Large Scale Synthesis and Light Emitting Fibers of Tailor-Made Graphene Quantum Dots

Scientific Reports

Volumn 5, Issue , 2015, Pages

  Park, Hun ^a   Hyun Noh, Sung ^a   Hye Lee, Ji ^b   Jun Lee, Won ^c   Yun Jaung, Jae ^a   Geol Lee, Seung ^b   Hee Han, Tae ^a  

^a Hanyang University   (South Korea)

^b Pusan National University   (South Korea)

^c IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84942011255     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep14163     Document Type: Article

References (50)

1. Hummers, W. S. & Offeman, R. E. Preparation of Graphitic Oxide. J. Am. Chem. Soc. 80, 1339-1339 (1958).
2. Brodie, B. C. Sur Le Poids Atomique Du Graphite. Ann. chim. Phys. 59, 466 (1860).
3. Dreyer, D. R., Park, S., Bielawski, C. W. & Ruoff, R. S. The Chemistry of Graphene Oxide. Chem. Soc. Rev. 39, 228-240 (2010).
4. Luo, J. Y., Kim, J. & Huang, J. X. Material Processing of Chemically Modified Graphene: Some Challenges and Solutions. Acc. Chem. Res. 46, 2225-2234 (2013).
5. Erickson, K. et al. Determination of the Local Chemical Structure of Graphene Oxide and Reduced Graphene Oxide. Adv. Mater. 22, 4467-4472 (2010).
6. Han, T. H., Huang, Y. K., Tan, A. T. L., Dravid, V. P. & Huang, J. X. Steam Etched Porous Graphene Oxide Network for Chemical Sensing. J. Am. Chem. Soc. 133, 15264-15267 (2011).
7. Bagri, A. et al. Structural Evolution During the Reduction of Chemically Derived Graphene Oxide. Nat. Chem. 2, 581-587 (2010).
8. Yang, D. et al. Chemical Analysis of Graphene Oxide Films after Heat and Chemical Treatments by X-Ray Photoelectron and Micro-Raman Spectroscopy. Carbon 47, 145-152 (2009).
9. Li, X. L. et al. Simultaneous Nitrogen Doping and Reduction of Graphene Oxide. J. Am. Chem. Soc. 131, 15939-15944 (2009).
10. Maiti, U. N. et al. 25th Anniversary Article: Chemically Modified/Doped Carbon Nanotubes & Graphene for Optimized Nanostructures & Nanodevices. Adv. Mater. 26, 40-67 (2014).
11. Lee, W. J. et al. Nitrogen-Doped Carbon Nanotubes and Graphene Composite Structures for Energy and Catalytic Applications. Chem. Commun. 50, 6818-6830 (2014).
12. Li, D. & Kaner, R. B. Materials Science - Graphene-Based Materials. Science 320, 1170-1171 (2008).
13. Park, S. & Ruoff, R. S. Chemical Methods for the Production of Graphenes. Nat. Nanotechnol. 4, 217-224 (2009).
14. Compton, O. C. & Nguyen, S. T. Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials. Small 6, 711-723 (2010).
15. Mattevi, C. et al. Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films. Adv. Funct. Mater. 19, 2577-2583 (2009).
16. Zhang, M. et al. Facile Synthesis of Water-Soluble, Highly Fluorescent Graphene Quantum Dots as a Robust Biological Label for Stem Cells. J. Mater. Chem. 22, 7461-7467 (2012).
17. Peng, J. et al. Graphene Quantum Dots Derived from Carbon Fibers. Nano Lett. 12, 844-849 (2012).
18. Zhu, S. J. et al. Strongly Green-Photoluminescent Graphene Quantum Dots for Bioimaging Applications. Chem. Commun. 47, 6858-6860 (2011).
19. Tetsuka, H. et al. Optically Tunable Amino-Functionalized Graphene Quantum Dots. Adv. Mater. 24, 5333-5338 (2012).
20. Jin, S. H., Kim, D. H., Jun, G. H., Hong, S. H. & Jeon, S. Tuning the Photoluminescence of Graphene Quantum Dots through the Charge Transfer Effect of Functional Groups. ACS Nano 7, 1239-1245 (2013).
21. Ananthanarayanan, A. et al. Facile Synthesis of Graphene Quantum Dots from 3d Graphene and Their Application for Fe3+ Sensing. Adv. Funct. Mater. 24, 3021-3026 (2014).
22. Yan, X., Cui, X. & Li, L. S. Synthesis of Large, Stable Colloidal Graphene Quantum Dots with Tunable Size. J. Am. Chem. Soc. 132, 5944-5945 (2010).
23. Liu, R. L., Wu, D. Q., Feng, X. L. & Mullen, K. Bottom-up Fabrication of Photoluminescent Graphene Quantum Dots with Uniform Morphology. J. Am. Chem. Soc. 133, 15221-15223 (2011).
24. Luo, J. Y. et al. Graphene Oxide Nanocolloids. J. Am. Chem. Soc. 132, 17667-17669 (2010).
25. Liu, F. et al. Facile Synthetic Method for Pristine Graphene Quantum Dots and Graphene Oxide Quantum Dots: Origin of Blue and Green Luminescence. Adv. Mater. 25, 3657-3662 (2013).
26. Pan, D. Y., Zhang, J. C., Li, Z. & Wu, M. H. Hydrothermal Route for Cutting Graphene Sheets into Blue-Luminescent Graphene Quantum Dots. Adv. Mater. 22, 734-738 (2010).
27. Pan, D. Y. et al. Cutting Sp(2) Clusters in Graphene Sheets into Colloidal Graphene Quantum Dots with Strong Green Fluorescence. J. Mater. Chem. 22, 3314-3318 (2012).
28. Chen, S., Liu, J. W., Chen, M. L., Chen, X. W. & Wang, J. H. Unusual Emission Transformation of Graphene Quantum Dots Induced by Self-Assembled Aggregation. Chem. Commun. 48, 7637-7639 (2012).
29. Lu, J. et al. One-Pot Synthesis of Fluorescent Carbon Nanoribbons, Nanoparticles, and Graphene by the Exfoliation of Graphite in Ionic Liquids. ACS Nano 3, 2367-2375 (2009).
30. Tang, L. B. et al. Deep Ultraviolet Photoluminescence of Water-Soluble Self-Passivated Graphene Quantum Dots. ACS Nano 6, 5102-5110 (2012).
31. Lin, L. X. & Zhang, S. W. Creating High Yield Water Soluble Luminescent Graphene Quantum Dots Via Exfoliating and Disintegrating Carbon Nanotubes and Graphite Flakes. Chem. Commun. 48, 10177-10179 (2012).
32. Cote, L. J., Kim, F. & Huang, J. X. Langmuir-Blodgett Assembly of Graphite Oxide Single Layers. J. Am. Chem. Soc. 131, 1043-1049 (2009).
33. Bishop, D. F., Stern, G., Fleischm, M. & Marshall, L. S. Hydrogen Peroxide Catalytic Oxidation of Refractory Organics in Municipal Waste Waters. Ind. Eng. Chem. Process Des. Dev. 7, 110-117 (1968).
34. Kitajima, N., Fukuzumi, S. & Ono, Y. Formation of Superoxide Ion During Decomposition of Hydrogen-Peroxide on Supported Metal-Oxides. J. Phys. Chem. 82, 1505-1509 (1978).
35. Yang, F. et al. Influence of Ph on the Fluorescence Properties of Graphene Quantum Dots Using Ozonation Pre-Oxide Hydrothermal Synthesis. J. Mater. Chem. 22, 25471-25479 (2012).
36. Wilson, N. R. et al. Graphene Oxide: Structural Analysis and Application as a Highly Transparent Support for Electron Microscopy. ACS Nano 3, 2547-2556 (2009).
37. Han, T. H. et al. Peptide/Graphene Hybrid Assembly into Core/Shell Nanowires. Adv. Mater. 22, 2060-2064 (2010).
38. Kim, J. et al. Graphene Oxide Sheets at Interfaces. J. Am. Chem. Soc. 132, 8180-8186 (2010).
39. Maiti, U. N., Lim, J., Lee, K. E., Lee, W. J. & Kim, S. O. Three-Dimensional Shape Engineered, Interfacial Gelation of Reduced Graphene Oxide for High Rate, Large Capacity Supercapacitors. Adv. Mater. 26, 615-619 (2014).
40. Delley, B. Dmol(3) Dft Studies: From Molecules and Molecular Environments to Surfaces and Solids. Comp. Mater. Sci. 17, 122-126 (2000).
41. Delley, B. From Molecules to Solids with the Dmol(3) Approach. J. Chem. Phys. 113, 7756-7764 (2000).
42. Sullivan, K. et al. Progressive Deterioration of Patients with Scleroderma with Pulmonary Involvement: 11-Year Outcomes from the Scleroderma Lung Study (Sls1). Clin. Exp. Rheumatol. 32, S17-S18 (2014).
43. Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized Gradient Approximation Made Simple. Phys. Rev. Lett. 77, 3865-3868 (1996).
44. Perdew, J. P., Burke, K. & Wang, Y. Generalized Gradient Approximation for the Exchange-Correlation Hole of a Many-Electron System. Phys. Rev. B 54, 16533-16539 (1996).
45. Sekiya, R., Uemura, Y., Murakami, H. & Haino, T. White-Light-Emitting Edge-Functionalized Graphene Quantum Dots. Angew. Chem. Int. Ed. 53, 5619-5623 (2014).
46. Song, S. H. et al. Primary Hepatocyte Imaging by Multiphoton Luminescent Graphene Quantum Dots. Chem. Commun. 51, 8041-8043 (2015).
47. Kim, J. & Suh, J. S. Size-Controllable and Low-Cost Fabrication of Graphene Quantum Dots Using Thermal Plasma Jet. ACS Nano 8, 4190-4196 (2014).
48. Volarevic, V. et al. Large Graphene Quantum Dots Alleviate Immune-Mediated Liver Damage. ACS Nano 8, 12098-12109 (2014).
49. Tang, L. B. et al. Deep Ultraviolet to near-Infrared Emission and Photoresponse in Layered N-Doped Graphene Quantum Dots. ACS Nano 8, 6312-6320 (2014).
50. Huang, Z. C. et al. Facile Synthesis of Analogous Graphene Quantum Dots with Sp(2) Hybridized Carbon Atom Dominant Structures and Their Photovoltaic Application. Nanoscale 6, 13043-13052 (2014).