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In that respect, our methodology is akin to assembling nanocrystals using the Langmuir-Blodgett technique. See also (23).
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23
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Large arrays of belts assembled from NCs of various compositions were previously prepared by evaporation-induced assembly (24); although this method bears some similarity to our results (e.g., NC assemblies were prepared at the liquid-air interface), the mechanism of assembly (based on contact-line instabilities) is conceptually different. In fact, we did not observe the formation of any well-defined structures in the absence of an applied magnetic field (see, e.g., fig. S8J).
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The formation of helices, and the self-assembly of NCs in our system in general, is likely facilitated by entropic forces; OA used in large excess during self-assembly may act as a depletion agent, inducing crystallization of NCs during hexane evaporation as reported previously (29).
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On the basis of measurements of electrophoretic mobility [see (34)] and the lack of literature reports on electric dipole moments of magnetite nanoparticles, we did not consider electrostatic and electric dipole-dipole interactions in our analysis of interparticle interactions. At the same time, we cannot exclude the possible presence of these interactions in our system.
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