CO 2 reduction at low overpotential on Cu electrodes resulting from the reduction of thick Cu 2O films

Journal of the American Chemical Society

Volumn 134, Issue 17, 2012, Pages 7231-7234

  Li, Christina W ^a   Kanan, Matthew W ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CU ELECTRODE; CU FOIL; IDENTICAL CONDITIONS; INITIAL THICKNESS; METAL ELECTRODES; MODIFIED ELECTRODES; OVERPOTENTIAL; POLYCRYSTALLINE; REDUCTION ACTIVITY; ROUGHNESS FACTOR;

ELECTRODES; METAL CLADDING;

CARBON DIOXIDE;

CUPROUS OXIDE; WATER;

ARTICLE; CATALYST; CRYSTAL STRUCTURE; DENSITY; ELECTROCHEMICAL ANALYSIS; ELECTRODE; FILM; HIGH TEMPERATURE; REDUCTION; STRUCTURE ANALYSIS; THICKNESS;

EID: 84860812959     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3010978     Document Type: Article

References (29)

1. Olah, G. A.; Prakash, G. K. S.; Goeppert, A. J. Am. Chem. Soc. 2011, 133, 12881
2. Cook, T. R.; Dogutan, D. K.; Reece, S. Y.; Surendranath, Y.; Teets, T. S.; Nocera, D. G. Chem. Rev. 2010, 110, 6474
3. Centi, G.; Perathoner, S. Catal. Today 2009, 148, 191
4. Arakawa, H.; Aresta, M.; Armor, J. N.; Barteau, M. A.; Beckman, E. J.; Bell, A. T.; Bercaw, J. E.; Creutz, C.; Dinjus, E.; Dixon, D. A.; Domen, K.; DuBois, D. L.; Eckert, J.; Fujita, E.; Gibson, D. H.; Goddard, W. A.; Goodman, D. W.; Keller, J.; Kubas, G. J.; Kung, H. H.; Lyons, J. E.; Manzer, L. E.; Marks, T. J.; Morokuma, K.; Nicholas, K. M.; Periana, R.; Que, L.; Rostrup-Nielson, J.; Sachtler, W. M. H.; Schmidt, L. D.; Sen, A.; Somorjai, G. A.; Stair, P. C.; Stults, B. R.; Tumas, W. Chem. Rev. 2001, 101, 953
5. Bell, A. T.; Gates, B. C.; Ray, D., U.S. Department of Energy. Basic Research Needs: Catalysis for Energy (PNNL-17214). Report from a workshop held August 6-8, 2007, Bethesda, MD, http://www.sc.doe.gov/bes/reports/ list.html.
6. Hori, Y.; Kikuchi, K.; Suzuki, S. Chem. Lett. 1985, 1695
7. Hori, Y. In Modern Aspects of Electrochemistry; Vayenas, C. G.; White, R. E.; Gamboa-Aldeco, M. E., Eds.; Springer: New York, 2008; Vol. 42, p 89.
8. Chen, Y.; Kanan, M. W. J. Am. Chem. Soc. 2012, 134, 1986
9. Gattrell, M.; Gupta, N.; Co, A. J. Electroanal. Chem. 2006, 594, 1
10. Dewulf, D. W.; Jin, T.; Bard, A. J. J. Electrochem. Soc. 1989, 136, 1686
11. Schouten, K. J. P.; Kwon, Y.; van der Ham, C. J. M.; Qin, Z.; Koper, M. T. M. Chem. Sci. 2011, 2, 1902
12. Peterson, A. A.; Abild-Pedersen, F.; Studt, F.; Rossmeisl, J.; Nørskov, J. K. Energ. Environ. Sci. 2010, 3, 1311
13. Durand, W. J.; Peterson, A. A.; Studt, F.; Abild-Pedersen, F.; Nørskov, J. K. Surf. Sci. 2011, 605, 1354
14. Hori, Y.; Murata, A.; Takahashi, R. J. Chem. Soc., Farad. Trans. 1 1989, 85, 2309
15. Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nature 2000, 407, 496
16. Zhang, D. W.; Chen, C. H.; Zhang, J.; Ren, F. J. Mater. Sci. 2008, 43, 1492
17. Han, W. K.; Choi, J. W.; Hwang, G. H.; Hong, S. J.; Lee, J. S.; Kang, S. G. Appl. Surf. Sci. 2006, 252, 2832
18. Reyter, D.; Odziemkowski, M.; Belanger, D.; Roue, L. J. Electrochem. Soc. 2007, 154, K36
19. Augustynski, J.; Kedzierzawski, P.; Jermann, B. Stud. Surf. Sci. Catal. 1998, 114, 107
20. Yano, J.; Yamasaki, S. J. Appl. Electrochem. 2008, 38, 1721
21. Tang, W.; Peterson, A. A.; Varela, A. S.; Jovanov, Z. P.; Bech, L.; Durand, W. J.; Dahl, S.; Nørskov, J. K.; Chorkendorff, I. Phys. Chem. Chem. Phys. 2012, 14, 76
22. Frese, K. W. J. Electrochem. Soc. 1991, 138, 3338
23. Le, M.; Ren, M.; Zhang, Z.; Sprunger, P. T.; Kurtz, R. L.; Flake, J. C. J. Electrochem. Soc. 2011, 158, E45
24. Larson, P. E. J Electron Spectrosc. 1974, 4, 213
25. Waszczuk, P.; Zelenay, P.; Sobkowski, J. Electrochim. Acta 1995, 40, 1717
26. Hori, Y.; Takahashi, I.; Koga, O.; Hoshi, N. J. Phys. Chem. B 2002, 106, 15
27. The production of ethane has been reported in one previous study of an electrode described as a copper electrodeposit, but no further details about the catalyst were provided. See: Goncalves, M. R.; Gomes, A.; Condeco, J.; Fernandes, R.; Pardal, T.; Sequeira, C. A. C.; Branco, J. B. Energy Convers. Manag. 2010, 51, 30-32
28. Whipple, D. T.; Finke, E. C.; Kenis, P. J. A. Electrochem. Solid St. 2010, 13, D109
29. Hara, K.; Sonoyama, N.; Sakata, T. Stud. Surf. Sci. Catal. 1998, 114, 577