Anhydrous Proton Transport in Polymerized Ionic Liquid Block Copolymers: Roles of Block Length, Ionic Content, and Confinement

Macromolecules

Volumn 49, Issue 1, 2016, Pages 395-404

  Evans, Christopher M ^a,b   Sanoja, Gabriel E ^c   Popere, Bhooshan C ^a,b   Segalman, Rachel A ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of California   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; IONIC CONDUCTIVITY; IONIC LIQUIDS; IONIC STRENGTH; LIQUIDS; NITROGEN; POLYMERS; TEMPERATURE DISTRIBUTION; X RAY SCATTERING;

CONFINEMENT EFFECTS; GROTTHUS MECHANISMS; PACKING EFFICIENCY; POLYMER BACKBONES; POLYMERIZED IONIC LIQUIDS; PROTON CONDUCTING; STRENGTH PARAMETERS; TEMPERATURE DEPENDENCE;

BLOCK COPOLYMERS;

EID: 84954350344     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/acs.macromol.5b02202     Document Type: Article

References (60)

1. Singh, M.; Odusanya, O.; Wilmes, G. M.; Eitouni, H. B.; Gomez, E. D.; Patel, A. J.; Chen, V. L.; Park, M. J.; Fragouli, P.; Iatrou, H.; Hadjichristidis, N.; Cookson, D.; Balsara, N. P. Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes Macromolecules 2007, 40, 4578-4585 10.1021/ma0629541
2. Sinha, K.; Maranas, J. K. Segmental Dynamics and Ion Association in PEO-Based Single Ion Conductors Macromolecules 2011, 44, 5381-5391 10.1021/ma2005074
3. Croce, F.; Appetecchi, G. B.; Persi, L.; Scrosati, B. Nanocomposite polymer electrolytes for lithium batteries Nature 1998, 394, 456-458 10.1038/28818
4. Abraham, K. M.; Jiang, Z. A Polymer Electrolyte-Based Rechargable Lithium/Oxygen Battery J. Electrochem. Soc. 1996, 143, 1-5 10.1149/1.1836378
5. Armand, M.; Tarascon, J.-M. Building better batteries Nature 2008, 451, 652-657 10.1038/451652a
6. Zawodzinski, T. A.; Springer, T. E.; Uribe, F.; Gottesfeld, S. Characterization of Polymer Electrolytes for Fuel Cell Applications Solid State Ionics 1993, 60, 199-211 10.1016/0167-2738(93)90295-E
7. Hickner, M. A.; Pivovar, B. S. The Chemical and Structural Nature of Proton Exchange Membrane Fuel Cell Properties Fuel Cells 2005, 5, 213-229 10.1002/fuce.200400064
8. Weber, A. Z.; Newman, J. Modeling Transport in Polymer-Electrolyte Fuel Cells Chem. Rev. 2004, 104, 4679-4726 10.1021/cr020729l
9. Borup, R.; Meyers, J.; Pivovar, B. S.; Kim, Y. S.; Mukundan, R.; Garland, N.; Myers, D.; Wilson, M.; Garzon, F.; Wood, D.; Zelenay, P.; More, K.; Stroh, K.; Zawodzinski, T.; Boncella, J.; McGrath, J. E.; Inaba, M.; Miyatake, K.; Hori, M.; Yasuda, K.; Kimijima, K.; Iwashita, N. Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation Chem. Rev. 2007, 107, 3904-3951 10.1021/cr050182l
10. Simon, P.; Gogotsi, Y. Materials for electrochemical capacitors Nat. Mater. 2008, 7, 845 10.1038/nmat2297
11. Snook, G. A.; Kao, P.; Best, A. S. Conducting-polymer-based supercapacitor devices and electrodes J. Power Sources 2011, 196, 1-12 10.1016/j.jpowsour.2010.06.084
12. Modestino, M. A.; Walczak, K. A.; Berger, A.; Evans, C. M.; Haussener, S.; Koval, C.; Newman, J. S.; Ager, J. W.; Segalman, R. A. Robust production of purified H2 in a stable, self-regulating, and continuously operating solar fuel generator Energy Environ. Sci. 2014, 7, 297 10.1039/C3EE43214A
13. Sangoro, J. R.; Iacob, C.; Agapov, A. L.; Wang, Y.; Berdzinski, S.; Rexhausen, H.; Strehmel, V.; Friedrich, C.; Sokolov, A. P.; Kremer, F. Decoupling of ionic conductivity from structural dynamics in polymerized ionic liquids Soft Matter 2014, 10, 3536-3540 10.1039/c3sm53202j
14. He, H.; Luebke, D.; Nulwala, H.; Matyjaszewski, K. Synthesis of Poly(ionic liquid)s by Atom Transfer Radical Polymerization with ppm of Cu Catalyst Macromolecules 2014, 47, 6601-6609 10.1021/ma501487u
15. Choi, U. H.; Ye, Y.; Salas de la Cruz, D.; Liu, W.; Winey, K. I.; Elabd, Y. A.; Runt, J.; Colby, R. H. Dielectric and Viscoelastic Responses of Imidazolium-Based Ionomers with Different Counterions and Side Chain Lengths Macromolecules 2014, 47, 777-790 10.1021/ma402263y
16. Choi, U. H.; Mittal, A.; Price, T. L.; Lee, M.; Gibson, H. W.; Runt, J.; Colby, R. H. Molecular Volume Effects on the Dynamics of Polymerized Ionic Liquids and their Monomers Electrochim. Acta 2015, 175, 55 10.1016/j.electacta.2014.12.140
17. Choi, U. H.; Lee, M.; Wang, S.; Liu, W.; Winey, K. I.; Gibson, H. W.; Colby, R. H. Ionic Conduction and Dielectric Response of Poly(imidazolium acrylate) Ionomers Macromolecules 2012, 45, 3974-3985 10.1021/ma202784e
18. Smith, T. W.; Zhao, M.; Yang, F.; Smith, D.; Cebe, P. Imidazole Polymers Derived from Ionic Liquid 4-Vinylimidazolium Monomers: Their Synthesis and Thermal and Dielectric Properties Macromolecules 2013, 46, 1133-1143 10.1021/ma300862t
19. Nakamura, K.; Fukao, K.; Inoue, T. Dielectric Relaxation and Viscoelastic Behavior of Polymerized Ionic Liquids with Various Counteranions Macromolecules 2012, 45, 3850-3858 10.1021/ma300040b
20. Nakamura, K.; Saiwaki, T.; Fukao, K.; Inoue, T. Viscoelastic Behavior of the Polymerized Ionic Liquid Poly(1-ethyl-3-vinylimidazolium bis(trifluoromethanesulfonylimide)) Macromolecules 2011, 44, 7719-7726 10.1021/ma201611q
21. Nakamura, K.; Saiwaki, T.; Fukao, K. Dielectric Relaxation Behavior of Polymerized Ionic Liquid Macromolecules 2010, 43, 6092-6098 10.1021/ma100918e
22. 2 separation from the flue gas Green Chem. 2012, 14, 1052 10.1039/c2gc16354c
23. Weber, R. L.; Ye, Y.; Schmitt, A. L.; Banik, S. M.; Elabd, Y. A.; Mahanthappa, M. K. Effect of Nanoscale Morphology on the Conductivity of Polymerized Ionic Liquid Block Copolymers Macromolecules 2011, 44, 5727-5735 10.1021/ma201067h
24. Green, M. D.; Long, T. E. Designing Imidazole-Based Ionic Liquids and Ionic Liquid Monomers for Emerging Technologies Polym. Rev. 2009, 49, 291-314 10.1080/15583720903288914
25. Marcilla, R.; Blazquez, J. A.; Rodriguez, J.; Pomposo, J. A.; Mecerreyes, D. Tuning the solubility of polymerized ionic liquids by simple anion-exchange reactions J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 208 10.1002/pola.11015
26. Choi, J. H.; Xie, W.; Gu, Y.; Frisbie, C. D.; Lodge, T. P. Single Ion Conducting, Polymerized Ionic Liquid Triblock Copolymer Films: High Capacitance Electrolyte Gates for n-type Transistors ACS Appl. Mater. Interfaces 2015, 7, 7294 10.1021/acsami.5b00495
27. Nykaza, J. R.; Ye, Y.; Elabd, Y. A. Polymerized ionic liquid diblock copolymers with long alkyl side-chain length Polymer 2014, 55, 3360 10.1016/j.polymer.2014.04.003
28. Schneider, Y.; Modestino, M. A.; McCulloch, B. L.; Hoarfrost, M. L.; Hess, R. W.; Segalman, R. A. Ionic Conduction in Nanostructured Membranes Based on Polymerized Protic Ionic Liquids Macromolecules 2013, 46, 1543-1548 10.1021/ma3024624
29. Ye, Y.; Choi, J.-H.; Winey, K. I.; Elabd, Y. A. Polymerized Ionic Liquid Block and Random Copolymers: Effect of Weak Microphase Separation on Ion Transport Macromolecules 2012, 45, 7027-7035 10.1021/ma301036b
30. Fan, F.; Wang, Y.; Hong, T.; Heres, M. F.; Saito, T.; Sokolov, A. P. Ion Conduction in Polymerized Ionic Liquids with Different Pendant Groups Macromolecules 2015, 48, 4461 10.1021/acs.macromol.5b00257
31. Chen, H.; Choi, J.-H.; Salas-de la Cruz, D.; Winey, K. I.; Elabd, Y. A. Polymerized Ionic Liquids: The Effect of Random Copolymer Composition on Ion Conduction Macromolecules 2009, 42, 4809-4816 10.1021/ma900713e
32. Choi, U. H.; Liang, S.; O'Reilly, M. V.; Winey, K. I.; Runt, J.; Colby, R. H. Influence of Solvating Plasticizer on Ion Conduction of Polysiloxane Single-Ion Conductors Macromolecules 2014, 47, 3145-3153 10.1021/ma500146v
33. Kim, O.; Kim, S. Y.; Park, B.; Hwang, W.; Park, M. J. Factors Affecting Electromechanical Properties of Ionic Polymer Actuators Based on Ionic Liquid-Containing Sulfonated Block Copolymers Macromolecules 2014, 47, 4357-4368 10.1021/ma500869h
34. Liang, S.; O'Reilly, M. V.; Choi, U. H.; Shiau, H.-S.; Bartels, J.; Chen, Q.; Runt, J.; Winey, K. I.; Colby, R. H. High Ion Content Siloxane Phosphonium Ionomers with Very LowTg Macromolecules 2014, 47, 4428-4437 10.1021/ma5001546
35. Adrjanowicz, K.; Kaminski, K.; Dulski, M.; Jasiurkowska-Delaporte, M.; Kolodziejczyk, K.; Jarek, M.; Bartkowiak, G.; Hawelek, L.; Jurga, S.; Paluch, M. Dynamic Glass Transition and Electrical Conductivity Behavior Dominated by Proton Hopping Mechanism Studied in the Family of Hyperbranched Bis-MPA Polyesters Macromolecules 2014, 47, 5798-5807 10.1021/ma5006155
36. Liu, L.; Li, Q.; Dai, J.; Wang, H.; Jin, B.; Bai, R. A facile strategy for the synthesis of guanidinium-functionalized polymer as alkaline anion exchange membrane with improved alkaline stability J. Membr. Sci. 2014, 453, 52-60 10.1016/j.memsci.2013.10.054
37. Yuan, J.; Mecerreyes, D.; Antonietti, M. Poly(ionic liquid)s: An update Prog. Polym. Sci. 2013, 38, 1009-1036 10.1016/j.progpolymsci.2013.04.002
38. Liang, S.; Choi, U. H.; Liu, W.; Runt, J.; Colby, R. H. Synthesis and Lithium Ion Conduction of Polysiloxane Single-Ion Conductors Containing Novel Weak-Binding Borates Chem. Mater. 2012, 24, 2316-2323 10.1021/cm3005387
39. Wang, W.; Tudryn, G. J.; Colby, R. H.; Winey, K. I. Thermally driven ionic aggregation in poly(ethylene oxide)-based sulfonate ionomers J. Am. Chem. Soc. 2011, 133, 10826-10831 10.1021/ja201405v
40. Lu, M.; Runt, J.; Painter, P. An Infrared Spectrocopic Study of a Polyester Copolymer Ionomer Based on Poly(ethylene oxide) Macromolecules 2009, 42, 6581-6587 10.1021/ma900978d
41. Ohno, H.; Ito, K. Room-temperature molten salt polymers as a matrix for fast ion conduction Chem. Lett. 1998, 751 10.1246/cl.1998.751
42. Bolintineanu, D. S.; Stevens, M. J.; Frischknecht, A. L. Atomistic Simulations Predict a Surprising Variety of Morphologies in Precise Ionomers ACS Macro Lett. 2013, 2, 206-210 10.1021/mz300611n
43. Bolintineanu, D. S.; Stevens, M. J.; Frischknecht, A. L. Influence of Cation Type on Ionic Aggregates in Precise Ionomers Macromolecules 2013, 46, 5381-5392 10.1021/ma400848m
44. Hall, L. M.; Seitz, M. E.; Winey, K. I.; Opper, K. L.; Wagener, K. B.; Stevens, M. J.; Frischknecht, A. L. Ionic aggregate structure in ionomer melts: effect of molecular architecture on aggregates and the ionomer peak J. Am. Chem. Soc. 2012, 134, 574-587 10.1021/ja209142b
45. Noda, A.; Susan, M. A. B. H.; Kudo, K.; Mitsushima, S.; Hayamizu, K.; Watanabe, M. Bronsted Acid-Base Ionic Liquids as Proton-Conducting Nonaqueous Electrolytes J. Phys. Chem. B 2003, 107, 4024 10.1021/jp022347p
46. Hoarfrost, M. L.; Tyagi, M.; Segalman, R. A.; Reimer, J. A. Proton hopping and long-range transport in the protic ionic liquid [Im][TFSI], probed by pulsed-field gradient NMR and quasi-elastic neutron scattering J. Phys. Chem. B 2012, 116, 8201-8209 10.1021/jp3044237
47. Hoarfrost, M. L.; Tyagi, M. S.; Segalman, R. A.; Reimer, J. A. Effect of confinement on proton transport mechanisms in block copolymer/ionic liquid membranes Macromolecules 2012, 45, 3112 10.1021/ma202741g
48. Iacob, C.; Sangoro, J. R.; Kipnusu, W. K.; Valiullin, R.; Karger, J.; Kremer, F. Enhanced charge transport in nano-confined ionic liquids Soft Matter 2012, 8, 289 10.1039/C1SM06581E
49. Kim, S. Y.; Kim, S.; Park, M. J. Enhanced proton transport in nanostructured polymer electrolyte/ionic liquid membranes under water-free conditions Nat. Commun. 2010, 1, 88-93 10.1038/ncomms1086
50. Di Noto, V.; Vittadello, M.; Lavina, S.; Fauri, M.; Biscazzo, S. Mechanism of ionic conductivity in poly(ethyleneglycol 400)/(LiCl)x Electrolyte Complexes: Studies based on electrical spectroscopy J. Phys. Chem. B 2001, 105, 4584 10.1021/jp0103934
51. Fukao, K.; Miyamoto, Y. Slow dynamics near glass transitions in thin polymer films Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top. 2001, 64, 011803 10.1103/PhysRevE.64.011803
52. Zhang, C.; Guo, Y.; Shepard, K. B.; Priestley, R. D. Fragility of an Isochorically Confined Polymer Glass J. Phys. Chem. Lett. 2013, 4, 431-436 10.1021/jz302002v
53. Arndt, M.; Stannarius, R.; Gorbatschow, W.; Kremer, F. Dielectric investigations of the dynamic glass transition in nanopores Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top. 1996, 54, 5377 10.1103/PhysRevE.54.5377
54. Dudowicz, J.; Freed, K. F.; Douglas, J. F. Fragility of glass-forming polymer liquids J. Phys. Chem. B 2005, 109, 21350 10.1021/jp053693k
55. Riggleman, R. A.; Yoshimoto, K.; Douglas, J. F.; de Pablo, J. J. Influence of Confinement on the Fragility of Antiplasticized and Pure Polymer Films Phys. Rev. Lett. 2006, 97, 045502 10.1103/PhysRevLett.97.045502
56. Evans, C. M.; Deng, H.; Jager, W. F.; Torkelson, J. M. Fragility is a Key Parameter in Determining the Magnitude ofTg-Confinement Effects in Polymer Films Macromolecules 2013, 46, 6091-6103 10.1021/ma401017n
57. Hoarfrost, M. L.; Segalman, R. A. Conductivity Scaling Relationships for Nanostructured Block Copolymer/Ionic Liquid Membranes ACS Macro Lett. 2012, 1, 937-943 10.1021/mz300241g
58. Hoarfrost, M. L.; Segalman, R. A. Ionic Conductivity of Nanostructured Block Copolymer/Ionic Liquid Membranes Macromolecules 2011, 44, 5281-5288 10.1021/ma200060g
59. Evans, C. M.; Narayanan, S.; Jiang, Z.; Torkelson, J. M. Modulus, Confinement, and Temperature Effects on Surface Capillary Wave Dynamics in Bilayer Polymer Films Near the Glass Transition Phys. Rev. Lett. 2012, 109, 038302 10.1103/PhysRevLett.109.038302
60. Semenov, A. N. Theory of block-copolymer interfaces in the strong segregation limit Macromolecules 1993, 26, 6617-6621 10.1021/ma00076a047