Model Approach in Heterogeneous Catalysis: Kinetics and Thermodynamics of Surface Reactions

Accounts of Chemical Research

Volumn 48, Issue 10, 2015, Pages 2775-2782

  Schauermann, Swetlana ^a,b   Freund, Hans Joachim ^a  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^b UNIVERSITY OF KIEL   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84945933208     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/acs.accounts.5b00237     Document Type: Article

References (37)

1. Ertl, G.; Knözinger, H.; Weitkamp, J. Handbook of Heterogeneous Catalysis; VCH: Weinheim, Germany, 1997.
2. Bäumer, M.; Freund, H.-J. Metal deposits on well-ordered oxide films Prog. Surf. Sci. 1999, 61, 127-198 10.1016/S0079-6816(99)00012-X
3. Ertl, G. Basic Principles; Reactions at Solid Surfaces; John Wiley & Sons, Inc.: Hoboken, NJ, 2010; pp 1-19.
4. Zheng, G.; Altman, E. I. The oxidation mechanism of Pd(100) Surf. Sci. 2002, 504, 253-270 10.1016/S0039-6028(02)01104-4
5. Zheng, G.; Altman, E. I. The oxidation of Pd(111) Surf. Sci. 2000, 462, 151-168 10.1016/S0039-6028(00)00599-9
6. Li, F.; Allegretti, F.; Surnev, S.; Netzer, F. P.; Zhang, Y.; Zhang, W. B.; Reuter, K. Oxygen adsorption on stepped Pd(100) surfaces Surf. Sci. 2010, 604, 1813-1819 10.1016/j.susc.2010.07.012
7. Klötzer, B.; Hayek, K.; Konvicka, C.; Lundgren, E.; Varga, P. Oxygen-induced surface phase transformation of Pd(111): sticking, adsorption and desorption kinetics Surf. Sci. 2001, 482-485 (Part 1) 237-242 10.1016/S0039-6028(01)00750-6
8. Engel, T. A molecular beam investigation of He, CO, and O2 scattering from Pd(111) J. Chem. Phys. 1978, 69, 373-385 10.1063/1.436363
9. Conrad, H.; Ertl, G.; Küppers, J.; Latta, E. E. Interaction of NO and O2 with Pd(111) surfaces. II Surf. Sci. 1977, 65, 245-260 10.1016/0039-6028(77)90305-3
10. Guo, X.; Hoffman, A.; Yates, J. T. Adsorption kinetics and isotopic equilibration of oxygen adsorbed on the Pd(111) surface J. Chem. Phys. 1989, 90, 5787-5792 10.1063/1.456386
11. Davies, P. W.; Lambert, R. M. Structural stability and chemisorption properties of a stepped palladium surface: O2 and no on Pd(331) Surf. Sci. 1981, 110, 227-249 10.1016/0039-6028(81)90598-7
12. Henry, C. R. Surface studies of supported model catalysts Surf. Sci. Rep. 1998, 31, 231-326 10.1016/S0167-5729(98)00002-8
13. Nolte, P.; Stierle, A.; Kasper, N.; Jin-Phillipp, N. Y.; Jeutter, N.; Dosch, H. Reversible Shape Changes of Pd Nanoparticles on MgO(100) Nano Lett. 2011, 11, 4697-4700 10.1021/nl2023564
14. Penner, S.; Bera, P.; Pedersen, S.; Ngo, L. T.; Harris, J. J. W.; Campbell, C. T. Interactions of O2 with Pd Nanoparticles on α-Al2O3(0001) at Low and High O2 Pressures J. Phys. Chem. B 2006, 110, 24577-24584 10.1021/jp0630267
15. Højrup Hansen, K.; Šljivančanin, Ž.; Lægsgaard, E.; Besenbacher, F.; Stensgaard, I. Adsorption of O2 and NO on Pd nanocrystals supported on Al2O3/NiAl(100): overlayer and edge structures Surf. Sci. 2002, 505, 25-38 10.1016/S0039-6028(02)01437-1
16. Schalow, T.; Brandt, B.; Starr, D. E.; Laurin, M.; Shaikhutdinov, S. K.; Schauermann, S.; Libuda, J.; Freund, H. J. Particle size dependent adsorption and reaction kinetics on reduced and partially oxidized Pd nanoparticles Phys. Chem. Chem. Phys. 2007, 9, 1347-1361 10.1039/b614546a
17. Lundgren, E.; Kresse, G.; Klein, C.; Borg, M.; Andersen, J. N.; De Santis, M.; Gauthier, Y.; Konvicka, C.; Schmid, M.; Varga, P. Two-Dimensional Oxide on Pd(111) Phys. Rev. Lett. 2002, 88, 246103 10.1103/PhysRevLett.88.246103
18. Stará, I.; Matolín, V. The influence of particle size on CO adsorption on Pd/alumina model catalysts Surf. Sci. 1994, 313, 99-106 10.1016/0039-6028(94)91159-2
19. Borroni-Bird, C. E.; Al-Sarraf, N.; Andersoon, S.; King, D. A. Single crystal adsorption calorimetry Chem. Phys. Lett. 1991, 183, 516-520 10.1016/0009-2614(91)80168-W
20. Fischer-Wolfarth, J.-H.; Hartmann, J.; Farmer, J. A.; Flores-Camacho, J. M.; Campbell, C. T.; Schauermann, S.; Freund, H.-J. An improved single crystal adsorption calorimeter for determining gas adsorption and reaction energies on complex model catalysts Rev. Sci. Instrum. 2011, 82, 024102-024101 10.1063/1.3544020
21. Nepijko, S. A.; Klimenkov, M.; Adelt, M.; Kuhlenbeck, H.; Schlögl, R.; Freund, H. J. Structural Investigation of Palladium Clusters on γ-AlO3(111)/NiAl(110) with Transmission Electron Microscopy Langmuir 1999, 15, 5309-5313 10.1021/la981012p
22. Krüger, S.; Vent, S.; Nörtemann, F.; Staufer, M.; Rösch, N. The average bond length in Pd clusters Pdn,n = 4-309: A density-functional case study on the scaling of cluster properties J. Chem. Phys. 2001, 115, 2082-2087 10.1063/1.1383985
23. Yudanov, I. V.; Metzner, M.; Genest, A.; Rösch, N. Size-Dependence of Adsorption Properties of Metal Nanoparticles: A Density Functional Study on Palladium Nanoclusters J. Phys. Chem. C 2008, 112, 20269-20275 10.1021/jp8075673
24. Shustorovich, E.; Sellers, H. The UBI-QEP method: A practical theoretical approach to understanding chemistry on transition metal surfaces Surf. Sci. Rep. 1998, 31, 1-119 10.1016/S0167-5729(97)00016-2
25. Peter, M.; Flores Camacho, J. M.; Adamovski, S.; Ono, L. K.; Dostert, K.-H.; O'Brien, C. P.; Roldan Cuenya, B.; Schauermann, S.; Freund, H.-J. Trends in the Binding Strength of Surface Species on Nanoparticles: How Does the Adsorption Energy Scale with the Particle Size? Angew. Chem., Int. Ed. 2013, 52, 5175-5179 10.1002/anie.201209476
26. Daley, S. P.; Utz, A. L.; Trautman, T. R.; Ceyer, S. T. Ethylene Hydrogenation on Ni(111) by Bulk Hydrogen J. Am. Chem. Soc. 1994, 116, 6001-6002 10.1021/ja00092a074
27. Teschner, D.; Borsodi, J.; Wootsch, A.; Révay, Z.; Hävecker, M.; Knop-Gericke, A.; Jackson, S. D.; Schlögl, R. The Roles of Subsurface Carbon and Hydrogen in Palladium-Catalyzed Alkyne Hydrogenation Science 2008, 320, 86-89 10.1126/science.1155200
28. Wilde, M.; Fukutani, K.; Ludwig, W.; Brandt, B.; Fischer, J.-H.; Schauermann, S.; Freund, H.-J. Influence of Carbon Deposition on the Hydrogen Distribution in Pd Nanoparticles and Their Reactivity in Olefin Hydrogenation Angew. Chem., Int. Ed. 2008, 47, 9289-9293 10.1002/anie.200801923
29. Ludwig, W.; Savara, A.; Schauermann, S.; Freund, H.-J. Role of Low-Coordinated Surface Sites in Olefin Hydrogenation: A Molecular Beam Study on Pd Nanoparticles and Pd(111) ChemPhysChem 2010, 11, 2319-2322 10.1002/cphc.201000355
30. Christmann, K. Interaction of hydrogen with solid surfaces Surf. Sci. Rep. 1988, 9, 1-163 10.1016/0167-5729(88)90009-X
31. Hydrogen in metals; Alefeld, G.; Volkl, J., Eds.; Springer-Verlag: Berlin, 1978.
32. Greeley, J.; Mavrikakis, M. Surface and Subsurface Hydrogen: Adsorption Properties on Transition Metals and Near-Surface Alloys J. Phys. Chem. B 2005, 109, 3460-3471 10.1021/jp046540q
33. Wilde, M.; Fukutani, K.; Naschitzki, M.; Freund, H. J. Hydrogen absorption in oxide-supported palladium nanocrystals Phys. Rev. B: Condens. Matter Mater. Phys. 2008, 77, 113412 10.1103/PhysRevB.77.113412
34. Brandt, B.; Fischer, J.-H.; Ludwig, W.; Libuda, J.; Zaera, F.; Schauermann, S.; Freund, H.-J. Isomerization and Hydrogenation of cis-2-Butene on Pd Model Catalyst J. Phys. Chem. C 2008, 112, 11408-11420 10.1021/jp800205j
35. Viñes, F.; Loschen, C.; Illas, F.; Neyman, K. M. Edge sites as a gate for subsurface carbon in palladium nanoparticles J. Catal. 2009, 266, 59-63 10.1016/j.jcat.2009.05.010
36. Ludwig, W.; Savara, A.; Madix, R. J.; Schauermann, S.; Freund, H.-J. Subsurface Hydrogen Diffusion into Pd Nanoparticles: Role of Low-Coordinated Surface Sites and Facilitation by Carbon J. Phys. Chem. C 2012, 116, 3539-3544 10.1021/jp209033s
37. Neyman, K. M.; Schauermann, S. Hydrogen Diffusion into Palladium Nanoparticles: Pivotal Promotion by Carbon Angew. Chem., Int. Ed. 2010, 49, 4743-4746 10.1002/anie.200904688