Incorporation of Nitrogen Defects for Efficient Reduction of CO2 via Two-Electron Pathway on Three-Dimensional Graphene Foam

Nano Letters

Volumn 16, Issue 1, 2016, Pages 466-470

  Wu, Jingjie ^a   Liu, Mingjie ^a   Sharma, Pranav P ^b   Yadav, Ram Manohar ^a   Ma, Lulu ^a   Yang, Yingchao ^a   Zou, Xiaolong ^a   Zhou, Xiao Dong ^b   Vajtai, Robert ^a   Yakobson, Boris I ^a   Lou, Jun ^a   Ajayan, Pulickel M ^a  

^a Rice University   (United States)

^b The Department of Mechanical Engineering   (United States)

Author keywords

CO2 reduction; electrocatalyst; first principles theory; low overpotential; N doped 3D graphene foam

Indexed keywords

CALCULATIONS; CARBON MONOXIDE; CATALYST ACTIVITY; CATALYSTS; DEFECTS; DENSITY FUNCTIONAL THEORY; DOPING (ADDITIVES); ELECTROCATALYSTS; ELECTROLYTIC REDUCTION; GRAPHENE; NITROGEN; REDUCTION; SILVER;

3D GRAPHENE; ELECTROCHEMICAL REDUCTIONS; EXPERIMENTAL INVESTIGATIONS; FARADAIC EFFICIENCIES; FIRST-PRINCIPLES THEORY; OVERPOTENTIAL; THREE-DIMENSIONAL GRAPHENE; THREEDIMENSIONAL (3-D);

CARBON DIOXIDE;

EID: 84957894467     PISSN: 15306984     EISSN: 15306992     Source Type: Journal    
DOI: 10.1021/acs.nanolett.5b04123     Document Type: Article

References (27)

1. Li, C. W.; Kanan, M. W. J. Am. Chem. Soc. 2012, 134, 7231-7234 10.1021/ja3010978
2. Li, C. W.; Ciston, J.; Kanan, M. W. Nature 2014, 508, 504-507 10.1038/nature13249
3. Kaneco, S.; Iiba, K.; Hiei, N.-H.; Ohta, K.; Mizuno, T.; Suzuki, T. Electrochim. Acta 1999, 44, 4701-4706 10.1016/S0013-4686(99)00262-5
4. Le, M.; Ren, M.; Zhang, Z.; Sprunger, P. T.; Kurtz, R. L.; Flake, J. C. J. Electrochem. Soc. 2011, 158, E45-E49 10.1149/1.3561636
5. Chen, Y.; Li, C. W.; Kanan, M. W. J. Am. Chem. Soc. 2012, 134, 19969-19972 10.1021/ja309317u
6. Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.; Zhu, W.; Whipple, D. T.; Kenis, P. J. A.; Masel, R. I. Science 2011, 334, 643-644 10.1126/science.1209786
7. Lu, Q.; Rosen, J.; Zhou, Y.; Hutchings, G. S.; Kimmel, Y. C.; Chen, J. G.; Jiao, F. Nat. Commun. 2014, 5, 3242 10.1038/ncomms4242
8. Zhu, W.; Michalsky, R.; Metin, Ö.; Lv, H.; Guo, S.; Wright, C. J.; Sun, X.; Peterson, A. A.; Sun, S. J. Am. Chem. Soc. 2013, 135, 16833-16836 10.1021/ja409445p
9. Kumar, B.; Asadi, M.; Pisasale, D.; Sinha-Ray, S.; Rosen, B. A.; Haasch, R.; Abiade, J.; Yarin, A. L.; Salehi-Khojin, A. Nat. Commun. 2013, 4, 2819 10.1038/ncomms3819
10. Zhang, S.; Kang, P.; Ubnoske, S.; Brennaman, M. K.; Song, N.; House, R. L.; Glass, J. T.; Meyer, T. J. J. Am. Chem. Soc. 2014, 136, 7845-7848 10.1021/ja5031529
11. Wu, J.; Yadav, R. M.; Liu, M.; Sharma, P. P.; Tiwary, C. S.; Ma, L.; Zou, X.; Zhou, X.-D.; Yakobson, B. I.; Lou, J. ACS Nano 2015, 9, 5364-5371 10.1021/acsnano.5b01079
12. Kaukonen, M.; Kujala, R.; Kauppinen, E. J. Phys. Chem. C 2012, 116, 632-636 10.1021/jp2059112
13. Yadav, R. M.; Wu, J.; Kochandra, R.; Ma, L.; Tiwary, C. S.; Ge, L.; Ye, G.; Vajtai, R.; Lou, J.; Ajayan, P. M. ACS Appl. Mater. Interfaces 2015, 7, 11991-12000 10.1021/acsami.5b02032
14. Chen, Z.; Ren, W.; Gao, L.; Liu, B.; Pei, S.; Cheng, H.-M. Nat. Mater. 2011, 10, 424-428 10.1038/nmat3001
15. Wu, J.; Ma, L.; Yadav, R. M.; Yang, Y.; Zhang, X.; Vajtai, R.; Lou, J.; Ajayan, P. M. ACS Appl. Mater. Interfaces 2015, 7, 14763-14769 10.1021/acsami.5b02902
16. Hao, Y.; Wang, Y.; Wang, L.; Ni, Z.; Wang, Z.; Wang, R.; Koo, C. K.; Shen, Z.; Thong, J. T. L. Small 2010, 6, 195-200 10.1002/smll.200901173
17. Qu, L.; Liu, Y.; Baek, J.-B.; Dai, L. ACS Nano 2010, 4, 1321-1326 10.1021/nn901850u
18. Ratso, S.; Kruusenberg, I.; Vikkisk, M.; Joost, U.; Shulga, E.; Kink, I.; Kallio, T.; Tammeveski, K. Carbon 2014, 73, 361-370 10.1016/j.carbon.2014.02.076
19. Sharifi, T.; Hu, G.; Jia, X.; Wågberg, T. ACS Nano 2012, 6, 8904-8912 10.1021/nn302906r
20. Jacobson, I. A.; Heady, H. H.; Dinneen, G. U. J. Phys. Chem. 1958, 62, 1563-1565 10.1021/j150570a023
21. Arrigo, R.; Havecker, M.; Schlogl, R.; Su, D. S. Chem. Commun. 2008, 40, 4891-4893 10.1039/b812769g
22. Wu, J.; Risalvato, F. G.; Sharma, P. P.; Pellechia, P. J.; Ke, F.-S.; Zhou, X.-D. J. Electrochem. Soc. 2013, 160, F953-F957 10.1149/2.030309jes
23. Feng, X.; Jiang, K.; Fan, S.; Kanan, M. W. J. Am. Chem. Soc. 2015, 137, 4606-4609 10.1021/ja5130513
24. Sharma, P. P.; Wu, J.; Yadav, R. M.; Liu, M.; Wright, C. J.; Tiwary, C. S.; Yakobson, B. I.; Lou, J.; Ajayan, P. M.; Zhou, X.-D. Angew. Chem., Int. Ed. 2015, 54, 13701-13705 10.1002/anie.201506062
25. Peterson, A. A.; Abild-Pedersen, F.; Studt, F.; Rossmeisl, J.; Norskov, J. K. Energy Environ. Sci. 2010, 3, 1311-1315 10.1039/c0ee00071j
26. Peterson, A. A.; Nørskov, J. K. J. Phys. Chem. Lett. 2012, 3, 251-258 10.1021/jz201461p
27. Hansen, H. A.; Varley, J. B.; Peterson, A. A.; Nørskov, J. K. J. Phys. Chem. Lett. 2013, 4, 388-392 10.1021/jz3021155