Enhanced photo-oxidation of formaldehyde on highly reduced o-TiO2(110)

Journal of Physical Chemistry C

Volumn 118, Issue 50, 2014, Pages 29242-29251

  Cremer, Till ^a   Jensen, Stephen C ^a   Friend, Cynthia M ^a,b  

^a HARVARD UNIVERSITY   (United States)

^b HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADATOMS; CARBON DIOXIDE; DENSITY FUNCTIONAL THEORY; FORMALDEHYDE; OXIDATION; OXIDE MINERALS; OXYGEN; OXYGEN VACANCIES; REACTION INTERMEDIATES; SCANNING TUNNELING MICROSCOPY; TITANIUM DIOXIDE;

ATMOSPHERIC POLLUTANTS; DEGREE OF REDUCTION; ELECTRON HOLE PAIRS; INTERSTITIAL DEFECTS; NEAR SURFACE REGIONS; PHOTO-DECOMPOSITION; PHOTOEFFICIENCY; TEMPERATURE-PROGRAMMED REACTION SPECTROSCOPIES;

SURFACE DEFECTS;

EID: 84949146737     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp5053908     Document Type: Article

References (66)

1. 2 Photocatalysis Surf. Sci. Rep. 2011, 66, 185-297
2. 2 Photocatalysts in Green Chemistry Pure Appl. Chem. 2000, 72, 1265-1270
3. Fujishima, A.; Honda, K. Electrochemical Photolysis of Water at a Semiconductor Electrode Nature 1972, 238, 37-38
4. 2 For Hydrogen Production Renewable Sustainable Energy Rev. 2007, 11, 401-425
5. 2 Capture in Amine-Based Aqueous Solution: Role of the Gas-Solution Interface Angew. Chem., Int. Ed. 2011, 50, 10178-10181
6. Ghosal, S.; Hemminger, J. C.; Bluhm, H.; Mun, B. S.; Hebenstreit, E. L. D.; Ketteler, G.; Ogletree, D. F.; Requejo, F. G.; Salmeron, M. Electron Spectroscopy of Aqueous Solution Interfaces Reveals Surface Enhancement of Halides Science 2005, 307, 563-566
7. 2 Nanoparticles Decorated on Step Edges of HOPG ACS Nano 2011, 5, 6325-6333
8. Hemminger, J.;; Crabtree, G.;; Sarrao, J. From Quanta to the Continuum: Opportunities for Mesoscale Science. U. S. Department of Energy: Washington, DC, 2012.
9. 2(110) Surf. Rev. Lett. 2000, 07, 613-617
10. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229
11. Reuss, F.; Disteldorf, W.; Gamer, A. O.; Hilt, A. Formaldehyde; Wiley-VCH: Weinheim, Germany, 2000.
12. Korzeniewski, C.; Childers, C. L. Formaldehyde Yields From Methanol Electrochemical Oxidation on Platinum J. Phys. Chem. B 1998, 102, 489-492
13. Aurian-Blajeni, B.; Halmann, M.; Manassen, J. Photoreduction of Carbon Dioxide and Water Into Formaldehyde and Methanol on Semiconductor Materials Sol. Energy 1980, 25, 165-170
14. 2(110) J. Am. Chem. Soc. 2013, 135, 574-577
15. 2(110), Initiated by Methanol Photocatalysis at 400 Nm J. Phys. Chem. C 2013, 117, 5293-5300
16. 2(110) Surface J. Am. Chem. Soc. 2013, 135, 5212-5219
17. 2 J. Phys. Chem. C 2012, 116, 21508-21513
18. 2 Rutile and Anatase Surfaces Toward Nitroaromatics J. Am. Chem. Soc. 2010, 132, 64-66
19. 2(110): Production and Chemical Detection of Active Sites J. Phys. Chem. 1994, 98, 11733-11738
20. 2(110) J. Phys. Chem. C 2007, 111, 3021-3027
21. 2(110) Surface J. Phys. Chem. B 2002, 106, 10680-10692
22. 2(110) Surface, Assisted by Bridge-Bonded Oxygen Atoms J. Phys. Chem. Lett. 2013, 4, 2668-2673
23. 18O-Labeling Studies J. Phys. Chem. 1995, 99, 15253-15261
24. 2(110) Surface J. Phys. Chem. B 1997, 101, 221-229
25. 2(110) Surfaces Toward DCOOD Decomposition J. Phys. Chem. B 2003, 107, 11709-11720
26. 2(110): Reductive C=C Coupling of Benzaldehyde Driven by Titanium Interstitials J. Am. Chem. Soc. 2009, 131, 15026-15031
27. 2(110) Reduction and Oxidation J. Phys.: Condens. Matter 2009, 21, 474224
28. 2(110) J. Phys. Chem. C 2012, 116, 18788-18795
29. 2(110) Surf. Sci. 2000, 454, 390-395
30. 2(110) Surface by Non-Contact Atomic Force Microscopy Chem. Phys. Lett. 1997, 280, 296-301
31. 2 New Photochemical Processes Chem. Rev. 2006, 106, 4428-4453
32. 2(110) Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 2391-2396
33. 2 J. Phys. Chem. Lett. 2011, 2, 2707-2710
34. 2(110) J. Am. Chem. Soc. 2012, 134, 13366-13373
35. 2(110) Phys. Rev. Lett. 2012, 109, 266103
36. 2 Undergoing Photocatalytic Oxidation of Adsorbed Alcohols: Evaluation of the Reaction Rates and Yields J. Am. Chem. Soc. 2006, 128, 416-417
37. 2 J. Phys. Chem. Lett. 2011, 2, 2223-2228
38. 2 J. Phys. Chem. C 2010, 114, 5891-5897
39. 3+ Species J. Phys. Chem. C 2009, 113, 20543-20552
40. 2 Dissociation at Vacancy Sites Surf. Sci. 1998, 412/413, 333-343
41. 2(110) Catal. Today 2012, 182, 25-38
42. 3+ Defects in the Oxygen Chemistry on Titania Surfaces J. Am. Chem. Soc. 2011, 133, 6529-6532
43. Wendt, S.; Sprunger, P. T.; Lira, E.; Madsen, G. K. H.; Li, Z.; Hansen, J. Ø.; Matthiesen, J.; Blekinge-Rasmussen, A.; Lægsgaard, E.; Hammer, B. The Role of Interstitial Sites in the Ti 3d Defect State in the Band Gap of Titania Science 2008, 320, 1755-1759
44. 2 Make or Break the Essential Reaction Intermediate on Titanium Dioxide Chem.-Eur. J. 2011, 17, 8309-8312
45. 2(001) Surfaces Catal. Lett. 1996, 40, 147-153
46. 2(110) Surf. Sci. 2008, 602, 2238-2249
47. 2 Nanoparticles J. Phys. Chem. C 2012, 116, 6623-6635
48. 2(110) Phys. Chem. Chem. Phys. 2013, 15, 5193
49. 2(110): One-Dimensional Motion in a Weakly Confined Potential Well ACS Nano 2012, 6, 2925-2930
50. 2(110) J. Phys. Chem. B 2004, 108, 18932-18941
51. 2(110): Conversion to Acetate via Methyl Radical Ejection J. Phys. Chem. B 2005, 109, 12062-12070
52. 2(110): the Extent of Molecular Versus Dissociative Adsorption Surf. Sci. 1996, 355, 151-166
53. 2(110) Surface Surf. Sci. 1994, 302, 329-340
54. 2 Single-Crystal Surfaces Langmuir 1996, 12, 5093-5098
55. Qiu, H.; Idriss, H.; Wang, Y.; Wöll, C. Carbon-Carbon Bond Formation on Model Titanium Oxide Surfaces: Identification of Surface Reaction Intermediates by High-Resolution Electron Energy Loss Spectroscopy J. Phys. Chem. C 2008, 112, 9828-9834
56. 2(110) Surface: Molecular and Dissociative Channels J. Phys. Chem. B 1999, 103, 5328-5337
57. 2(110)-(1 × 1): a Direct View at the Atomic Scale Prog. Surf. Sci. 2010, 85, 161-205
58. 2(110) ACS Nano 2011, 5, 834-843
59. 2(110) J. Phys. Chem. C 2012, 116, 16541-16552
60. 2(110) Surfaces Surf. Sci. 1997, 380, 352-364
61. 2(110) Surfaces Surf. Sci. 2003, 544, 241-260
62. 2(110) Chem. Sci. 2010, 1, 575-580
63. 2(110) Surfaces J. Phys. Chem. C 2009, 113, 1908-1916
64. 2(110) Chem.-Eur. J. 2011, 17, 4496-4506
65. 2(110) J. Am. Chem. Soc. 2013, 135, 10206-10209
66. 2(110) Chem. Rev. 2013, 113, 4428-4455