Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI)

Nano Research

Volumn 8, Issue 9, 2015, Pages 2913-2924

  Qiao, Botao ^a,b   Liang, Jin Xia ^c,d   Wang, Aiqin ^b   Xu, Cong Qiao ^c   Li, Jun ^c   Zhang, Tao ^b   Liu, Jingyue Jimmy ^a  

^a ARIZONA STATE UNIVERSITY   (United States)

^b DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^c Tsinghua University   (China)

^d GUIZHOU EDUCATION UNIVERSITY   (China)

Author keywords

CO oxidation; covalent metal support interaction; gold catalyst; single atom catalysis

Indexed keywords

EID: 84941749397     PISSN: 19980124     EISSN: 19980000     Source Type: Journal    
DOI: 10.1007/s12274-015-0796-9     Document Type: Article

References (71)

1. Bell, A. T. The impact of nanoscience on heterogeneous catalysis. Science2003, 299, 1688–1691.
2. Chen, M. S.; Goodman, D. W. The structure of catalytically active gold on titania. Science2004, 306, 252–255.
3. Judai, K.; Abbet, S.; Worz, A. S.; Heiz, U.; Henry, C. R. Low-temperature cluster catalysis. J. Am. Chem. Soc. 2004, 126, 2732–2737.
4. Herzing, A. A.; Kiely, C. J.; Carley, A. F.; Landon, P.; Hutchings, G. J. Identification of active gold nanoclusters on iron oxide supports for CO oxidation. Science2008, 321, 1331–1335.
5. Turner, M.; Golovko, V. B.; Vaughan, O. P. H.; Abdulkin, P.; Berenguer- Murcia, A.; Tikhov, M. S.; Johnson, B. F. G.; Lambert, R. M. Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters. Nature2008, 454, 981–983.
6. Vajda, S.; Pellin, M. J.; Greeley, J. P.; Marshall, C. L.; Curtiss, L. A.; Ballentine, G. A.; Elam, J. W.; Catillon-Mucherie, S.; Redfern, P. C.; Mehmood, F. et al. Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane. Nat. Mater. 2009, 8, 213–216.
7. Haruta, M. When gold is not noble: Catalysis by nanoparticles. Chem. Rec. 2003, 3, 75–87.
8. Remediakis, I. N.; Lopez, N.; Nørskov, J. K. CO oxidation on rutile-supported Au nanoparticles. Angew. Chem., Int. Ed. 2005, 44, 1824–1826.
9. Yang, X.-F.; Wang, A. Q.; Qiao, B. T.; Li, J.; Liu, J. Y.; Zhang, T. Single-atom catalysts: A new frontier in heterogeneous catalysis. Acc. Chem. Res. 2013, 46, 1740–1748.
10. Ouyang, R. H.; Liu, J.-X.; Li, W.-X. Atomistic theory of Ostwald ripening and disintegration of supported metal particles under reaction conditions. J. Am. Chem. Soc. 2012, 135, 1760–1771.
11. Hansen, T. W.; DeLaRiva, A. T.; Challa, S. R.; Datye, A. K. Sintering of catalytic nanoparticles: Particle migration or Ostwald ripening? Acc. Chem. Res. 2013, 46, 1720–1730.
12. 4 spinel facets at high temperatures in oxidizing atmospheres. Nat. Commun. 2013, 4, 2481.
13. Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide. J. Catal. 1989, 115, 301–309.
14. Hughes, M. D.; Xu, Y.-J.; Jenkins, P.; McMorn, P.; Landon, P.; Enache, D. I.; Carley, A. F.; Attard, G. A.; Hutchings, G. J.; King, F. et al. Tunable gold catalysts for selective hydrocarbon oxidation under mild conditions. Nature2005, 437, 1132–1135.
15. Corma, A.; Serna, P. Chemoselective hydrogenation of nitro compounds with supported gold catalysts. Science2006, 313, 332–334.
16. Grirrane, A.; Corma, A.; García, H. Gold-catalyzed synthesis of aromatic azo compounds from anilines and nitroaromatics. Science2008, 322, 1661–1664.
17. Wittstock, A.; Zielasek, V.; Biener, J.; Friend, C. M.; Bäumer, M. Nanoporous gold catalysts for selective gas-phase oxidative coupling of methanol at low temperature. Science2010, 327, 319–322.
18. Haruta, M. Spiers memorial Lecture Role of perimeter interfaces in catalysis by gold nanoparticles. Faraday Discuss. 2011, 152, 11–32.
19. Ball, L. T.; Lloyd-Jones, G. C.; Russell, C. A. Gold-catalyzed direct arylation. Science2012, 337, 1644–1648.
20. Bond, G. C.; Louis, C.; Thompson, D. T. Catalysis by Gold; Imperial College Press: London, 2006.
21. Corti, C. W.; Holliday, R. J.; Thompson, D. T. Progress towards the commercial application of gold catalysts. Top. Catal. 2007, 44, 331–343.
22. x. Nat. Chem. 2011, 3, 634–641.
23. x-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes. Nat. Commun.2014, 5, 5634.
24. x single-atom catalyst in water gas shift reaction. J. Am. Chem. Soc.2013, 135, 15314–15317.
25. Fu, Q.; Saltsburg, H.; Flytzani-Stephanopoulos, M. Active nonmetallic Au and Pt species on ceria-based water-gas shift catalysts. Science2003, 301, 935–938.
26. Zhai, Y. P.; Pierre, D.; Si, R.; Deng, W.; Ferrin, P.; Nilekar, A. U.; Peng, G.; Herron, J. A.; Bell, D. C.; Saltsburg, H. Alkali-stabilized Pt-OHx species catalyze low-temperature water-gas shift reactions. Science2010, 329, 1633–1636.
27. Huang, Z. W.; Gu, X.; Cao, Q. Q.; Hu, P. P.; Hao, J. M.; Li, J. H.; Tang, X. F. Catalytically active single-atom sites fabricated from silver particles. Angew. Chem., Int. Ed. 2012, 57, 4198–4203.
28. Kyriakou, G.; Boucher, M. B.; Jewell, A. D.; Lewis, E. A.; Lawton, T. J.; Baber, A. E.; Tierney, H. L.; Flytzani-Stephanopoulos, M.; Sykes, E. C. H. Isolated metal atom geometries as a strategy for selective heterogeneous hydrogenations. Science2012, 335, 1209–1212.
29. Flytzani-Stephanopoulos, M.; Gates, B. C. Atomically dispersed supported metal catalysts. Annu. Rev. Chem. Biomol. Eng. 2012, 3, 545–574.
30. 2 activation and co oxidation: Mechanism efects of hydration oxdation state ad cluster size. ChemCatChem2013, 5, 1811–1821.
31. Zhang, X. F.; Guo, J. J.; Guan, P. F.; Liu, C. J.; Huang, H.; Xue, F. H.; Dong, X. L.; Pennycook, S. J.; Chisholm, M. F. Catalytically active single-atom niobium in graphitic layers. Nat. Commun. 2013, 4, 1924.
32. Sun, S. H.; Zhang, G. X.; Gauquelin, N.; Chen, N.; Zhou, J. G.; Yang, S. L.; Chen, W. F.; Meng, X. B.; Geng, D. S.; Banis, M. N. et al. Single-atom catalysis using Pt/graphene achieved through atomic layer deposition. Sci. Rep. 2013, 3, 1–9.
33. Yang, M.; Allard, L. F.; Flytzani-Stephanopoulos, M. Atomically dispersed Au–(OH)x species bound on titania catalyze the low-temperature water-gas shift reaction. J. Am. Chem. Soc.2013, 135, 3768–3771.
34. 3(010) surface. J. Am. Chem. Soc. 2013, 135, 12634–12645.
35. Peterson, E. J.; DeLaRiva, A. T.; Lin, S.; Johnson, R. S.; Guo, H.; Miller, J. T.; Hun Kwak, J.; Peden, C. H. F.; Kiefer, B.; Allard, L. F. et al. Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina. Nat. Commun. 2014, 5, 4885.
36. Kistler, J. D.; Chotigkrai, N.; Xu, P. H.; Enderle, B.; Praserthdam, P.; Chen, C.-Y.; Browning, N. D.; Gates, B. C. A single-site platinum CO oxidation catalyst in Zeolite KLTL: Microscopic and spectroscopic determination of the locations of the platinum atoms. Angew. Chem., Int. Ed. 2014, 53, 8904–8907.
37. x for CO oxidation. J. Phys. Chem. C2014, 118, 21945–21951.
38. Li, Z.-Y.; Yuan, Z.; Li, X.-N.; Zhao, Y.-X.; He, S.-G. CO oxidation catalyzed by single gold atoms supported on aluminum oxide clusters. J. Am. Chem. Soc.2014, 136, 14307–14313.
39. Liu, Y.; Jia, C.-J.; Yamasaki, J.; Terasaki, O.; Schüth, F. Highly active iron oxide supported gold catalysts for CO oxidation: How small must the gold nanoparticles be? Angew. Chem., Int. Ed. 2010, 49, 5771–5775.
40. Comotti, M.; Li, W.-C.; Spliethoff, B.; Schuth, F. Support effect in high activity gold catalysts for CO oxidation. J. Am. Chem. Soc. 2006, 128, 917–924.
41. Kresse, G.; Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B1999, 59, 1758–1775.
42. 3 ultrafine nanorod arrays. Adv. Mater.2005, 17, 2320–2323.
43. 3. J. Phys. Condens. Matter1996, 8, 983.
44. 3) (0001) surface: Evidence for domains of distinct chemistry. Phys. Rev. Lett. 1998, 81, 1038–1041
45. Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B1994, 50, 17953–17979.
46. Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868.
47. 2 and NiO. Phys. Status Solidi A1998, 166, 429–443.
48. Henkelman, G.; Jonsson, H. A dimer method for finding saddle points on high dimensional potential surfaces using only first derivatives. J. Chem. Phys. 1999, 111, 7010–7022.
49. Freund, H. J.; Meijer, G.; Scheffler, M.; Schlogl, R.; Wolf, M. CO oxidation as a prototypical reaction for heterogeneous processes. Angew. Chem., Int. Ed. 2011, 50, 10064–10094.
50. Shelef, M.; McCabe, R. W. Twenty-five years after introduction of automotive catalysts: What next? Catal. Today2000, 62, 35–50.
51. 4 nanorods. Nature2009, 458, 746–749.
52. Fu, Q.; Li, W.-X.; Yao, Y. X.; Liu, H. Y.; Su, H.-Y.; Ma, D.; Gu, X.-K.; Chen, L. M.; Wang, Z.; Zhang, H. et al. Interfaceconfined ferrous centers for catalytic oxidation. Science2010, 328, 1141–1144.
53. Fang, H.-C.; Li, Z. H.; Fan, K.-N. CO oxidation catalyzed by a single gold atom: Benchmark calculations and the performance of DFT methods. Phys. Chem. Chem. Phys. 2011, 13, 13358–13369.
54. 2-supported gold. J. Catal. 2008, 260, 351–357.
55. 3 catalysts for the CO oxidation and the water-gas shift reactions. Top. Catal. 2007, 44, 199–208.
56. Landman, U.; Yoon, B.; Zhang, C.; Heiz, U.; Arenz, M. Factors in gold nanocatalysis: Oxidation of CO in the nonscalable size regime. Top. Catal. 2007, 44, 145–158.
57. x-hydroxyapatite catalyst for CO oxidation. Chem. Commun. 2011, 47, 1779–781.
58. 2 from ab initio molecular dynamics. J. Am. Chem. Soc. 2013, 135, 10673–10683.
59. 4(001). Phys. Rev. Lett. 2012, 108, 216103.
60. Bartholomew, C. H. Mechanisms of catalyst deactivation. Appl. Catal. A2001, 212, 17–60.
61. 2(111) Surface. J. Phys. Chem. C2013, 117, 23082–23089.
62. – cluster anions. J. Phsy. Chem. Lett. 2014, 5, 1585–1590.
63. 2(110): A density functional theory study. ACS Catal. 2014, 4, 1885–1892.
64. Liu, Z.-P.; Jenkins, S. J.; King, D. A. Origin and activity of oxidized gold in water-gas-shift catalysis. Phys. Rev. Lett. 2005, 94, 196102.
65. + adatoms. J. Am. Chem. Soc. 2009, 131, 10473–10483.
66. x for low-temperature CO oxidation: Direct evidence for a redox mechanism. J. Catal. 2013, 299, 90–100.
67. Glendening, E. D.; Weinhold, F. Natural resonance theory: I. General formalism. J. Comput. Chem. 1998, 19, 593–609.
68. Pyykkö, P.; Atsumi, M. Molecular single-bond covalent radii for elements 1–118. Chem.—Eur. J. 2009, 15, 186–197.
69. Tang, W.; Sanville, E.; Henkelman, G. A grid-based Bader analysis algorithm without lattice bias. J. Phys.: Condens. Matter2009, 21, 084204.
70. Böhme, D. K.; Schwarz, H. Gas-phase catalysis by atomic and cluster metal ions: The ultimate single-site catalysts. Angew. Chem., Int. Ed. 2005, 44, 2336–2354.
71. Thomas, J. M.; Saghi, Z.; Gai, P. L. Can a single atom serve as the active site in some heterogeneous catalysts? Top. Catal. 2011, 54, 588–594.