An interferometric study of the dissolution kinetics of anorthite: The role of reactive surface area

American Journal of Science

Volumn 299, Issue 7-9, 1999, Pages 652-678

  Luttge A ^a,b   Bolton, E W ^a   Lasaga, A C ^a  

^a YALE UNIVERSITY   (United States)

^b RICE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0040531893     PISSN: 00029599     EISSN: None     Source Type: Journal    
DOI: 10.2475/ajs.299.7-9.652     Document Type: Article

References (96)

1. Berger, G., Cadore, E., Schott, J., and Dove, P. M., 1994, Dissolution rate of quartz in lead and sodium electrolyte solutions between 25 and 300 degrees C; effect of the nature of surface complexes and reaction affinity: Geochimica et Cosmochimica Acta, v. 58, p. 541-551.
2. Berner, R. A., 1978, Rate control of mineral dissolution under Earth surface conditions: American Journal of Science, v. 278, p. 1235-1252.
3. Berner, R. A., and Holdren, G. R., 1977, Mechanism of feldspar weathering. Some observational evidence: Geology, v. 5, p. 369-372.
4. _ 1979, Mechanism of feldspar weathering II. Observations of feldspars from soils: Geochimica et Cosmochimica Acta, v. 43, p. 1173-1186.
5. Berner, R. A., Holdren, G. R. Jr., and Schott, J., 1985, Surface layers on dissolving silicates; comments on "Study of the weathering of albite at room temperature and pressure with a fluidized bed reactor": Geochimica et Cosmochimica Acta, v. 49, p. 1657-1660.
6. Berner, R. A., and Schott, J., 1982, Mechanism of pyroxene and amphibole weathering; II. Observations of soil grains: American Journal of Science, v. 282, p. 1214-1231.
7. Berner, R. A., Sjoberg, E. L., Velbel, M. A., and Krom, M. D., 1980, Dissolution of pyroxenes and amphiboles during weathering: Science, v. 207, p. 1205-1206.
8. Berner, R. A., Westrich, J. T., Graber, R., Smith, J., and Martens, C. S., 1978, Inhibition of aragonite precipitation from supersaturated seawater. A laboratory and field study: American Journal of Science, v. 278, p. 816-837.
9. Blum, A. E., and Lasaga, A. C., 1987, Monte Carlo simulations of surface rate laws, in Stumm, W., editor, Aquatic surface chemistry; chemical processes at the particle-water interface: New York, John Wiley, Environmental Science & Techniques Series, p. 255-292.
10. Bolton, E. W., Lasaga, A. C., and Rye, D. M., 1996, A model for the kinetic control of quartz dissolution and precipitation in porous media flow with spatially variable permeability: Formulation and examples of thermal convection: Journal of Geophysical Research, v. 101, p. 22157-22187.
11. Bosbach, D., Hall, C., and Putnis, A., 1998, Mineral precipitation and dissolution in aqueous solution: in-situ microscopic observations on barite (001) with atomic force microscopy: Chemical Geology, v. 151, p. 143-160.
12. Brady, P. V., and Walther, J. W., 1989, Controls on silicate dissolution rates in neutral and basic pH solutions at 25 degrees C: Geochimica et Cosmochimca Acta, v. 53, p. 2823-2830.
13. _ 1992, Surface chemistry and silicate dissolution at elevated temperatures: American Journal of Science, v. 292, p. 639-658.
14. Brantley, S. L., Crane, S. R., Crerar, D. A., Hellmann, R., and Stallard, R., 1986, Dissolution at dislocation etch pits in quartz: Geochimica et Cosmochimica Acta, v. 50, p. 2349-2361.
15. Brantley, S. L., and Stillings, L. L., 1996, Feldspar dissolution at 25 degrees C and low pH: American Journal of Science, v. 296, p. 101-127.
16. Brunauer, S., Emmet, P. H., and Teller, E., 1938, Adsorption of gases in multimolecular layers: Journal of the American Chemical Society, v. 60, p. 309-319.
17. Bruning, J. H., Herriott, D. R., Gallagher, D. P., White, A. D., and Brangaccio, D. J., 1974, Digital wavefront measuring interferometer for testing optical surfaces and lenses: Applied Optics, v. 13, p. 2693-2703.
18. Burch, T. E., Nagy, K. L., and Lasaga, A. C., 1993, Free energy dependence of albite dissolution kinetics at 80 degrees C and pH 8.8: Chemical Geology, v. 105, p. 137-162.
19. 2 partial pressure: Geochimica et Cosmochimica Acta, v. 40, p. 41-49.
20. Cama, J., Ganor, J., and Lasaga, A. C., 1994, The kinetics of smectite dissolution: Mineralogical Magazine, v. 54A, p. 140-141.
21. Casey, W. H., Banfield, J. F., Westrich, H. R., and McLaughlin, L., 1993, What do dissolution experiments tell us about natural weathering?: Chemical Geology, v. 105, p. 1-15.
22. Casey, W. H., and Sposito, G., 1992, On the temperature dependence of mineral dissolution rates: Geochimica et Cosmochimica Acta, v. 56, p. 3825-3830.
23. Casey, W. H., and Westrich, H. R., 1992, Control of dissolution rates of orthosilicate minerals by divalent metal-oxygen bonds: Nature, v. 355, p. 157-159.
24. Casey, W. H., Westrich, H. R., and Holdren, G. R., 1991, Dissolution rates of plagioclase at pH = 2 and 3: American Mineralogist, v. 76, p. 211-217.
25. Chen, Y., and Brantley, S. L., 1997, Temperature and pH dependence of albite dissolution rate at acid pH: Chemical Geology, v. 135, p. 275-290.
26. _ 1998, Diopside and anthophyllite dissolution at 25 degrees and 90 degrees C and acid pH: Chemical Geology, v. 147, p. 233-248.
27. Chou, L., and Wollast, R., 1984, Study of the weathering of albite at room temperature and pressure with a fluidized bed reactor: Geochimica et Cosmochimica Acta, v. 48, p. 2205-2217.
28. Dove, P. M., 1994, The dissolution kinetics of quartz in sodium chloride solutions at 25°C to 300°C: American Journal of Science, v. 294, p. 665-712.
29. Dove, P. M., and Crerar, C. A., 1990, Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor: Geochimica et Cosmochimica Acta, v. 54, p. 955-969.
30. Dove, P. M., and Elston, S. F., 1992, The low-temperature dissolution kinetics of quartz in sodium chloride solutions: Analysis of existing data and a rate model for 25°C, pH 2-13: Geochimica et Cosmochimica Acta, v. 56, p. 4147-4156.
31. Dove, P. M., and Hochella, M. F., 1993, Calcite precipitation mechanisms and inhibition by orthophosphate; in-situ observations by scanning force microscopy: Geochimica et Cosmochimica Acta, v. 57, p. 705-714.
32. Dove, P. M., and Nix, C. J., 1997, The influence of the alkaline earth cations, magnesium, calcium and barium on the dissolution kinetics of quartz: Geochimica et Cosmochimica Acta, v. 61, p. 3329-3340.
33. Dove, P. M., and Platt, F. M., 1996, Compatible real-time rates of mineral dissolution by atomic force microscopy (AFM): Chemical Geology, v. 127, p. 331-338.
34. Drake, B., and Hellmann, R., 1991, Atomic force microscopy imaging of the albite (010) surface: American Mineralogists, v. 76, p. 1773-1776.
35. Gout, R., Oelkers, E. H., Schott, J., and Zwick, A., 1997, The surface chemistry and structure of acid-leached albite: new insights on the dissolution mechanisms of the alkali feldspars: Geochimica et Cosmochimica Acta, v. 61, p. 3013-3018.
36. Gratz, A. J., and Bird, P., 1993a, Quartz dissolution theory of rough and smooth surfaces: Geochimica et Cosmochimica Acta, v. 57, p. 977-989.
37. _ 1993b, Quartz dissolution: negative crystal experiments and a rate law: Geochimica et Cosmochimica Acta, v. 57, p. 965-976.
38. Hillner, P. E., Gratz, A. J., Manne, S., and Hansma, P. K., 1992, Atomic-scale imaging of calcite growth and dissolution in real time: Geology, v. 20, p. 359-362.
39. Holdren, G. R., and Berner, R. A., 1979, Mechanism of feldspar weathering I. Experimental studies: Geochimica et Cosmochimica Acta, v. 43, p. 1161-1172.
40. Kumar, A., and Dove, P. M., 1996, Surface coating induced evolution of microscale geochemical heterogeneity and quartz surface reactivity: Geological Society of America, Abstracts with Programs, v. 28, p. 322.
41. Lasaga, A. C., 1995, Fundamental approaches in describing mineral dissolution and precipitation rates: Reviews in Mineralalogy, v. 31, p. 23-86.
42. _ 1998, Kinetic theory and applications in earth sciences: Princeton, New Jersey, Princeton Press, 600 p.
43. Lasaga, A. C., and Blum, A. E., 1986, Surface chemistry, etch pits and mineral-water reactions. Geochimica et Cosmochimica Acta, v. 50, p. 2363-2379.
44. Lasaga, A. C., and Rye, D. M., 1993, Fluid flow and chemical reaction kinetics in metamorphic systems: American Journal of Science, v. 293, p. 361-404.
45. Lasaga, A. C., Soler, J. M., Ganor, J., Burch, T. E., and Nagy, K. L., 1994, Chemical weathering rate laws and global geochemical cycles: Geochimica et Cosmochimica Acta, v. 58, p. 2361-2386.
46. Liang, Y., Baer, D. R., McCoy, J. M., Amonette, J. E., and LaFemina, J. P., 1996, Dissolution kinetics at the calcite-water interface: Geochimica et Cosmochimica Acta, v. 60, p. 4883-4887.
47. Liu, C., and Huang, P. M., 1999, Atomic force microscopy and surface characteristics of iron oxides formed in citrate solutions: Soil Science Society of America Journal, v. 63, p. 65-72.
48. 2 mixture. Part I: American Mineralogist, submitted.
49. th, Gatlinburg, Tennessee, Proceedings, p. 61-64.
50. Lüttge, A., and Metz, P., 1991, Mechanism and kinetics of the reaction 1 dolomite + 2 Quartz = 1 diopside + 2 CO2 investigated by powder experiments: Canadian Mineralogist, v. 29, p. 803-821.
51. Lüttge, A., Neumann, U., and Lasaga, A. C., 1998, The influence of heating rate on the kinetics of mineral reaction: An experimental study and computer models: American Mineralogist, v. , p.
52. MacInnis, I. N., and Brantley, S. L., 1992, The role of dislocations and surface morphology in calcite dissolution: Geochimica et Cosmochimica Acta, v. 56, p. 1113-1126.
53. _ 1993, Development of etch pit size distributions on dissolving minerals: Chemical Geology, v. 105, p. 31-49.
54. Maiwa, K., Tsukamoto, K., and Sunagawa, I., 1990, Activities of spiral growth hillocks on the (111) faces of barium nitrate crystals growing in an aqueous solution: Journal of Crystal Growth, v. 102, p. 43-53.
55. Mast, M. A., and Drever, J. I., 1987, The effect of oxalate on the dissolution rates of digoclase and tremolite: Geochimica et Cosmochimica Acta, v. 51, p. 2559-2568.
56. Mogollon, J. L., Ganor, J. W., Soler, J., and Lasaga, A. C., 1996, Column experiments and the full dissolution rate law of gibbsite: American Journal of Science, v. 296, p. 729-765.
57. Nagy, K. L., and Lasaga, A. C., 1992, Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: The dependence on solution saturation state: Geochimica et Cosmochimica Acta, v. 56, p. 3093-3111.
58. Oelkers, E. H., and Schott, J., 1995, Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis: Geochimica et Cosmochimica Acta, v. 59, p. 5039-5053.
59. Ohmoto, H., Hayashi, K., Onuma, K., Tsukamoto, K., Kitakaze, A., Nakano, Y., and Yamamoto, Y., 1991, Solubility and reaction kinetics of solution-solid reactions determined by in situ observations: Nature, v. 351, p. 634-636.
60. Onuma, K., Karneyama, T., and Tsukamoto, K., 1994, In situ study of surface phenomena by real time phase shift interferometry: Journal of Crystal Growth, v. 137, p. 610-622.
61. Onuma, K., Tsukamoto, K., and Nakadate, S., 1993, Application of real time phase shift interferometer to the measurement of concentration field: Journal of Crystal Growth, v. 129, p. 706-622.
62. Onuma, K., Tsukamoto, K., and Sunagawa, I., 1991, Dissolution kinetics of K-alum crystals as judged from the measurements of surface undersaturations: Journal of Crystal Growth, v. 110, p. 724-732.
63. Petit, J. C., Della Mea, G., Dran, J. C., Schott, J., and Berner, R. A., 1987, Mechanism of diopside dissolution from hydrogen depth profiling: Nature, v. 325, p. 705-707.
64. Petrovic, R., Berner, R. A., and Goldhaber, M. B., 1976, Rate control in dissolution of alkali feldspars; I, Study of residual feldspar grains by X-ray photoelectron spectroscopy: Geochimica et Cosmochimica Acta, v. 40, p. 537-548.
65. Rimstidt, J. D., and Dove, P. M., 1986, Mineral/solution reaction rates in a mixed flow reactor; wollastonite hydrolysis: Geochimica et Cosmochimica Acta, v. 50, p. 2509-2516.
66. Schott, J., and Berner, R. A., 1983a, X-Ray photoelectron studies of the mechanism of iron silicate dissolution during weathering: Geochimica et Cosmochimica Acta, v. 47, p. 2233-2240.
67. _ 1983b, X-ray photoelectron studies of the mechanism of iron silicate dissolution during weathering: Geochimica et Cosmochimica Acta, v. 47, p. 2233-2240.
68. Schott, J., Berner, R. A., and Sjoberg, E. L., 198Ia, Mechanism of pyroxene and amphibole weathering; I. Experimental studies of iron-free minerals: Geochimica et Cosmochimica Acta, v. 45, p. 2123-2135.
69. _ 1981b, Mechanism of pyroxene and amphibole weathering; I. Experimental studies of iron-free minerals: Geochimica et Cosmochimica Acta, v. 45, p. 2123-2135.
70. _ 1985, Dissolution mechanisms of pyroxenes and olivines during weathering, in Drever, J. I., editor, The chemistry of weathering: NATO ASI Series, Series C: Mathematical and Physical Science, v. 149, p. 35-53.
71. Schramke, J. A., Kerrick, D. M., and Lasaga, A. C., 1987, The reaction muscovite + quartz = andalusite + K-feldspar + water. Part 1. Growth kinetics and mechanism: American Journal of Science, v. 287, p. 517-559.
72. Shiraki, R., and Brantley, S. L., 1995, Kinetics of near-equilibrium calcite precipitation at 100 degrees C: an evaluation of elementary reaction-based and affinity-based rate laws: Geochimica et Cosmochimica Acta, v. 59, p. 1457-1471.
73. Soler, J., and Lasaga, A. C., 1996, A mass transfer model of bauxite formation: Geochimica et Cosmochimica Acta, v. 60, p. 4913-4932.
74. Stillings, L. L., and Brantley, S. L., 1995, Feldspar dissolution at 25 degrees C and pH 3: reaction stoichiometry and the effect of cations: Geochimica et Cosmochimica Acta, v. 59, p. 1483-1496.
75. Stillings, L. L., Brantley, S. L., and Machesky, M. L., 1995, Proton adsorption at an adularia feldspar surface: Geochimica et Cosmochimica Acta, v. 59, p. 1483-1496.
76. Stillings, L. L., Drever, J. I., Brantley, S. L., Sun, Y., and Oxburgh, R., 1996, Rates of feldspar dissolution at pH 3-7 with 0-8 mM oxalic acid: Chemical Geology, v. 132, p. 79-89.
77. Stipp, S. L. S., Eggleston, C. M., and Nielsen, B. S., 1994, Calcite surface observed at microtopographic and molecular scales with Atomic Force Microscopy (AFM): Geochimica et Cosmochimica Acta, v. 58, p. 3023-3033.
78. Stumm, W., and Wollast, R., 1990, Coordination chemistry of weathering: kinetics of the surface-controlled dissolution of oxide minerals: Reviews in Geophysics, v. 28, p. 53-69.
79. Swoboda, C., Norbert, G., and Drever, J. I., 1993, Mineral dissolution rates in plot-scale field and laboratory experiments: Chemical Geology, v. 105, p. 51-69.
80. Tanner, S. B., Kerrick, D. M., and Lasaga, A. C., 1985, Experimental kinetic study of the reaction: calcite + quartz = wollastonite + carbon dioxide, from 1 to 3 kilobars and 500° to 850°C: American Journal of Science, v. 285, p. 577-620.
81. Taylor, A. S., Blum, J. D., and Lasaga, A. C., 1999, Plagioclase dissolution and Sr release rates: the dependence on solution saturation state: Geochimica et Cosmochimica Acta, in review.
82. Teng, H. H., and Dove, P. M., 1997, Surface site-specific interactions of aspartate with calcite during dissolution; implications for biomineralization: American Mineralogist, v. 82, p. 878-887.
83. Teng, H. H., Dove, P. M., DeYoreo, J. J., and Orme, C., 1998, Thermodynamic controls on calcite growth; determining foundations of biomineral formation. Geological Society of America, Abstracts with Programs, 30:7, p. 156.
84. th, Awara, Japan, Proceedings, p. 227-231.
85. Valsami-Jones, E., Ragnarsdottir, K. V., Putnis, A., Bosbach, D., Kemp, and A. J. Cressey, G., 1998, The dissolution of apatite in the presence of aqueous metal cations at pH 2-7: Chemical Geology, v. 151, p. 215-233.
86. van Enckevort, W. J. P., 1992, Phase shifting interferometry of growth patters on the octahedral faces of natural diamonds: Journal of Crystal Growth, v. 119, p. 177-194.
87. Velbel, M. A., 1984, Natural weathering mechanisms of almandine garnet: Geology, v. 12, p. 631-634.
88. _ 1986, Influence of surface area, surface characteristics, and solution composition on feldspar weathering rates, in Davis, J. A. and Hayes, K. F., editors, Geochemical Processes at mineral surfaces: American Chemical Society Symposium Series 323, p. 615-634.
89. _ 1989, Effect of chemical affinity on feldspar hydrolysis rates in two natural weathering systems: Chemical Geology, v. 78, p. 245-253.
90. _ 1992, Geochemical mass balances and weathering rates in forested watersheds of the southern Blue Ridge III. Cation budgets and the weathering rate of amphibole: American Journal of Science, v. 292, p. 58-78.
91. _ 1993, Constancy of silicate mineral weathering rate ratios between natural and experimental weathering: Implications for hydrologic control of difference in absolute rates: Chemical Geology, v. 105,
92. Wicks, F. J., Kjoller, K., Eby, R. K., Hawthorne, F. C., Henderson, G. S., and Vrdoljak, G. A., 1993, Imaging the internal atomic structure of layered silicates using the atomic force microscope: Canadian Mineralogist, v. 31, p. 541-550.
93. Wollast, R., and Chou, L., 1992, Surface reactions during the early stages of weathering of albite: Geochimica et Cosmochimica Acta, v. 56, p. 3113-3121.
94. +) catalysis: Geochimica et Cosmochimica Acta, v. 58, p. 5379-5400.
95. - catalysis: Geochimica et Cosmochimica Acta, v. 60, p. 2283-2295.
96. Zhang, Z. Z., and Bailey, G. W., 1998, Reactivity of basal surfaces, steps and edges of muscovite: an AFM study: Clays and Clay Minerals, v. 46, p. 290-300.