Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH

Catalysis Today

Volumn 260, Issue , 2016, Pages 8-13

  Varela, Ana Sofia ^a   Kroschel, Matthias ^a   Reier, Tobias ^a   Strasser, Peter ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

CO2 reduction; Copper; Electrocatalysis; Local pH

Indexed keywords

ALKALINITY; COPPER; ELECTROCATALYSIS; ELECTRODES; ELECTROLYTES; ETHYLENE; PH EFFECTS; REDUCTION;

COPPER ELECTRODES; ELECTRO REDUCTION; ELECTROCHEMICAL REDUCTIONS; ELECTRODE POTENTIALS; ELECTROLYTE CONCENTRATION; LOCAL PH; PRODUCT DISTRIBUTIONS; PRODUCT FORMATION;

ELECTROLYTIC REDUCTION;

EID: 84947868008     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cattod.2015.06.009     Document Type: Article

References (29)

1. M. Gattrell, N. Gupta, and A. Co Energy Convers. Manag. 48 2007 1255 1265
2. J. Qiao, Y. Liu, F. Hong, and J. Zhang Chem. Soc. Rev. 43 2014 631 675
3. 2 Reduction Catalysis in Carbon Capture 2012 Springer 245 256
4. D. Kim, K.K. Sakimoto, D. Hong, and P. Yang Angew. Chem. Int. Ed. 54 2015 3259 3266
5. N. Gupta, M. Gattrell, and B. MacDougall J. Appl. Electrochem. 36 2006 161 172
6. 2 reduction on metal electrodes C. Vayenas, R. White, M. Gamboa-Aldeco, Modern Aspects of Electrochemistry 2008 Springer New York 89 189
7. K.J.P. Schouten, Y. Kwon, C.J.M. van der Ham, Z. Qin, and M.T.M. Koper Chem. Sci. 2 2011 1902 1909
8. R. Reske, H. Mistry, F. Behafarid, B. Roldan Cuenya, and P. Strasser J. Am. Chem. Soc. 136 2014 6978 6986
9. C.W. Li, J. Ciston, and M.W. Kanan Nature 508 2014 504 507
10. F.S. Roberts, K.P. Kuhl, and A. Nilsson Angew. Chem. Int. Ed. 54 2015 5179 5182
11. Y. Hori, A. Murata, and R. Takahashi J. Chem. Soc. Faraday Trans. 1: Phys. Chem. Condens. Phases 85 1989 2309 2326
12. K.P. Kuhl, E.R. Cave, D.N. Abram, and T.F. Jaramillo Energy Environ. Sci. 5 2012 7050 7059
13. Y. Hori, A. Murata, K. Kikuchi, and S. Suzuki J. Chem. Soc. Chem. Commun. 1987 728 729
14. W. Tang, A.A. Peterson, A.S. Varela, Z.P. Jovanov, L. Bech, W.J. Durand, S. Dahl, J.K. Norskov, and I. Chorkendorff Phys. Chem. Chem. Phys. 14 2012 76 81
15. C.W. Li, and M.W. Kanan J. Am. Chem. Soc. 134 2012 7231 7234
16. Y. Hori, R. Takahashi, Y. Yoshinami, and A. Murata J. Phys. Chem. B 101 1997 7075 7081
17. K.J.P. Schouten, E.P. Gallent, and M.T.M. Koper J. Electroanal. Chem. 716 2014 53 57
18. K.J.P. Schouten, E.P. Gallent, and M.T.M. Koper J. Electroanal. Chem. 699 2013 6 9
19. K.J.P. Schouten, E.P. Gallent, and M.T.M. Koper ACS Catal. 3 2013 1292 1295
20. K.J.P. Schouten, Z.S. Qin, E.P. Gallent, and M.T.M. Koper J. Am. Chem. Soc. 134 2012 9864 9867
21. R. Kas, R. Kortlever, H. YIlmaz, M.T.M. Koper, and G. Mul ChemElectroChem 2 2015 354 358
22. S. Huemann, N.T. Minh Hai, P. Broekmann, K. Wandelt, H. Zajonz, H. Dosch, and F. Renner J. Phys. Chem. B 110 2006 24955 24963
23. I. Katsounaros, J.C. Meier, S.O. Klemm, A.A. Topalov, P.U. Biedermann, M. Auinger, and K.J.J. Mayrhofer Electrochem. Commun. 13 2011 634 637
24. F. Calle-Vallejo, and M.T.M. Koper Angew. Chem. 125 2013 7423 7426
25. A.A. Peterson, F. Abild-Pedersen, F. Studt, J. Rossmeisl, and J.K. Norskov Energy Environ. Sci. 3 2010 1311 1315
26. J.H. Montoya, A.A. Peterson, and J.K. Nørskov ChemCatChem 5 2013 737 742
27. R. Kas, R. Kortlever, A. Milbrat, M.T.M. Koper, G. Mul, and J. Baltrusaitis Phys. Chem. Chem. Phys. 16 2014 12194 12201
28. D. Kim, S. Lee, J.D. Ocon, B. Jeong, J.K. Lee, and J. Lee Phys. Chem. Chem. Phys. 17 2015 824 830
29. Y.-J. Zhang, and A.A. Peterson Phys. Chem. Chem. Phys. 17 2015 4505 4515