Model anodes and anode models for understanding the mechanism of hydrogen oxidation in solid oxide fuel cells

Physical Chemistry Chemical Physics

Volumn 12, Issue 42, 2010, Pages 13888-13903

  Bessler, Wolfgang G ^a,b   Vogler, Marcel ^a,b   Störmer, Heike ^c   Gerthsen, Dagmar ^c   Utz, Annika ^c   Weber, André ^c   Ivers Tiffée, Ellen ^c  

^a GERMAN AEROSPACE CENTER DLR   (Germany)

^b UNIVERSITY OF STUTTGART   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77958609067     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/c0cp00541j     Document Type: Article

References (63)

1. W. Nernst Über die elektrolytische Leitung fester Körper bei sehr hohen Temperaturen Z. Elektrochem. 1899 6 41 43
2. H. Möbius On the history of solid electrolyte fuel cells J. Solid State Electrochem. 1997 1 2 16
3. E. Baur H. Preis Über Brennstoff-Ketten mit Festleitern Z. Elektrochem. 1937 43 727 732
4. S. C. Singhal and K. Kendall, High-temperature solid oxide fuel cells: Fundamentals, design and applications, Elsevier Science, Oxford, 2003
5. B. C. H. Steele Fuel cell technology: Running on natural gas Nature 1999 400 619 620
6. A. Atkinson S. Barnett R. J. Gorte J. T. S. Irvine A. J. McEvoy M. Mogensen S. C. Singhal J. M. Vohs Advanced anodes for high-temperature fuel cells Nat. Mater. 2004 3 17 27
7. S. B. Adler and W. G. Bessler, Elementary kinetic modeling of SOFC electrode reactions, in Handbook of Fuel Cells - Fundamentals, Technology and Applications, ed., W. Vielstich,,, H. Yokokawa, and, H. A. Gasteiger,, John Wiley & Sons, Chichester, UK, 2009, vol. 5, pp. 441-462
8. 2, CO and methane in SOFCs with Ni/YSZ-cermet anodes Solid State Ionics 2002 152-153 543 550
9. H. Timmermann W. Sawady R. Reimert E. Ivers-Tiffée Kinetics of (reversible) internal reforming of methane in solid oxide fuel cells under stationary and APU conditions J. Power Sources 2010 195 214 222
10. V. Sonn A. Leonide E. Ivers-Tiffée Towards understanding the impedance response of Ni/YSZ anodes J. Electrochem. Soc. 2007 155 B675
11. S. Gewies W. G. Bessler Physically based impedance modeling of Ni/YSZ cermet anodes J. Electrochem. Soc. 2008 155 B937 B952
12. J. R. Wilson W. Kobsiriphat R. Mendoza H.-Y. Chen J. M. Hiller D. J. Miller K. Thornton P. W. Voorhees S. B. Adler S. A. Barnett Three-dimensional reconstruction of a solid-oxide fuel-cell anode Nat. Mater. 2006 5 541 544
13. B. de Boer, SOFC Anode. Hydrogen oxidation at porous nickel and nickel/yttria-stabilised zirconia cermet electrodes, Ph.D. Thesis, University of Twente, Twente, The Netherlands, 1998
14. A. Bieberle L. P. Meier L. J. Gauckler The electrochemistry of Ni pattern anodes used as solid oxide fuel cell model electrodes J. Electrochem. Soc. 2001 148 A646 A656
15. 2O atmospheres J. Electrochem. Soc. 1994 141 2129 2134
16. 2 mixtures on patterned Ni anodes on YSZ electrolytes J. Electrochem. Soc. 2006 153 A705 A715
17. 2O atmosphere J. Electrochem. Soc. 2010 157 B920 B930
18. 2O atmospheres Solid State Ionics 1994 70/71 52 58
19. D. Kek M. Mogensen S. Pejovnik A study of metal (Ni, Pt, Au)/yttria-stabilized zirconia interface in hydrogen atmosphere at elevated temperature J. Electrochem. Soc. 2001 148 A878 A886
20. 2O-Ni-YSZ electrode performance. Effect of segregation to the interface J. Electrochem. Soc. 2004 151 A1436 A1444
21. M. S. Schmidt K. V. Hansen K. Norrman M. Mogensen Three-phase-boundary dynamics at the Ni/ScYSZ interface Solid State Ionics 2009 180 431 438
22. G. O. Lauvstad R. Tunold S. Sunde Electrochemical oxidation of CO on Pt and Ni point electrodes in contact with an yttria-stabilized zirconia electrolyte. II. Steady-state and impedance measurements J. Electrochem. Soc. 2002 149 E506 E514
23. K. V. Jensen S. Primdahl I. Chorkendorff M. Mogensen Microstructural and chemical changes at the Ni/YSZ interface Solid State Ionics 2001 144 197 209
24. K. V. Jensen R. Wallenberg I. Chorkendorff M. Mogensen Effect of impurities on structural and electrochemical properties of the Ni-YSZ interface Solid State Ionics 2003 160 27 37
25. 2O/Ni/YSZ electrode, PhD Thesis, Risø National Laboratory, Roskilde, 2005
26. J. Guindet, C. Roux and A. Hammou, Hydrogen Oxidation at the Ni/Zirconia Electrode, in Proceedings of the 2nd Internat. Symp. on SOFC, ed., P. Grosz et al.,, Greece, 1991, p. 553
27. 2 system at the interface of Ni grid electrode/YSZ electrolyte, in Proceedings of the Seventh International Symposium on Solid Oxide Fuel Cells, Electrochemical Society Proceedings Volume 2001-16, ed., H. Yokokawa, and, S.C. Singhal,, The Electrochemical Society, 2001, pp. 759-768
28. S. B. Adler Reference electrode placement in thin solid electrolytes J. Electrochem. Soc. 2002 149 E166 E172
29. J. Mukherjee S. Linic First-principles investigations of electrochemical oxidation of hydrogen at solid oxide fuel cell operating conditions J. Electrochem. Soc. 2007 154 B919 B924
30. J. Rossmeisl W. G. Bessler Trends in catalytic activity for SOFC anode materials Solid State Ionics 2008 178 1694 1700
31. D. B. Ingram S. Linic First-Principles Analysis of the Activity of Transition and Noble Metals in the Direct Utilization of Hydrocarbon Fuels at Solid Oxide Fuel Cell Operating Conditions J. Electrochem. Soc. 2009 156 B1457 B1465
32. N. Kleis G. Jones F. Abild-Pedersen V. Tripkovic T. Bligaard J. Rossmeisl Trends for Methane Oxidation at Solid Oxide Fuel Cell Conditions J. Electrochem. Soc. 2009 156 B1447 B1456
33. A. B. Anderson E. Vayner Hydrogen oxidation and proton transport at the Ni-zirconia interface in solid oxide fuel cell anodes: Quantum chemical predictions Solid State Ionics 2006 177 1355 1359
34. 4 and CO Molecules at the Interface between Nickel and Yttria-Stabilized Zirconia: A Theoretical Study Based on DFT J. Phys. Chem. C 2009 113 21667 21678
35. A. Bieberle L. J. Gauckler State-space modeling of the anodic SOFC system Solid State Ionics 2002 146 23 41
36. W. G. Bessler A new computational approach for SOFC impedance based on detailed electrochemical reaction-diffusion models Solid State Ionics 2005 176 997 1011
37. M. Vogler A. Bieberle-Hütter L. J. Gauckler J. Warnatz W. G. Bessler Modelling study of surface reactions, diffusion and spillover at a Ni/YSZ patterned anode J. Electrochem. Soc. 2009 156 B663 B672
38. D. G. Goodwin H. Zhu A. M. Colclasure R. J. Kee Modeling electrochemical oxidation of hydrogen on Ni-YSZ pattern anodes J. Electrochem. Soc. 2009 156 B1004 B1021
39. M. Vogler W. G. Bessler The role of interstitial hydrogen species in Ni/YSZ patterned anodes: A 2D modeling study ECS Trans. 2009 25 1957 1966
40. B. Rüger A. Weber E. Ivers-Tiffée 3D-modelling and performance evaluation of mixed conducting (MIEC) cathodes ECS Trans. 2007 7 2065 2074
41. D. Larrain J. van Herle D. Favrat Simulation of SOFC stack and repeat elements including interconnect degradation and anode reoxidation risk J. Power Sources 2006 161 392 403
42. F. Leucht W. G. Bessler J. Kallo K. A. Friedrich H. Müller- Steinhagen Fuel Cell System Modelling for SOFC/GT Hybrid Power Plants, Part I: Modelling and simulation framework J. Power Sources 2010
43. M. Andersson J. Yuan B. Sundén Review on modeling development for multiscale chemical reactions coupled transport phenomena in solid oxide fuel cells Appl. Energy 2010 87 1461 1476
44. SPIP Scanning Probe Image Processor, Version 4.0, Image Metrology A/S. 1998
45. 2/YSZ Acta Mater. 1996 44 3679 3692
46. A. Utz H. Störmer D. Gerthsen A. Weber E. Ivers-Tiffée Microstructure stability studies of Ni patterned anodes for SOFC Solid State Ionics 2010 10.1016/j.ssi.2010.05.004
47. M. Mogensen and K. V. Hansen, Impact of impurities and interface reaction on electrochemical activity, in Handbook of Fuel Cells - Fundamentals, Technology and Applications, ed., W. Vielstich,,, H. Yokokawa, and, H. A. Gasteiger,, John Wiley & Sons, Chichester, UK, 2009, vol. 5
48. A. J. Bard and L. R. Faulkner, Electrochemical methods: Fundamentals and Applications, Wiley, New York, 2nd edn, 2001
49. C. H. Hamann, A. Hamnett and W. Vielstich, Electrochemistry, Wiley-VCH, Weinheim, 1998
50. V. S. Bagotzki, Fundamentals of Electrochemistry, Plenum Press, New York, 1993
51. W. G. Bessler J. Warnatz D. G. Goodwin The influence of equilibrium potential on hydrogen oxidation kinetics of SOFC anodes Solid State Ionics 2007 177 3371 3383
52. W. G. Bessler S. Gewies M. Vogler A new framework for physically based modeling of solid oxide fuel cells Electrochim. Acta 2007 53 1782 1800
53. C. Endler A. Leonide A. Weber F. Tietz E. Ivers-Tiffée Time-Dependent Electrode Performance Changes in Intermediate Temperature Solid Oxide Fuel Cells J. Electrochem. Soc. 2010 157 B292 B298
54. V. Sonn A. Leonide E. Ivers-Tiffée Combined deconvolution and CNLS Fitting Approach Applied on the Impedance Response of Technical Ni/8YSZ Cermet Electrodes J. Electrochem. Soc. 2008 155 B675 B679
55. J. Nowotny C. C. Sorrell T. Bak Segregation in zirconia: equilibrium versus non-equilibrium segregation Surf. Interface Anal. 2005 37 316 324
56. R. B. McLellan W. A. Oates The solubility of hydrogen in Rhodium, Ruthenium, Iridium and Nickel Acta Metall. 1973 21 181 185
57. 3-Mischkristallen Ber. Bunsen-Ges. Phys. Chem. 1968 72 778 781
58. W. G. Bessler S. Gewies C. Willich G. Schiller K. A. Friedrich Spatial distribution of electrochemical performance in a segmented SOFC: A combined modeling and experimental study Fuel Cells 2010 10 411 418
59. H. Zhu R. J. Kee Modeling distributed charge-transfer processes in SOFC membrane electrode assemblies J. Electrochem. Soc. 2008 155 B715 B729
60. V. M. Janardhanan O. Deutschmann CFD analysis of a solid oxide fuel cell with internal reforming: Coupled interactions of transport, heterogeneous catalysis and electrochemical processes J. Power Sources 2006 162 1192 1202
61. J. Fleig On the current-voltage characteristics of charge transfer reactions at mixed conducting electrodes on solid electrolytes Phys. Chem. Chem. Phys. 2005 7 2027 2037
62. E. Ivers-Tiffée, H. Timmermann, A. Leonide, N. H. Menzler and J. Malzbender, Methane reforming kinetics, carbon deposition and redox durability of Ni/8-yttria-stabilized zirconia (YSZ) anodes, in Handbook of Fuel Cells - Fundamentals, Technology and Applications, ed., W. Vielstich,,, H. Yokokawa, and, H. A. Gasteiger,, John Wiley & Sons, Chichester, UK, 2009, vol. 5
63. E. S. Hecht G. K. Gupta H. Zhu A. M. Dean R. J. Kee J. Maier O. Deutschmann Methane reforming kinetics within a Ni-YSZ SOFC anode support Appl. Catal., A 2005 295 40 51