Carbon monoxide/carbon dioxide electrochemical conversion on patterned nickel electrodes operating in fuel cell and electrolysis cell modes

International Journal of Hydrogen Energy

Volumn 41, Issue 6, 2016, Pages 3762-3773

  Li, Wenying ^a,b   Shi, Yixiang ^a   Luo, Yu ^a   Wang, Yuqing ^a   Cai, Ningsheng ^a  

^a Tsinghua University   (China)

^b RESEARCH CENTER OF LASER FUSION   (China)

Author keywords

Carbon dioxide; Carbon monoxide; Nickel electrode; Patterned; Solid oxide electrolysis cell; Solid oxide fuel cell

Indexed keywords

CARBON DIOXIDE; CARBON MONOXIDE; CHARGE TRANSFER; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMICAL OXIDATION; ELECTRODES; ELECTROLYSIS; ELECTROLYTIC CELLS; ELECTROLYTIC REDUCTION; FUEL CELLS; NICKEL; PARTIAL PRESSURE; POLARIZATION; REDUCTION; REGENERATIVE FUEL CELLS; SINGLE CRYSTALS; SURFACE DIFFUSION; YTTRIA STABILIZED ZIRCONIA;

CHARGE-TRANSFER REACTIONS; ELECTROCHEMICAL CONVERSION; ELECTROCHEMICAL PERFORMANCE; ELECTROCHEMICAL REDUCTIONS; NICKEL ELECTRODE; PARTIAL PRESSURE OF CO; PATTERNED; RATE DETERMINING STEP;

SOLID OXIDE FUEL CELLS (SOFC);

EID: 84962082392     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2016.01.019     Document Type: Article

References (32)

1. Graves, C., Ebbesen, S.D., Mogensen, M., Lackner, K.S., Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy. Renew Sust Energ Rev 15 (2011), 1–23.
2. Uhm, S., Kim, Y.D., Electrochemical conversion of carbon dioxide in a solid oxide electrolysis cell. Curr Appl Phys 14 (2014), 672–679.
3. Jensen, S.H., Sun, X., Ebbesen, S.D., Knibbe, R., Mogensen, M., Hydrogen and synthetic fuel production using pressurized solid oxide electrolysis cells. Int J Hydrogen Energy 35 (2010), 9544–9549.
4. Gorte, R.J., Vohs, J.M., Catalysis in solid oxide fuel cells. Annu Rev Chem Biomol 2 (2011), 9–30.
5. Ebbesen, S.D., Mogensen, M., Electrolysis of carbon dioxide in solid oxide electrolysis cells. J Power Sources 193 (2009), 349–358.
6. Zhan, Z., Lin, Z., Electrochemical reduction of CO2 in solid oxide electrolysis cells. J Power Sources 195 (2010), 7250–7254.
7. Kim-Lohsoontorn, P., Bae, J., Electrochemical performance of solid oxide electrolysis cell electrodes under high-temperature coelectrolysis of steam and carbon dioxide. J Power Sources 196 (2011), 7161–7168.
8. Li, W., Wang, H., Shi, Y., Cai, N., Performance and methane production characteristics of H2O–CO2 co-electrolysis in solid oxide electrolysis cells. Int J Hydrogen Energy 38 (2013), III04–9.
9. Stoots, C., O'Brien, J., Hartvigsen, J., Results of recent high temperature coelectrolysis studies at the Idaho National Laboratory. Int J Hydrogen Energy 34 (2009), 4208–4215.
10. Luo, Y., Shi, Y., Li, W., Ni, M., Cai, N., Elementary reaction modeling and experimental characterization of solid oxide fuel-assisted steam electrolysis cells. Int J Hydrogen Energy 39 (2014), 10359–10373.
11. Ehn, A., Hogh, J., Graczyk, M., Norrman, K., Montelius, L., Linne, M., et al. Electrochemical investigation of nickel pattern electrodes in H2/H2O and CO/CO2 atmospheres. J Electrochem Soc 157 (2010), B1588–B1596.
12. Sukeshini, A.M., Habibzadeh, B., Becker, B.P., Stoltz, C.A., Eichhorn, B.W., Jackson, G.S., Electrochemical oxidation of H2, CO, and CO/H2 mixtures on patterned Ni anodes on YSZ electrolytes. J Electrochem Soc 153 (2006), A705–A715.
13. Utz, A., Störmer, H., Gerthsen, D., Weber, A., Ivers-Tiffée, E., Microstructure stability studies of Ni patterned anodes for SOFC. Solid State Ionics 192 (2011), 565–570.
14. Mukhopadhyay, M., Mukhopadhyay, J., Sharma, A.D., Basu, R.N., In-situ patterned intra-anode triple phase boundary in SOFC electroless anode: an enhancement of electrochemical performance. Int J Hydrogen Energy 36 (2011), 7677–7682.
15. Bessler, W.G., Vogler, M., Störmer, H., Gerthsen, D., Utz, A., Weber, A., et al. Model anodes and anode models for understanding the mechanism of hydrogen oxidation in solid oxide fuel cells. Phys Chem Chem Phys 12 (2010), 13888–13903.
16. Vogler, M., Bieberle-Hutter, A., Gauckler, L., Warnatz, J., Bessler, W.G., Modelling study of surface reactions, diffusion, and spillover at a Ni/YSZ patterned anode. J Electrochem Soc 156 (2009), B663–B672.
17. Goodwin, D.G., Zhu, H., Colclasure, A.M., Kee, R.J., Modeling electrochemical oxidation of hydrogen on Ni-YSZ pattern anodes. J Electrochem Soc 156 (2009), B1004–B1021.
18. Shi, Y., Cai, N., Mao, Z., Simulation of EIS spectra and polarization curves based on Ni/YSZ patterned anode elementary reaction models. Int J Hydrogen Energy 37 (2012), 1037–1043.
19. Utz, A., Hansen, K.V., Norrman, K., Ivers-Tiffee, E., Mogensen, M., Impurity features in Ni-YSZ-H2-H2O electrodes. Solid State Ionics 183 (2011), 60–70.
20. Li, W., Shi, Y., Luo, Y., Wang, Y., Cai, N., Carbon deposition on patterned nickel/yttria stabilized zirconia electrodes for solid oxide fuel cell/solid oxide electrolysis cell modes. J Power Sources 276 (2015), 26–31.
21. Utz, A., Leonide, A., Weber, A., Ivers-Tiffee, E., Studying the CO-CO2 characteristics of SOFC anodes by means of patterned Ni anodes. J Power Sources 196 (2011), 7217–7224.
22. Lauvstad, G.Ø., Tunold, R., Sunde, S., Electrochemical oxidation of CO on Pt and Ni point electrodes in contact with an yttria-stabilized zirconia electrolyte: II. Steady-state and impedance measurements. J Electrochem Soc 149 (2002), E506–E514.
23. Williford, R.E., Chick, L.A., Maupin, G.D., Simner, S.P., Stevenson, J.W., Diffusion limitations in the porous anodes of SOFCs. J Electrochem Soc 150 (2003), A1067–A1072.
24. Xiao, X.D., Xie, Y., Shen, Y.R., Coverage dependence of anisotropic surface diffusion: CO/Ni(110). Phys Rev B Condens Matter 48 (1993), 17452–17462.
25. Burghaus, U., Surface chemistry of CO2 – adsorption of carbon dioxide on clean surfaces at ultrahigh vacuum. Prog Surf Sci 89 (2014), 161–217.
26. Bartos, B., Freund, H.J., Kuhlenbeck, H., Neumann, M., Lindner, H., Müller, K., Adsorption and reaction of CO2 and CO2/O CO-adsorption on Ni(110): angle resolved photoemission (ARUPS) and electron energy loss (HREELS) studies. Surf Sci 179 (1987), 59–89.
27. Hayek, K., Kramer, R., Paál, Z., Metal-support boundary sites in catalysis. Appl Catal A General 162 (1997), 1–15.
28. Ali, A., Wen, X., Nandakumar, K., Luo, J., Chuang, K.T., Geometrical modeling of microstructure of solid oxide fuel cell composite electrodes. J Power Sources 185 (2008), 961–966.
29. Erhan Aksoylu, A., Ïlsen Önsan, Z., Hydrogenation of carbon oxides using coprecipitated and impregnated Ni/Al2O3 catalysts. Appl Catal A General 164 (1997), 1–11.
30. Janardhanan, V.M., Deutschmann, O., CFD analysis of a solid oxide fuel cell with internal reforming: coupled interactions of transport, heterogeneous catalysis and electrochemical processes. J Power Sources 162 (2006), 1192–1202.
31. Menon, V., Fu, Q., Janardhanan, V.M., Deutschmann, O., A model-based understanding of solid-oxide electrolysis cells (SOECs) for syngas production by H2O/CO2 co-electrolysis. J Power Sources 274 (2015), 768–781.
32. Yurkiv, V., Utz, A., Weber, A., Ivers-Tiffée, E., Volpp, H., Bessler, W.G., Elementary kinetic modeling and experimental validation of electrochemical CO oxidation on Ni/YSZ pattern anodes. Electrochim Acta 59 (2012), 573–580.