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Volumn 81, Issue 8, 2016, Pages 708-713

Liquid-Phase Epitaxially Grown Metal–Organic Framework Thin Films for Efficient Tandem Catalysis Through Site-Isolation of Catalytic Centers

Author keywords

cyclic carbonates; epoxidation; liquid phase epitaxy; metal organic frameworks; tandem catalysis

Indexed keywords


EID: 84963657761     PISSN: None     EISSN: 21926506     Source Type: Journal    
DOI: 10.1002/cplu.201600046     Document Type: Article
Times cited : (24)

References (78)
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    • The LPE approach, at least in our hands, also typically requires much lower reactant concentrations than conventional approaches to MOF synthesis
    • The liquid-phase epitaxial (LPE) synthesis method of the article title typically entails even milder conditions (lower temperatures) than solvothermal synthesis
    • The liquid-phase epitaxial (LPE) synthesis method of the article title typically entails even milder conditions (lower temperatures) than solvothermal synthesis. The LPE approach, at least in our hands, also typically requires much lower reactant concentrations than conventional approaches to MOF synthesis. Thus, LPE is particularly attractive if reactant solubilities are low or if the absolute quantity of a reactant available is small.
    • Thus, LPE is particularly attractive if reactant solubilities are low or if the absolute quantity of a reactant available is small
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    • Generation of cyclic carbonates through CO, insertion into an epoxide is one of the most successful examples of CO, fixation and could potentially be a more environmentally friendly route for the industrial preparation of carbonates, which currently involves highly toxic and corrosive phosgene and diols. (,) MOFs are found to be interesting catalysts for this reaction
    • 2fixation and could potentially be a more environmentally friendly route for the industrial preparation of carbonates, which currently involves highly toxic and corrosive phosgene and diols. (T. Sakakura, K. Kohno, Chem. Commun. 2009, 1312–1330.) MOFs are found to be interesting catalysts for this reaction.
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    • Sakakura, T.1    Kohno, K.2
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    • Mechanistically, in general the epoxidation reaction is via the formation of the proposed formally Mn, =O intermediate, which, in the case of homogenous catalysts, undergoes dimerization into an unreactive and autodestructive μ-oxo Mn, -porphyrin dimer. This decomposition pathway is disallowed if the catalyst is incorporated into the MOF
    • IV-porphyrin dimer. This decomposition pathway is disallowed if the catalyst is incorporated into the MOF. (J. A. A. W. Elemans, E. J. A. Bijsterveld, A. E. Rowan, R. J. M. Nolte, Eur. J. Org. Chem. 2007, 751–757).
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    • For an important safety note regarding the preparation of this oxidant, see “Chemical safety Synthesis procedure”
    • For an important safety note regarding the preparation of this oxidant, see: “Chemical safety: Synthesis procedure”; J. T. Hupp, S. T. Nguyen, Chem. Eng. News 2011, 89, 2.
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    • O. Shekhah, Materials 2010, 3, 1302–1315;
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    • It should be noted that the resulting thin film was not studied further after completion of the tandem reaction.
    • It should be noted that the resulting thin film was not studied further after completion of the tandem reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.