Lithiation of Rutile TiO2-Coated Si NWs Observed by in Situ TEM

Chemistry of Materials

Volumn 27, Issue 20, 2015, Pages 6929-6933

  Kim, Sung Joo ^a,b   Kargar, Alireza ^c   Wang, Deli ^c   Graham, George W ^a   Pan, Xiaoqing ^a,b,d  

^a UNIVERSITY OF MICHIGAN   (United States)

^b University of California at Irvine   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC LAYER DEPOSITION; COATINGS; EXPANSION; LITHIUM-ION BATTERIES; METALS; MORPHOLOGY; OXIDE MINERALS; PHOSPHORUS; TITANIUM DIOXIDE;

AXIAL CONTRACTIONS; ELECTRICAL CONDUCTION; ELECTRICALLY CONDUCTIVE; LITHIATION PROCESS; MORPHOLOGY CONTROL; RADIAL EXPANSIONS; SI NANOWIRES (NWS); VOLUMETRIC EXPANSION;

SILICON;

EID: 84945569481     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/acs.chemmater.5b02565     Document Type: Article

References (26)

1. Armand, M.; Tarascon, J. M. Building better batteries Nature 2008, 451, 652-657 10.1038/451652a
2. Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J.-M.; van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices Nat. Mater. 2005, 4, 366-377 10.1038/nmat1368
3. Liu, X. H.; Zhang, L. Q.; Zhong, L.; Liu, Y.; Zheng, H.; Wang, J. W.; Cho, J.-H.; Dayeh, S. A.; Picraux, S. T.; Sullivan, J. P.; Mao, S. X.; Ye, Z. Z.; Huang, J. Y. Ultrafast Electrochemical Lithiation of Individual Si Nanowire Anodes Nano Lett. 2011, 11, 2251-2258 10.1021/nl200412p
4. Park, Y.; Choi, N.-S.; Park, S.; Woo, S. H.; Sim, S.; Jang, B. Y.; Oh, S. M.; Park, S.; Cho, J.; Lee, K. T. Si-Encapsulating Hollow Carbon Electrodes via Electroless Etching for Lithium-Ion Batteries Adv. Energy Mater. 2013, 3, 206-212 10.1002/aenm.201200389
5. Shu, J.; Li, H.; Yang, R.; Shi, Y.; Huang, X. Cage-like carbon nanotubes/Si composite as anode material for lithium ion batteries Electrochem. Commun. 2006, 8, 51-54 10.1016/j.elecom.2005.08.024
6. Luo, L.; Wu, J.; Luo, J.; Huang, J.; Dravid, V. P. Dynamics of Electrochemical Lithiation/Delithiation of Graphene-Encapsulated Silicon Nanoparticles Studied by In-situ TEM Sci. Rep. 2014, 4, 1-6 10.1038/srep03863
7. Cui, L.-F.; Yang, Y.; Hsu, C.-M.; Cui, Y. Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries Nano Lett. 2009, 9, 3370-3374 10.1021/nl901670t
8. Bogart, T. D.; Oka, D.; Lu, X.; Gu, M.; Wang, C.; Korgel, B. A. Lithium Ion Battery Peformance of Silicon Nanowires with Carbon Skin ACS Nano 2014, 8, 915-922 10.1021/nn405710w
9. Koo, B.; Kim, H.; Cho, Y.; Lee, K. T.; Choi, N.-S.; Cho, J. A Highly Cross-Linked Polymeric Binder for High-Performance Silicon Negative Electrodes in Lithium Ion Batteries Angew. Chem., Int. Ed. 2012, 51, 8762-8767 10.1002/anie.201201568
10. Kovalenko, I.; Zdyrko, B.; Magasinski, A.; Hertzberg, B.; Milicev, Z.; Burtovyy, R.; Luzinov, I.; Yushin, G. A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries Science 2011, 334, 75-79 10.1126/science.1209150
11. Kohandehghan, A.; Kalisvaart, P.; Cui, K.; Kupsta, M.; Memarzadeh, E.; Mitlin, D. Silicon nanowire lithium-ion battery anodes with ALD deposited TiN coatings demonstrate a major improvement in cycling performance J. Mater. Chem. A 2013, 1, 12850-12861 10.1039/c3ta12964k
12. 2coated silicon nanowires for lithium ion battery anodes with enhanced cycling stability and coulombic efficiency Phys. Chem. Chem. Phys. 2013, 15, 13646-13657 10.1039/c3cp52485j
13. Rong, J.; Fang, X.; Ge, M.; Chen, H.; Xu, J.; Zhou, C. Coaxial Si/anodic titanium oxide/Si nanotube arrays for lithium-ion battery anodes Nano Res. 2013, 6, 182-190 10.1007/s12274-013-0294-x
14. 2Coating Layer on Core@Shell Bulk@Nanowire Si Anode Materials for Li-Ion Batteries Adv. Mater. 2013, 25, 4498-4503 10.1002/adma.201301454
15. Yoo, H.; Lee, J.-I.; Kim, H.; Lee, J.-P.; Cho, J.; Park, S. Helical Silicon/Silicon Oxide Core-Shell Anodes Grown onto the Surface of Bulk Silicon Nano Lett. 2011, 11, 4324-4328 10.1021/nl202417c
16. 2Nanocomposite Film Anode for Lithium-Ion Batteries Electrochem. Solid-State Lett. 2008, 11, A105-A107 10.1149/1.2906460
17. McDowell, M. T.; Lee, S. W.; Ryu, I.; Wu, H.; Nix, W. D.; Choi, J. W.; Cui, Y. Novel Size and Surface Oxide Effects in Silicon Nanowires as Lithium Battery Anodes Nano Lett. 2011, 11, 4018-4025 10.1021/nl202630n
18. Bang, B. M.; Kim, H.; Song, H.-K.; Cho, J.; Park, S. Scalable approach to multi-dimensional bulk Si anodes via metal-assisted chemical etching Energy Environ. Sci. 2011, 4, 5013-5019 10.1039/c1ee02310a
19. Jeong, G.; Kim, J.-H.; Kim, Y.-U.; Kim, Y.-J. Multifunctional TiO2 coating for a SiO anode in Li-ion batteries J. Mater. Chem. 2012, 22, 7999-8004 10.1039/c2jm15677f
20. Borghols, W. J. H.; Wagemaker, M.; Lafont, U.; Kelder, E. M.; Mulder, F. M. Impact of Nanosizing on Lithiated Rutile TiO2 Chem. Mater. 2008, 20, 2949-2955 10.1021/cm703376e
21. Karki, K.; Epstein, E.; Cho, J.-H.; Jia, Z.; Li, T.; Picraux, S. T.; Wang, C.; Cumings, J. Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes Nano Lett. 2012, 12, 1392-1397 10.1021/nl204063u
22. Yang, H.; Huang, S.; Huang, X.; Fan, F.; Liang, W.; Liu, X. H.; Chen, L.-Q.; Huang, J. Y.; Li, J.; Zhu, T.; Zhang, S. Orientation-Dependent Interfacial Mobility Governs the Anisotropic Swelling in Lithiated Silicon Nanowires Nano Lett. 2012, 12, 1953-1958 10.1021/nl204437t
23. Hu, Y. S.; Kienle, L.; Guo, Y. G.; Maier, J. High Lithium Electroactivity of Nanometer-Sized Rutile TiO2 Adv. Mater. 2006, 18, 1421-1426 10.1002/adma.200502723
24. Wang, C.-M.; Li, X.; Wang, Z.; Xu, W.; Liu, J.; Gao, F.; Kovarik, L.; Zhang, J.-G.; Howe, J.; Burton, D. J.; Liu, Z.; Xiao, X.; Thevuthasan, S.; Baer, D. R. In Situ TEM Investigation of Congruent Phase Transition and Structural Evolution of Nanostructured Silicon/Carbon Anode for Lithium Ion Batteries Nano Lett. 2012, 12, 1624-1632 10.1021/nl204559u
25. McDowell, M. T.; Woo Lee, S.; Wang, C.; Cui, Y. The effect of metallic coatings and crystallinity on the volume expansion of silicon during electrochemical lithiation/delithiation Nano Energy 2012, 1, 401-410 10.1016/j.nanoen.2012.03.004
26. Karki, K.; Zhu, Y.; Liu, Y.; Sun, C.-F.; Hu, L.; Wang, Y.; Wang, C.; Cumings, J. Hoop-Strong Nanotubes for Battery Electrodes ACS Nano 2013, 7, 8295-8302 10.1021/nn403895h