Resolving time-dependent evolution of pore-scale structure, permeability and reactivity using X-ray microtomography

Reviews in Mineralogy and Geochemistry

Volumn 80, Issue 1, 2015, Pages 247-285

  Noiriel, Catherine ^a  

^a Environmental Research Observatory (ORE) HYBAM Centre IRD d'Ile de France   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84948673434     PISSN: 15296466     EISSN: None     Source Type: Book Series    
DOI: 10.2138/rmg.2015.80.08     Document Type: Article

References (225)

1. 2-rich brine. Env Sci Technol 47:10332-10338, doi:10.1021/es401317c
2. Agbogun H M D, Al TA, Hussein E M A (2013) Three dimensional imaging of porosity and tracer concentration distributions in a dolostone sample during diffusion experiments using X-ray micro-CT. J Contam Hydrol 145:44-53, doi:10.1016/j.jconhyd.2012.11.008
3. Al-Raoush RI (2009) Impact of wettability on pore-scale characteristics of residual nonaqueous phase liquids. Env Sci Technol 43:4796-4801, doi:10.1021/es802566s
4. Al-Raoush RI (2014) Experimental investigation of the influence of grain geometry on residual NAPL using synchrotron microtomography. J Contam Hydrol 159:1-10, doi:10.1016/j.jconhyd.2014.01.008
5. Al-Raoush RI, Willson CS (2005) Extraction of physically realistic pore network properties from three-dimensional synchrotron X-ray microtomography images of unconsolidated porous media systems. J Hydrol 300:44-64, doi:10.1016/j.jhydrol.2004.05.005
6. Altman SJ, Peplinski WJ, Rivers ML (2005) Evaluation of synchrotron X-ray computerized microtomography for the visualization of transport processes in low-porosity materials. J Contam Hydrol 78:167-183
7. Anbeek C (1992) Surface roughness of minerals and implications for dissolution studies. Geochim Cosmochim Acta 56:1461-1469
8. Andrä H, Combaret N, Dvorkin J, Glatt E, Han J, Kabel M, Keehm Y, Krzikalla F, Lee M, Madonna C, Marsh M, Mukerji T, Saenger EH, Sain R, Saxena N, Ricker S, Wiegmann A, Zhan X (2013a) Digital rock physics benchmarks-Part II: Computing effective properties. Comput Geosci 50:33-43, doi:10.1016/j.cageo.2012.09.008
9. Andrä H, Combaret N, Dvorkin J, Glatt E, Han J, Kabel M, Keehm Y, Krzikalla F, Lee M, Madonna C, Marsh M, Mukerji T, Saenger EH, Sain R, Saxena N, Ricker S, Wiegmann A, Zhan X (2013b) Digital rock physics benchmarks-Part I: Imaging and segmentation. Comput Geosci 50:25-32, doi:10.1016/j. cageo.2012.09.005
10. 2. Water Resour Res 50:8760-8774, doi:10.1002/2014wr015970
11. Armstrong R, Ajo-Franklin J (2011) Investigating biomineralization using synchrotron based X-ray computed microtomography. Geophys Res Lett 38, doi:10.1029/2011gl046916
12. Armstrong RT, Porter ML, Wildenschild D (2012) Linking pore-scale interfacial curvature to column-scale capillary pressure. Adv Water Resour 46:55-62
13. Armstrong RT, Georgiadis A, Ott H, Klemin D, Berg S (2014a) Critical capillary number: Desaturation studied with fast X-ray computed microtomography. Geophys Res Lett 41:2013GL058075, doi:10.1002/2013gl058075
14. Armstrong RT, Ott H, Georgiadis A, Rücker M, Schwing A, Berg S (2014b) Subsecond pore-scale displacement processes and relaxation dynamics in multiphase flow. Water Resour Res 50:9162-9176, doi:10.1002/2014wr015858
15. Arns CH, Knackstedt MA, Pinczewski WV, Lindquist WB (2001) Accurate estimation of transport properties from microtomographic images. Geophys Res Lett 28:3361-3364, doi:10.1029/2001gl012987
16. Arns JY, Arns CH, Sheppard AP, Sok RM, Knackstedt MA, Pinczewski WV (2003) Relative permeability from tomographic images; effect of correlated heterogeneity. J Petrol Sci Eng 39:247-259, doi:10.1016/s0920-4105 (03) 00066-4
17. Arns CH, Bauget F, Limaye A, Sakellariou A, Senden TJ, Sheppard AP, Sok RM, Pinczewski WV, Bakke S, Berge LI, Oren PE, Knackstedt MA (2005) Pore-scale characterization of carbonates using X-ray microtomography. SPE J 10:475-484
18. Arvidson RS, Evren Ertan I, Amonette JE, Lüttge A (2003) Variation in calcite dissolution rates: A fundamental problem? Geochim Cosmochim Acta 67:1623-1634
19. Arzilli F, Mancini L, Voltolini M, Cicconi MR, Mohammadi S, Giuli G, Mainprice D, Paris E, Barou F, Carroll MR (2015) Near-liquidus growth of feldspar spherulites in trachytic melts: 3D morphologies and implications in crystallization mechanisms. Lithos 216:93-105, doi:10.1016/j.lithos.2014.12.003
20. Batchelor GK (1967) An Introduction to Fluid Dynamics. Cambridge University press
21. Bauer D, Youssef S, Fleury M, Bekri S, Rosenberg E, Vizika O (2012) Improving the estimations of petrophysical transport behavior of carbonate rocks using a dual pore network approach combined with computed microtomography. Transp Porous Media 94:505-524, doi:10.1007/s11242-012-9941-z
22. Bear J (1972) Dynamics of Fluids in Porous Media. American Elsevier Publishing Company Inc.
23. Beckingham LE, Peters CA, Um W, Jones KW, Lindquist WB (2013) 2D and 3D imaging resolution tradeoffs in quantifying pore throats for prediction of permeability. Adv Water Resour 62:1-12, doi:10.1016/j. advwatres.2013.08.010
24. Bera B, Mitra SK, Vick D (2011) Understanding the micro structure of Berea Sandstone by the simultaneous use of micro-computed tomography (micro-CT) and focused ion beam-scanning electron microscopy (FIB-SEM). Micron 42:412-418, doi:10.1016/j.micron. 2010.12.002
25. Berger JM, Hubbell JH, Seltzer SM, Chang J, Coursey JS, Sukumar R, Zucker DS (2011) XCOM: Photon cross section database. http://physics.nist.gov/PhysRefData/Xcom/Text/XCOM.html.
26. Bernard D (2005) 3D quantification of pore scale geometrical changes using synchrotron computed microtomography. Oil Gas Sci Technol 60:747-762
27. Berner RA (1980) Early Diagenesis: A Theoretical Approach. Princeton University Press, NJ.
28. Betson M, Barker J, Barnes P, Atkinson T (2005) Use of synchrotron tomographic techniques in the assessment of diffusion parameters for solute transport in groundwater flow. Transp Porous Media 60:217-223, doi:10.1007/s11242-004-5737-0
29. Beucher S (1992) The watershed transformation applied to image segmentation. Scanning Microscopy International suppl. 6, Cambridge, p 299-314
30. Bijeljic B, Mostaghimi P, Blunt MJ (2013a) Insights into non-Fickian solute transport in carbonates. Water Resour Res 49:2714-2728
31. Bijeljic B, Raeini A, Mostaghimi P, Blunt MJ (2013b) Predictions of non-Fickian solute transport in different classes of porous media using direct simulation on pore-scale images. Phys Rev E: Stat Nonlinear Soft Matter Phys 87:013011, doi:10.1103/PhysRevE.87.013011
32. Blunt MJ, Bijeljic B, Dong H, Gharbi O, Iglauer S, Mostaghimi P, Paluszny A, Pentland C (2013) Pore-scale imaging and modelling. Adv Water Resour 51:197-216, doi:10.1016/j.advwatres.2012.03.003
33. Bourbié T, Zinszner B (1985) Hydraulic and acoustic properties as function of porosity in Fontainebleau sandstones. J Geophys Res 90:11524-11532
34. Brantley SL (2008) Kinetics of Mineral Dissolution. In: Kinetics of Water-Rock Interaction. Brantley SL, Kubicki JD, White AF, (eds). Springer, New York, p 151-210
35. Brisard S, Chae RS, Bihannic I, Michot L, Guttmann P, Thieme J, Schneider G, Monteiro P J M, Levitz P (2012) Morphological quantification of hierarchical geomaterials by X-ray nano-CT bridges the gap from nano to micro length scales. Am Mineral 97:480-483, doi:10.2138/am.2012.3985
36. Brown SR, Scholz CH (1985) Broad bandwidth study of the topography of natural rock surfaces. J Geophys Res 90:12575-12582
37. Brunauer S, Emmet PH, Teller EA (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309-319
38. Burlion N, Bernard D, Chen D (2006) X-ray microtomography: Application to microstructure analysis of a cementitious material during leaching process. Cem Concr Res 36:346-357
39. Cai R, Lindquist WB, Um W, Jones KW (2009) Tomographic analysis of reactive flow induced pore structure changes in column experiments. Adv Water Resour 32:1396-1403, doi:10.1016/j.advwatres.2009.06.006
40. Cama J, Zhang L, Soler JM, De Giudici G, Arvidson RS, Luttge A (2010) Fluorite dissolution at acidic pH: In situ AFM and ex situ VSI experiments and Monte Carlo simulations. Geochim Cosmochim Acta 74:4298-4311, doi:10.1016/j.gca.2010.04.067
41. Carlson WD (2006) Three-dimensional imaging of earth and planetary materials. Earth Planet Sci Lett 249:133-147
42. Carlson WD, Rowe T, Ketcham RA, Colbert MW (2003) Applications of high-resolution X-ray computed tomography in petrology, meteoritics and palaeontology. In: Applications of X-ray Computed Tomography in the Geosciences. Mees F, Swennen R, Van Geet M, Jacobs P (eds) Geological Society Special Publication 215, p7-22
43. Carman PC (1937) Fluid flow through granular beds. Trans Inst Chem Eng 15:150-166
44. Carminati A, Kaestner A, Lehmann P, Fluhler H (2008) Unsaturated water flow across soil aggregate contacts. Adv Water Resour 31:1221-1232, doi:10.1016/j.advwatres.2008.01.008
45. 2-rock interactions within Weyburn-Midale carbonate flow units. Int J Greenhouse Gas Control 16:185-193
46. Celauro JG, Torrealba VA, Karpyn ZT, Klise KA, McKenna SA (2014) Pore-scale multiphase flow experiments in bead packs of variable wettability. Geofluids 14:95-105, doi:10.1111/gfl.12045
47. Chen C, Packman AI, Gaillard J-F (2008) Pore-scale analysis of permeability reduction resulting from colloid deposition. Geophys Res Lett 35:L07404 doi:10.1029/2007gl033077
48. Chen C, Packman AI, Zhang D, Gaillard J-F (2010) A multi-scale investigation of interfacial transport, pore fluid flow, and fine particle deposition in a sediment bed. Water Resour Res 46:W11560, doi:10.1029/2009wr009018
49. Chou L, Garrels RM, Wollast R (1989) Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals. Chem Geol 78:269-282
50. Cilona A, Faulkner DR, Tondi E, Agosta F, Mancini L, Rustichelli A, Baud P, Vinciguerra S (2014) The effects of rock heterogeneity on compaction localization in porous carbonates. J Struct Geol 67:75-93, doi:10.1016/j.jsg.2014.07.008
51. Cloetens P, Ludwig W, Baruchel J, Guigay JP, Pernot-Rejmankova P, Salome-Pateyron M, Schlenker M, Buffiere JY, Maire E, Peix G (1999) Hard X-ray phase imaging using simple propagation of a coherent synchrotron radiation beam. J Phys D-Appl Phys 32:A145-A151, doi:10.1088/0022-3727/32/10a/330
52. Cnudde V, Boone MN (2013) High-resolution X-ray computed tomography in geosciences: A review of the current technology and applications. Earth Sci Rev 123:1-17, doi:10.1016/j.earscirev. 2013.04.003
53. Coles ME, Hazlett RD, Muegge EL, Jones KW, Andrews B, Dowd B, Siddons P, Peskin A (1996) Developments of synchrotron X-ray microtomography with applications to flow in porous media. Vol SPE 36531, p 1-12
54. Colombani J (2008) Measurement of the pure dissolution rate constant of a mineral in water. Geochim Cosmochim Acta 72:5634-5640, doi:10.1016/j.gca.2008.09.007
55. Crandall D, Ahmadi G, Smith DH (2010a) Computational Modeling of Fluid Flow through a Fracture in Permeable Rock. Transp Porous Media 84:493-510, doi:10.1007/s11242-009-9516-9
56. Crandall D, Bromhal G, Karpyn ZT (2010b) Numerical simulations examining the relationship between wallroughness and fluid flow in rock fractures Int J Rock Mech Min Sci 47:784-796
57. Crandell LE, Peters CA, Um W, Jones KW, Lindquist WB (2012) Changes in the pore network structure of Hanford sediment after reaction with caustic tank wastes. J Contam Hydrol 131:89-99, doi:10.1016/j. jconhyd.2012.02.002
58. 2 Storage and EOR in Carbonate Reservoirs. Rev Mineral Geochem 77:431-458
59. Culligan KA, Wildenschild D, Christensen B S B, Gray WG, Rivers ML, Tompson A F B (2004) Interfacial area measurements for unsaturated flow through a porous medium. Water Resour Res 40:W12413, doi:10.1029/2004wr003278
60. Daccord G, Lietard O, Lenormand R (1993) Chemical dissolution of a porous medium by a reactive fluid: 1. model for the wormholing phenomenon. Chem Eng Sci 48:169-178
61. Dalla E, Hilpert M, Miller CT (2002) Computation of the interfacial area for two-fluid porous medium systems. J Contam Hydrol 56:25-48, doi: 10.1016/s0169-7722 (01) 00202-9
62. Dann R, Turner M, Close M, Knackstedt M (2011) Multi-scale characterisation of coastal sand aquifer media for contaminant transport using X-ray computed tomography. Env Earth Sci 63:1125-1137, doi:10.1007/s12665-010-0788-8
63. Dautriat J, Gland N, Dimanov A, Raphanel J (2009) Hydromechanical behavior of heterogeneous carbonate rock under proportional triaxial loadings. J Geophys Res B: Solid Earth 116:B01205, doi:10.1029/2009jb000830
64. Davit Y, Iltis G, Debenest G, Veran-Tissoires S, Wildenschild D, Gerino M, Quintard M (2010) Imaging biofilm in porous media using X-ray computed microtomography. J Microsc 242:15-25, doi:10.1111/j.1365-2818.2010.03432.x
65. DeCarlo KF, Shokri N (2014) Salinity effects on cracking morphology and dynamics in 3D desiccating clays. Water Resour Res 50:3052-3072, doi:10.1002/2013wr014424
66. 2-acidified brine flow. Energy & Fuels 27:4221-4231, doi:10.1021/ef302041s
67. Dewanckele J, De Kock T, Boone MA, Cnudde V, Brabant L, Boone MN, Fronteau G, Van Hoorebeke L, Jacobs P (2012) 4D imaging and quantification of pore structure modifications inside natural building stones by means of high resolution X-ray CT. Sci Total Environ 416:436-448, doi:10.1016/j.scitotenv. 2011.11.018
68. Dierick M, Masschaele B, Van Hoorebeke L (2004) Octopus, a fast and user-friendly tomographic reconstruction package developed in LabView (R). Meas Sci Technol 15:1366-1370, doi:10.1088/0957-0233/15/7/020
69. Dove PM, Platt FM (1996) Compatible real-time reaction rates for in situ imaging of mineral-water interactions using scanning force microscopy. Chem Geol 127:331-338
70. Egan CK, Jacques S D M, Connolley T, Wilson MD, Veale MC, Seller P, Cernik RJ (2014) Dark-field hyperspectral X-ray imaging. Proc R Soc A 470:20130629, doi:10.1098/rspa.2013.0629
71. Elliott JC, Dover SD (1982) X-ray microtomography. J Microsc 126:211-213
72. 2-acidified brine flow. Greenhouse Gas Sci Technol 1:248-260, doi:10.1002/ghg.25
73. Ellis BR, Fitts JP, Bromhal GS, McIntyre DL, Tappero R, Peters CA (2013) Dissolution-driven permeability reduction of a fractured carbonate caprock. Environ Eng Sci 30:187-193, doi:10.1089/ees.2012.0337
74. Emmanuel S (2014) Mechanisms influencing micron and nanometer-scale reaction rate patterns during dolostone dissolution. Chem Geol 363:262-269, doi:10.1016/j.chemgeo.2013.11.002
75. Enzmann F, Kersten M, Kienzler B (2004a) Microscale modeling of fluid transport in fractured granite using a lattice Boltzmann method with X-ray computed tomography data. LBNL Report 54275:300-304, LBNL, Berkeley, CA, USA
76. Enzmann F, Kersten M, Stampanoni M (2004b) Synchrotron-based microtomography of geological samples for modeling fluid transport in real pore space. Proceeding of the Second International Symposium on Dynamics of Fluid in Fractured Rocks, February 10-12, 2004, Berkeley, California: 114-119
77. Fischer C, Luttge A (2007) Converged surface roughness parameters - A new tool to quantify rock surface morphology and reactivity alteration. Am J Sci 307:955-973, doi:10.2475/07.2007.01
78. Flannery BP, Deckman HW, Roberge WG, Damico KL (1987) 3-dimensional X-ray microtomography. Science 237:1439-1444, doi:10.1126/science.237.4821.1439
79. 2 saturated water flow in real rocks: Principles and first results. Chem Geol 265:171-180
80. Fonseca J, O'Sullivan C, Coop MR, Lee PD (2012) Non-invasive characterization of particle morphology of natural sands. Soils and Foundations 52:712-722, doi:10.1016/j.sandf.2012.07.011
81. Fredrich JT, Digiovanni AA, Noble DR (2006) Predicting macroscopic transport properties using microscopic image data. J Geophys Res B: Solid Earth 111:B03201, doi:03210.01029/02005JB003774
82. Gaillard JF, Chen C, Stonedahl SH, Lau B L T, Keane DT, Packman AI (2007) Imaging of colloidal deposits in granular porous media by X-ray difference micro-tomography. Geophys Res Lett 34:L18404 doi: 18410.11029/12007GL030514
83. Gautier JM, Oelkers EH, Schott J (2001) Are quartz dissolution rates proportional to BET surface areas? Geochim Cosmochim Acta 65:1059-1070
84. Ghosh J, Tick GR (2013) A pore scale investigation of crude oil distribution and removal from homogeneous porous media during surfactant-induced remediation. J Contam Hydrol 155:20-30, doi:10.1016/j. jconhyd.2013.09.003
85. Golfier F, Zarcone C, Bazin B, Lenormand R, Lasseux D, Quintard M (2002) On the ability of a Darcyscale model to capture wormhole formation during the dissolution of a porous medium. J Fluid Mech 457:213-254
86. Gonzales RC, Woods RE (1992) Digital Image Processing. Addison-Wesley Publishing Company, Reading, Massachusetts
87. Gouze P, Luquot L (2011) X-ray microtomography characterization of porosity, permeability and reactive surface changes during dissolution. J Contam Hydrol 120-21:45-55, doi:10.1016/j.jconhyd.2010.07.004
88. Gouze P, Noiriel C, Bruderer C, Loggia D, Leprovost R (2003) X-Ray tomography characterisation of fracture surfaces during dissolution. Geophys Res Lett 30:1267, doi:1210.1029/2002/GL016755
89. Gouze P, Melean Y, Le Borgne T, Dentz M, Carrera J (2008) Non-Fickian dispersion in porous media explained by heterogeneous microscale matrix diffusion. Water Resour Res 44:W11416, doi:10.1029/2007wr006690
90. Hall SA, Bornert M, Desrues J, Pannier Y, Lenoir N, Viggiani G, Besuelle P (2010) Discrete and continuum analysis of localised deformation in sand using X-ray mu CT and volumetric digital image correlation. Geotechnique 60:315-322, doi:10.1680/geot.2010.60.5.315
91. Hébert V, Garing C, Luquot L, Pezard PA, Gouze P (2015) Multi-scale X-ray tomography analysis of carbonate porosity. In: Fundamental Controls on Fluid Flow in Carbonates: Current Workflows to Emerging Technologies. Vol 409. Agar SM, Geiger S (eds) Geological Society London, p 61-79
92. Herman GT (1980) Image Reconstruction from Projections: Fundamentals of Computerized Tomography. Academic Press, New York
93. Higo Y, Oka F, Sato T, Matsushima Y, Kimoto S (2013) Investigation of localized deformation in partially saturated sand under triaxial compression using microfocus X-ray CT with digital image correlation. Soils and Foundations 53:181-198, doi:10.1016/j.sandf.2013.02.001
94. Hilgers C, Urai JL (2002) Experimental study of syntaxial vein growth during lateral fluid flow in transmitted light: first results. J Struct Geol 24:1029-1043, doi:10.1016/s0191-8141 (01) 00089-x
95. Hillner PE, Gratz AJ, Manne S, Hasma PK (1992) Atomic-scale imaging of calcite growth and dissolution in real time. Geology 20:359-362
96. Hodson ME (2006) Does reactive surface area depend on grain size? Results from pH 3, 25°C far-fromequilibrium flow-through dissolution experiments on anorthite and biotite. Geochim Cosmochim Acta 70:1655-1667
97. Hoefner ML, Fogler HS (1998) Pore evolution and channel formation during flow and reaction in porous media. AIChE Journal 34:45-53
98. Iassonov P, Gebrenegus T, Tuller M (2009) Segmentation of X-ray computed tomography images of porous materials: A crucial step for characterization and quantitative analysis of pore structures. Water Resour Res 45:W09415, doi:10.1029/2009wr008087
99. 2 imaged with X-ray micro-tomography. Geophys Res Lett 38:L21403, doi:10.1029/2011gl049680
100. Iltis GC, Armstrong RT, Jansik DP, Wood BD, Wildenschild D (2011) Imaging biofilm architecture within porous media using synchrotron-based X-ray computed microtomography. Water Resour Res 47:W02601, doi:10.1029/2010wr009410
101. 2: The COTAGES experiment. Inter J Greenhouse Gas Control 12:56-71, doi:10.1016/j.ijggc.2012.11.001
102. Jones RA, Steude JS, Castanier LM, Roberts PV (1993) Nondestructive measurements of fracture aperture in crystalline rock cores using X-ray computed tomography. J Geophys Res 98:1889-1900
103. Jung HB, Jansik D, Um W (2013) Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic Sequestration Conditions Using X-ray Computed Microtomography. Environ Sci Technol 47:283-289, doi:10.1021/es3012707
104. Kang PK, de Anna P, Nunes JP, Bijeljic B, Blunt MJ, Juanes R (2014) Pore-scale intermittent velocity structure underpinning anomalous transport through 3-D porous media. Geophys Res Lett 41:6184-6190, doi:10.1002/2014gl061475
105. Karpyn ZT, Piri M (2007) Prediction of fluid occupancy in fractures using network modeling and x-ray microtomography. I: Data conditioning and model description. Phys Rev E: Stat Nonlinear Soft Matter Phys 76, doi:10.1103/PhysRevE.76.016315
106. Karpyn ZT, Grader AS, Halleck PM (2007) Visualization of fluid occupancy in a rough fracture using microtomography. J Colloid Interface Sci 307:181-187
107. Kaszuba J, Yardley B, Andreani M (2013) Experimental perspectives of mineral dissolution and precipitation due to carbon dioxide-water-rock interactions. Rev Mineral Geochem 77:153-188
108. Keller A (1998) High resolution, non-destructive measurement and characterisation of fracture apertures. Int J Rock Mech Min Sci 35:1037-1050
109. Kim D, Lindquist WB (2013) Effects of network dissolution changes on pore-to-core upscaled reaction rates for kaolinite and anorthite reactions under acidic conditions. Water Resour Res 49:7575-7586, doi:10.1002/2013wr013667
110. King HE, Satoh H, Tsukamoto K, Putnis A (2014) Surface-specific measurements of olivine dissolution by phase-shift interferometry. Am Mineral 99:377-386, doi:10.2138/am.2014.4606
111. 2 flow through a layered silica sand/calcite sand system: Experiment and modified maximal inscribed spheres analysis. Inter J Greenhouse Gas Control 14:141-150, doi:10.1016/j.ijggc.2012.12.031
112. Koestel J, Larsbo M (2014) Imaging and quantification of preferential solute transport in soil macropores. Water Resour Res 50:4357-4378, doi:10.1002/2014wr015351
113. Köhler S, Dufaud F, Oelkers EH (2003) An experimental study of illite dissolution rates as a function of pH from 1.4 to 12.4 and temperature from 5 to 50°C. Geochim Cosmochim Acta 67:3583-3594
114. 2 mineralization. Chem Geol 318:113-125, doi:10.1016/j. chemgeo.2012.05.010
115. Landry CJ, Karpyn ZT, Ayala O (2014) Pore-Scale Lattice Boltzmann Modeling and 4D X-ray Computed Microtomography Imaging of Fracture-Matrix Fluid Transfer. Transp Porous Media 103:449-468, doi:10.1007/s11242-014-0311-x
116. Lasaga AC, Kirkpatrick RJ (eds) (1981) Kinetics of Geochemical Processes. Rev Mineral 8
117. Lemelle L, Simionovici A, Truche R, Rau C, Chukalina M, Gillet P (2004) A new nondestructive X-ray method for the determination of the 3D mineralogy at the micrometer scale. Am Mineral 89:547-553
118. Lenoir N, Bornert M, Desrues J, Besuelle P, Viggiani G (2007) Volumetric digital image correlation applied to X-ray microtomography images from triaxial compression tests on argillaceous rock. Strain 43:193-205, doi:10.1111/j.1475-1305.2007.00348.x
119. Levenson Y, Emmanuel S (2014) Pore-scale heterogeneous reaction rates on a dissolving limestone surface. Geochim Cosmochim Acta 119:188-197, doi:10.1016/j.gca.2013.05.024
120. Li L, Peters CA, Celia MA (2006) Upscaling geochemical reaction rates using pore-scale network modeling. Adv Water Resour 29:1351-1370, doi:10.1016/j.advwatres.2005.10.011
121. Li L, Peters CA, Celia MA (2007) Effects of mineral spatial distribution on reaction rates in porous media. Water Resour Res 43:W01419, doi10.1029/2005WR004848
122. Li L, Steefel CI, Yang L (2008) Scale dependence of mineral dissolution rates within single pores and fractures. Geochim Cosmochim Acta 72:360-377
123. Li L, Salehikhoo F, Brantley SL, Heidari P (2013) Spatial zonation limits magnesite dissolution in porous media. Geochim Cosmochim Acta 126:555-573, doi:10.1016/j.gca.2013.10.051
124. Lind OC, De Nolf W, Janssens K, Salbu B (2013) Micro-analytical characterisation of radioactive heterogeneities in samples from Central Asian TENORM sites. J Environ Radioact 123:63-70, doi:10.1016/j.jenvrad.2012.02.012
125. Lindquist WB, Lee S, Coker DA, Jones KW, Spanne P (1996) Medial axis analysis of void structure in three-dimensional tomographic image of porous media. J Geophys Res 101:8297-8310
126. Lindquist WB, Venkatarangan A, Dunsmuir J, Wong T (2000) Pore and throat size distributions measured from synchrotron X-ray tomographic images of Fontainebleau sandstones. J Geophys Res 105:21509-21527
127. Liu C, Liu Y, Kerisit S, Zachara J (2015) Pore-scale process coupling and effective surface reaction rates in heterogeneous subsurface materials. Rev Mineral Geochem 80:191-216
128. Lorensen WE, Cline HE (1987) Marching cubes: a high resolution 3D surface construction algorithm. Comput Graphics 21:164-169
129. 2 trapping mechanism. Environ Sci Technol 47:242-251
130. 2-charged brine at 100 degrees C and 150 bar: Evolution of porosity, permeability, and reactive surface area. Chem Geol 380:145-160, doi:10.1016/j.chemgeo.2014.05.001
131. 2 into carbonate rocks. Chem Geol 265:148-159, doi:10.1016/j.chemgeo.2009.03.028
132. 2 percolation experiment through chlorite/zeolite-rich sandstone (Pretty Hill Formation - Otway Basin-Australia). Chem Geol 294:75-88, doi:10.1016/j. chemgeo.2011.11.018
133. 2-rich brine. Inter J Greenhouse Gas Control 16:167-179, doi:10.1016/j. ijggc.2013.04.002
134. Luquot L, Roetting TS, Carrera J (2014a) Characterization of flow parameters and evidence of pore clogging during limestone dissolution experiments. Water Resour Res 50:6305-6321, doi:10.1002/2013wr015193
135. Luquot L, Rodriguez O, Gouze P (2014b) Experimental characterization of porosity structure and transport property changes in limestone undergoing different dissolution regimes. Transp Porous Media 101:507-532, doi:10.1007/s11242-013-0257-4
136. Lüttge A, Bolton EW, Lasaga AC (1999) An interferometric study of the dissolution kinetics of anorthite: The role of reactive surface area. Am J Sci 299:652-678
137. Lüttge A, Winkler U, Lasaga AC (2003) An interferometric study of dolomite dissolution: A new conceptual model for mineral dissolution. Geochim Cosmochim Acta 67:1099-1116
138. Maintz JB, Viergever MA (1998) A survey of medical image registration. Med Image Anal 2:1-36, doi:10.1016/s1361-8415 (01) 80026-8
139. 2-rich injection. Geophys Res Lett 40:4614-4619, doi:10.1002/grl.50595
140. Marinoni N, Voltolini M, Mancini L, Vignola P, Pagani A, Pavese A (2009) An investigation of mortars affected by alkali-silica reaction by X-ray synchrotron microtomography: a preliminary study. J Mater Sci 44:5815-5823, doi:10.1007/s10853-009-3817-9
141. Mason HE, Walsh S D C, DuFrane WL, Carroll SA (2014) Determination of diffusion profiles in altered wellbore cement using X-ray computed tomography methods. Environ Sci Technol 48:7094-7100, doi:10.1021/es4055737
142. Mehmani Y, Balhoff MT (2015) Mesoscale and hybrid models of fluid flow and solute transport. Rev Mineral Geochem 80:433-459
143. Menon M, Yuan Q, Jia X, Dougill AJ, Hoon SR, Thomas AD, Williams RA (2010) Assessment of physical and hydrological properties of biological soil crusts using X-ray microtomography and modeling. J Hydrol 397:47-54, doi:10.1016/j.jhydrol.2010.11.021
144. Mokso R, Marone F, Haberthur D, Schittny JC, Mikuljan G, Isenegger A, Stampanoni M (2011) Following dynamic processes by X-ray tomographic microscopy with sub-second temporal resolution. 10th International Conference on X-Ray Microscopy 1365:38-41, doi:10.1063/1.3625299
145. Molins S (2015) Reactive interfaces in direct numerical simulation of pore scale processes. Rev Mineral Geochem 80:461-481
146. Molins S, Trebotich D, Yang L, Ajo-Franklin JB, Ligocki TJ, Shen CP, Steefel CI (2014) Pore-scale controls on calcite dissolution rates from flow-through laboratory and numerical experiments. Environ Sci Technol 48:7453-7460, doi:10.1021/es5013438
147. Myers NO (1962) Characterization of surface roughness. Wear 5:182-189
148. Nakashima Y, Nakano T (2012) Steady-state local diffusive fluxes in porous geo-materials obtained by porescale simulations. Transp Porous Media 93:657-673, doi:10.1007/s11242-012-9976-1
149. Narsilio GA, Buzzi O, Fityus S, Yun TS, Smith DW (2009) Upscaling of Navier-Stokes equations in porous media: Theoretical, numerical and experimental approach. Comput Geotech 36:1200-1206, doi:10.1016/j. compgeo.2009.05.006
150. Navarre-Sitchler A, Steefel CI, Yang L, Tomutsa L, Brantley SL (2009) Evolution of porosity and diffusivity associated with chemical weathering of a basalt clast. J Geophys Res F: Earth Surf 114
151. Navarre-Sitchler A, Steefel CI, Sak PB, Brantley SL (2011) A reactive-transport model for weathering rind formation on basalt. Geochim Cosmochim Acta 75:7644-7667, doi:10.1016/j.gca.2011.09.033
152. Navarre-Sitchler A, Brantley SL, Rother G (2015) How porosity increases during incipient weathering of crystalline silicate rocks. Rev Mineral Geochem 80:331-354
153. Noiriel C (2005) Contribution à la détermination expérimentale et à la modélisation des différents processus contrôlant l'évolution géochimique, structurale et hydrodynamique des roches fissurées carbonatées. PhD thesis, Ecole des Mines de Paris
154. Noiriel C, Gouze P, Bernard D (2004) Investigation of porosity and permeability effects from microstructure changes during limestone dissolution. Geophys Res Lett 31:L24603, doi:24610.21029/22004GL021572
155. 2-enriched water. Oil Gas Sci Technol 60:177-192
156. Noiriel C, Gouze P, Madé B (2007a) Time-resolved 3D characterisation of flow and dissolution patterns in a single rough-walled fracture. In: IAH Selected Papers Series9 on Groundwater in Fractured Rocks. Krasny J, Sharp J (eds) Taylor & Francis, p 629-642
157. Noiriel C, Madé B, Gouze P (2007b) Impact of coating development on the hydraulic and transport properties in argillaceous limestone fracture. Water Resour Res 43:W09046, doi:09010.01029/02006WR005379
158. Noiriel C, Luquot L, Madé B, Raimbault L, Gouze P, van der Lee J (2009) Changes in reactive surface area during limestone dissolution: An experimental and modelling study. Chem Geol 265:160-170
159. Noiriel C, Renard F, Doan ML, Gratier JP (2010) Intense fracturing and fracture sealing induced by mineral growth in porous rocks. Chem Geol 269:197-209, doi:10.1016/j.chemgeo.2009.09.018
160. Noiriel C, Steefel CI, Yang L, Ajo-Franklin J (2012) Upscaling calcium carbonate precipitation rates from pore to continuum scale. Chem Geol 318-319:60-74
161. Noiriel C, Gouze P, Made B (2013) 3D analysis of geometry and flow changes in a limestone fracture during dissolution. J Hydrol 486:211-223, doi:10.1016/j.jhydrol.2013.01.035
162. Nollet S, Hilgers C, Urai JL (2006) Experimental study of polycrystal growth from an advecting supersaturated fluid in a model fracture. Geofluids 6:185-200, doi:10.1111/j.1468-8123.2006.00142.x
163. Oh W, Lindquist WB (1999) Image thresholding by indicator kriging. IEEE Trans Pattern Anal Mach Intell 21:590-602
164. Oren PE, Bakke S, Held R (2007) Direct pore-scale computation of material and transport properties for North Sea reservoir rocks. Water Resour Res 43:W12S04, doi:10.1029/2006wr005754
165. Ortoleva PJ, Chadam J, Merino E, Sen A (1987) Geochemical self-organization II. The reactive infiltration instability. Am J Sci 287:1008-1040
166. Patir N, Cheng HS (1978) An average flow model for determining effects of the three-dimensional roughness on partial hydrodynamic lubrication. J Lubr Technol 100:12-17
167. Peng S, Hu Q, Dultz S, Zhang M (2012) Using X-ray computed tomography in pore structure characterization for a Berea sandstone: Resolution effect. J Hydrol 472:254-261, doi:10.1016/j.jhydrol.2012.09.034
168. Peng S, Marone F, Dultz S (2014) Resolution effect in X-ray microcomputed tomography imaging and small pore's contribution to permeability for a Berea sandstone. J Hydrol 510:403-411, doi:10.1016/j. jhydrol.2013.12.028
169. 2 injection. 10th International Conference on Greenhouse Gas Control Technologies 4:4387-4394, doi:10.1016/j.egypro.2011.02.391
170. Peyton RL, Haeffner BA, Anderson SH, Gantzer CJ (1992) Hydraulic and mechanical properties of natural fractures in low permability rocks. In: Proceedings of the 6th International Congress of Rocks Mechanics. Herget G, Vongpaisal S (eds) Balkema, Rotterdam.
171. Pitas I (2000) Digital Image Processing Algorithms and Applications. Wiley
172. Plougonven E, Bernard D (2011) Optimal removal of topological artefacts in microtomographic images of porous materials. Adv Water Resour 34:731-736, doi:10.1016/j.advwatres.2011.03.004
173. 2. Am J Sci 278:179-216
174. Polak A, Grader AS, Wallach R, Nativ R (2003) Chemical diffusion between a fracture and the surrounding matrix: Measurement by computed tomography and modeling. Water Resour Res 39:WR000813
175. Porter ML, Wildenschild D (2010) Image analysis algorithms for estimating porous media multiphase flow variables from computed microtomography data: a validation study. Comput Geosci 14:15-30, doi:10.1007/s10596-009-9130-5
176. Prodanovic M, Lindquist WB, Seright RS (2006) Porous structure and fluid partitioning in polyethylene cores from 3D X-ray microtomographic imaging. J Colloid Interface Sci 298:282-297, doi:10.1016/j. jcis.2005.11.053
177. Prodanovic M, Lindquist WB, Seright RS (2007) 3D image-based characterization of fluid displacement in a Berea core. Adv Water Resour 30:214-226, doi:10.1016/j.advwatres.2005.05.015
178. Prodanovic M, Bryant SL, Karpyn ZT (2010) Investigating Matrix/Fracture Transfer via a Level Set Method for Drainage and Imbibition. SPE Reservoir Eval Eng 15:125-136
179. Prodanovic M, Mehmani A, Sheppard A (2015) Imaged-based multiscale network modelling of microporosity in carbonates. In: Fundamental Controls on Fluid Flow in Carbonates: Current Workflows to Emerging Technologies. Vol 406. Agar SM, Geiger S, (eds). Geological Society, Special Publication, London, p 95-113
180. Qajar J, Francois N, Arns CH (2013) Microtomographic Characterization of Dissolution-Induced Local Porosity Changes Including Fines Migration in Carbonate Rock. Spe J 18:545-562
181. Quintard M, Whitaker S (1996) Transport in chemically and mechanically heterogeneous porous media.1. Theoretical development of region-averaged equations for slightly compressible single-phase flow. Adv Water Resour 19:29-47, doi:10.1016/0309-1708 (95) 00023-c
182. Rad MN, Shokri N, Sahimi M (2013) Pore-scale dynamics of salt precipitation in drying porous media. Phys Rev E: Stat Nonlinear Soft Matter Phys 88:5, doi:10.1103/PhysRevE.88.032404
183. Remeysen K, Swennen R (2010) Combination of dual energy microfocus computed tomography and petrography for objective 3D reservoir characterization. In: Advances in X-ray Tomography for Geomaterials. Desrues J, Viggiani G, Bésuelle J, (eds). ISTE, p 155-160
184. Renard F, Bernard D, Boller E, Thibaut X (2004) Synchrotron 3D microtomography of halite aggregates during experimental pressure solution creep and evolution of the permeability. Geophys Res Lett 31:L07607, doi:07610.01029/02004GL019605
185. Rickard D, Sjöberg EL (1983) Mixed kinetic control of calcite dissolution rates. Am J Sci 283:815-830
186. Rougelot T, Burlion N, Bernard D, Skoczylas F (2009) About microcracking due to leaching in cementitious composites: X-ray microtomography description and numerical approach. Cem Concr Res 40:271-283, doi:10.1016/j.cemconres.2009.09.021
187. Salehikhoo F, Li L, Brantley SL (2013) Magnesite dissolution rates at different spatial scales: The role of mineral spatial distribution and flow velocity. Geochim Cosmochim Acta 108:91-106, doi:10.1016/j. gca.2013.01.010
188. Sasov AY (1987a) Microtomography 2. Examples of applications. J Microsc 147:179-192
189. Sasov AY (1987b) Microtomography 1. Methods and equipment. J Microsc 147:169-178
190. Schlüter S, Sheppard A, Brown K, Wildenschild D (2014) Image processing of multiphase images obtained via X-ray microtomography: A review. Water Resour Res 50:3615-3639, doi:10.1002/2014wr015256
191. 2 sequestration experiment with saline aquifer sandstone. Environ Sci Technol 47:198-204, doi:10.1021/es3013358
192. Seright RS, Liang J, Lindquist WB, Dunsmuir JH (2002) Characterizing disproportionate permeability reduction using synchrotron X-ray computed microtomography. SPE Reserv Eval Eng 5:355-364
193. Seth S, Morrow NR (2007) Efficiency of the Conversion of Work of Drainage to Surface Energy for Sandstone and Carbonate SPE Reserv Eval Eng 10:338-347
194. Sheppard AP, Sok RM, Averdunk H (2004) Techniques for image enhancement and segmentation of tomographic images of porous materials. Phys A 339:145-151
195. Shiraki R, Rock PA, Casey WH (2000) Dissolution kinetics of calcite in 0.1M NaCl solution at room temperature: an atomic force microscopic (AFM) study. Aquat Geochem 6:87-108
196. Shokri N, Lehmann P, Or D (2009) Critical evaluation of enhancement factors for vapor transport through unsaturated porous media. Water Resour Res 45:W10433, doi:10.1029/2009wr007769
197. Silin D, Tomutsa L, Benson SM, Patzek TW (2011) Microtomography and pore-scale modeling of two-phase fluid distribution. Transp Porous Media 86:525-545, doi:10.1007/s11242-010-9636-2
198. Sjöberg EL, Rickard D (1985) The effect of added dissolved calcium on calcite dissolution kinetics in aqueous solution at 25°C. Chem Geol 49:405-413
199. 2-induced dissolution of low permeability carbonates. Part I: Characterization and experiments. Adv Water Resour 62:370-387, doi:10.1016/j. advwatres.2013.09.008
200. 2 exposure. Environ Sci Technol 47:262-268, doi:10.1021/es3012723
201. Snigirev A, Snigireva I, Kohn V, Kuznetsov S, Schelokov I (1995) On the possibilities of x-ray phase contrast microimaging by coherent high-energy synchrotron radiation. Rev Sci Instrum 66:5486-5492, doi:10.1063/1.1146073
202. Sok RM, Varslot T, Ghous A, Latham S, Sheppard AP, Knackstedt MA (2010) Pore scale characterization of carbonates at multiple scales: Integration of Micro-CT, BSEM, and FIBSEM. Petrophys 51:379-387
203. Spanne P, Thovert JF, Jacquin CJ, Lindquist WB, Jones KW, Adler PM (1994) Synchrotron computed microtomography of porous media: topology and transport. Phys Rev Lett 73:2001-2004
204. Steefel CI (2008) Geochemical Kinetics and Transport. In: Kinetics of Water-Rock Interaction. Brantley SL, Kubicki JD, White AF, (eds). Springer, New York, p 545-598
205. Steefel CI, Lasaga AC (1990) Evolution of dissolution patterns: Permeability change due to coupled flow and reaction. In: Chemical Modeling of Aqueous Systems II. Vol Chapter 16. Melchior D, Bassett RL, (eds). American Chemical Society, Washington DC, p 212-225
206. Steefel CI, Beckingham LE, Landrot G (2015) Micro-continuum approaches for modeling pore-scale geochemical processes. Rev Mineral Geochem 80:217-246
207. 2 injection and sequestration. Rev Mineral Geochem 77:259-303
208. Stipp S L S, Eggleston CM, Nielsen BS (1994) Calcite surface observed at microtopographic and molecular scales with atomic force microscopy (AFM). Geochim Cosmochim Acta 58:3023-3033
209. Teng HH (2004) Controls by saturation state on etch pit formation during calcite dissolution. Geochim Cosmochim Acta 68:253-262
210. Teng HH, Dove PM, De Yoreo JJ (2000) Kinetics of calcite growth: Surface processes and relationships to macroscopic rate laws. Geochim Cosmochim Acta 64:2255-2266, doi:10.1016/s0016-7037 (00) 00341-0
211. Thompson KE, Willson CS, Zhang W (2006) Quantitative computer reconstruction of particulate materials from microtomography images. Powder Technol 163:169-182, doi:10.1016/j.powtec.2005.12.016
212. Thovert JF, Salles J, Adler PM (1993) Computerized characterisation of the geometry of real porous media: their discretization, analysis and interpretation. J Microsc 170:65-79
213. Tsuchiyama A, Nakano T, Uesugi K, Uesugi M, Takeuchi A, Suzuki Y, Noguchi R, Matsumoto T, Matsuno J, Nagano T, Imai Y, Nakamura T, Ogami T, Noguchi T, Abe M, Yada T, Fujimura A (2013) Analytical dualenergy microtomography: A new method for obtaining three-dimensional mineral phase images and its application to Hayabusa samples. Geochim Cosmochim Acta 116:5-16, doi:10.1016/j.gca.2012.11.036
214. van der Lee J (1998) Thermodynamic and mathematical concepts of CHESS. Technical report LHM/RD/98/3, p 99
215. Van Geet M, Swennen R, Wevers M (2000) Quantitative analysis of reservoir rocks by microfocus X-ray computerised tomography. Sediment Geol 132:25-36
216. Van Geet M, Swennen R, Wevers M (2001) Toward 3-D petrography: application of microfocus computer tomography in geological science. Comput Geosci 27:1091-1099
217. Vandersteen K, Busselen B, Van den Abeele K, Carmeleir J (2003) Quantitative characterization of fracture apertures using microfocus computed tomography. In: Applications of X-ray Computed Tomography in the Geosciences. Mees F, Swennen R, Van Geet M, Jacobs P (eds) Geological Society Special Publication 215, p 61-69
218. 2rich fluids in a limestone sample: Evolution of hydraulic, electrical, chemical, and structural properties. J Geophys Res B: Solid Earth 119:2828-2847, doi:10.1002/2013jb010656
219. Vlassenbroeck J, Dierick M, Masschaele B, Cnudde V, Hoorebeke L, Jacobs P (2007) Software tools for quantification of X-ray microtomography. Nucl Instrum Methods Phys Res Sect A-Accel Spectrom Dect Assoc Equip 580:442-445, doi:10.1016/j.nima.2007.05.073
220. Walsh S D C, Mason HE, Du Frane WL, Carroll SA (2014a) Experimental calibration of a numerical model describing the alteration of cement/caprock interfaces by carbonated brine. Inter J Greenhouse Gas Control 22:176-188, doi:10.1016/j.ijggc.2014.01.004
221. Walsh S D C, Mason HE, Du Frane WL, Carroll SA (2014b) Mechanical and hydraulic coupling in cementcaprock interfaces exposed to carbonated brine. Inter J Greenhouse Gas Control 25:109-120, doi:10.1016/j.ijggc.2014.04.001
222. Wildenschild D, Sheppard AP (2013) X-ray imaging and analysis techniques for quantifying pore-scale structure and processes in subsurface porous medium systems. Adv Water Resour 51:217-246, doi:10.1016/j.advwatres.2012.07.018
223. Wildenschild D, Vaz C M P, Rivers ML, Rikard D, Christensen B S B (2002) Using X-ray computed tomography in hydrology: systems, resolutions, and limitations. J Hydrol 267:285-297
224. Wu YX, Ajo-Franklin JB, Spycher N, Hubbard SS, Zhang GX, Williams KH, Taylor J, Fujita Y, Smith R (2011) Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation. Geochem Trans 12:20, doi:10.1186/1467.4866.12.7
225. Yoon H, Kang Q, Valocchi A (2015) Lattice Boltzmann-based approaches for pore-scale reactive transport. Rev Mineral Geochem 80:393-431