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Volumn 2, Issue , 2014, Pages 707-738

Safer Solvents and Processes: Deep Eutectic Solvents and their Applications as New Green and Biorenewable Reaction Media

Author keywords

[No Author keywords available]

Indexed keywords

BIORENEWABLE; DEEP EUTECTIC SOLVENTS; REACTION MEDIA;

EID: 84942237592     PISSN: None     EISSN: None     Source Type: Book    
DOI: None     Document Type: Chapter
Times cited : (5)

References (189)
  • 4
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    • A recent editorial in Organic Process Research and Development discourages chemists to use solvents that are either known to be toxic, dangerous for large scale preparations or expensive to dispose as waste.
    • Laird T. Org. Process Res. Dev. 2012, 16:1. A recent editorial in Organic Process Research and Development discourages chemists to use solvents that are either known to be toxic, dangerous for large scale preparations or expensive to dispose as waste.
    • (2012) Org. Process Res. Dev. , vol.16 , pp. 1
    • Laird, T.1
  • 6
    • 67651116322 scopus 로고    scopus 로고
    • 6, Green Solvents: Volume 4: Supercritical Solvents (Eds. W. Leitner and P. G. Jessop); Volume 5: Reactions in Water (Ed. C.-J. Li); Volume 6: Ionic Liquids (Eds. P. Wasserschied and A. Stark); Wiley-VCH, Weinheim, 2010.
    • P. T. Anastas, Handbook of Green Chemistry, Vol. 4, 5 and 6, Green Solvents: Volume 4: Supercritical Solvents (Eds. W. Leitner and P. G. Jessop); Volume 5: Reactions in Water (Ed. C.-J. Li); Volume 6: Ionic Liquids (Eds. P. Wasserschied and A. Stark); Wiley-VCH, Weinheim, 2010.
    • Handbook of Green Chemistry , vol.4-5
    • Anastas, P.T.1
  • 44
    • 84942261174 scopus 로고    scopus 로고
    • Carboxylic acids and sugar polyols have been described as the HBD that lead to the lowest melting point for a selected acceptor salt (HBA). See ref. 24.
    • Carboxylic acids and sugar polyols have been described as the HBD that lead to the lowest melting point for a selected acceptor salt (HBA). See ref. 24.
  • 50
    • 84878752041 scopus 로고    scopus 로고
    • It has been recently demonstrated that, by using molecular dynamics (MD) simulations, the insertion of the urea in DESs could change the density distribution of cations and anions of the eutectic mixture and disrupt the structure of ChCl.
    • Sun H., Li Y., Wu X., Li G. J. Mol. Model. 2013, 19:2433. It has been recently demonstrated that, by using molecular dynamics (MD) simulations, the insertion of the urea in DESs could change the density distribution of cations and anions of the eutectic mixture and disrupt the structure of ChCl.
    • (2013) J. Mol. Model. , vol.19 , pp. 2433
    • Sun, H.1    Li, Y.2    Wu, X.3    Li, G.4
  • 61
    • 85032539725 scopus 로고    scopus 로고
    • As compare to the conventional route, the Perkin reaction in the eutectic mixture 1ChCl/2Urea proceed in a much lower temperature (30°C vs. 140°C).
    • As compare to the conventional route, the Perkin reaction in the eutectic mixture 1ChCl/2Urea proceed in a much lower temperature (30°C vs. 140°C).
  • 89
    • 80051967440 scopus 로고    scopus 로고
    • HMF is a valuable molecule platform, especially for the fabrication of safer polymers and fuel additives. See for example:
    • Karinen R., Vilonen K., Niemelä M. ChemSusChem 2011, 4:1002. HMF is a valuable molecule platform, especially for the fabrication of safer polymers and fuel additives. See for example:.
    • (2011) ChemSusChem , vol.4 , pp. 1002
    • Karinen, R.1    Vilonen, K.2    Niemelä, M.3
  • 104
    • 33746871798 scopus 로고    scopus 로고
    • For a systematic study of the solubility of transition metal oxides of the Period 4th of the periodic table see:
    • Abbott A.P., Capper G., Davies D.L., McKenzie K.J., Obi S.U. J. Chem. Eng. Data 2006, 51:1280. For a systematic study of the solubility of transition metal oxides of the Period 4th of the periodic table see:.
    • (2006) J. Chem. Eng. Data , vol.51 , pp. 1280
    • Abbott, A.P.1    Capper, G.2    Davies, D.L.3    McKenzie, K.J.4    Obi, S.U.5
  • 119
    • 33845919349 scopus 로고    scopus 로고
    • Deposition of Zn, Sn and Zn/Sn alloys from different DESs (ChCl/Urea and ChCl/EG) has been reported in:
    • Abbott A.P., Capper G., McKenzie K.J., Ryder K.S. J. Electroanal. Chem. 2007, 599:288. Deposition of Zn, Sn and Zn/Sn alloys from different DESs (ChCl/Urea and ChCl/EG) has been reported in:.
    • (2007) J. Electroanal. Chem. , vol.599 , pp. 288
    • Abbott, A.P.1    Capper, G.2    McKenzie, K.J.3    Ryder, K.S.4
  • 140
    • 85032550243 scopus 로고    scopus 로고
    • For an outstanding review in the synthesis of polymeric materials in DESs see ref. 23.
    • For an outstanding review in the synthesis of polymeric materials in DESs see ref. 23.
  • 149
    • 85032542165 scopus 로고    scopus 로고
    • For an exceptional and complete review in the synthesis of inorganic materials in DESs see ref. 24.
    • For an exceptional and complete review in the synthesis of inorganic materials in DESs see ref. 24.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.