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Volumn 352, Issue 6283, 2016, Pages 329-332

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

Author keywords

[No Author keywords available]

Indexed keywords

BORON; OXYGEN; PALLADIUM;

EID: 84963522319     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.aad6981     Document Type: Article
Times cited : (253)

References (45)
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    • note
    • 3P(c-Hex, cyclohexyl), which has widespread application (2, 26).
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    • note
    • This nomenclature designates an N-X-L species, where N is the number of formally valence-shell electrons around atom X that are involved in bonding L ligands to X (29).
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    • note
    • We cannot unambiguously exclude the possibility that thallium hydroxide dissociates to a minor extent, forming the palladium hydroxide complex 6. These results do not contradict the conclusions of the studies led by Hartwig (13) and Amatore and Jutand (14-16). The kinetic incompetence of sodium or potassium boronates in aqueous-organic solutions need not carry over to organic-only solutions of thallium boronates.
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    • note
    • We cannot unambiguously exclude the possibility that methanol has incorporated into complex 20.
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    • note
    • Although 18 and 7 are both observed at -100°C, at -30°C, these species converge, thus preventing a definitive assignment of whether 18 or 20 is the actual species undergoing decay in the kinetic analysis.
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    • note
    • The identity of the species that is inducing autocatalysis has not been determined at this time.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.