoms with alkenes

Science

Volumn 317, Issue 5834, 2007, Pages 102-105

  Sabbah, Hassan ^a   Biennier, Ludovic ^a   Sims, Ian R ^a   Georgievskii, Yuri ^b   Klippenstein, Stephen J ^c   Smith, Ian W M ^d  

^a UNIVERSITÉ DE RENNES 1   (France)

^b SANDIA NATIONAL LABORATORIES   (United States)

^c ARGONNE NATIONAL LABORATORY   (United States)

^d UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

1 BUTENE; ALKENE; ETHYLENE; FREE RADICAL; OXYGEN; PROPYLENE; UNCLASSIFIED DRUG;

ALKENE; EXPERIMENTAL STUDY; FREE RADICAL; OXYGEN; RADICAL; REACTION KINETICS; REACTION RATE; TEMPERATURE PROFILE;

ARTICLE; CALCULATION; ENERGY; LOW TEMPERATURE; MATHEMATICAL ANALYSIS; PRIORITY JOURNAL; REACTION ANALYSIS; REACTION TIME; TEMPERATURE DEPENDENCE; TEMPERATURE SENSITIVITY;

EID: 34447326681     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1142373     Document Type: Article

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21. Supported by the European Union via the award of a Marie Curie Chair (contract MEXC-CT-2004-006734, "Chemistry at Extremely Low Temperatures") (I.R.S.) and by grants from the Région de Bretagne, Rennes Métropole and the French Programme National de Physique Chimie du Milieu Interstellaire. The theoretical work (S.J.K. and Y.G.) was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. The portion at Argonne was supported under contract DE-AC02-06CH11357. Sandia is a multiprogram laboratory operated by Sandia Corp., a Lockheed Martin Company, for the U.S. Department of Energy under contract DE-AC04-94- AL8500.