FeO x -supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes

Nature Communications

Volumn 5, Issue , 2014, Pages

  Wei, Haisheng ^a,b   Liu, Xiaoyan ^a   Wang, Aiqin ^a   Zhang, Leilei ^a   Qiao, Botao ^a,c   Yang, Xiaofeng ^a   Huang, Yanqiang ^a   Miao, Shu ^a   Liu, Jingyue ^a,c   Zhang, Tao ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

3 NITROSTYRENE; AROMATIC NITRO COMPOUND; IRON OXIDE; PLATINUM; STYRENE DERIVATIVE; UNCLASSIFIED DRUG;

AGROCHEMICAL; CATALYST; CHEMICAL BONDING; DYE; MOLECULAR ANALYSIS;

ARTICLE; CATALYST; CHEMICAL BINDING; HIGH ANGLE ANNULAR DARK FIELD SCANNING TRANSMISSION ELECTRON MICROSCOPY; HYDROGENATION; SCANNING TRANSMISSION ELECTRON MICROSCOPY; SPECTROSCOPY; X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY;

EID: 84923323568     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms6634     Document Type: Article

References (35)

1. Ono, N. The Nitro Group in Organic Synthesis (ed. Feuer, H.) (Wiley-VCH, New York, 2001
2. Blaser, H. U., Siegrist, U. & Steiner, H. Aromatic Nitro Compounds: Fine Chemicals Through Heterogeneous Catalysis (eds Sheldon, R. A. & van Bekkum, H.) (Wiley-VCH, Weinheim, 2001
3. Downing, R., Kunkeler, P. & Van Bekkum, H. Catalytic syntheses of aromatic amines. Catal. Today 37, 121-136 (1997
4. Siegrist, U., Baumeister, P., Blaser, H.-U. & Studer, M. Chemical Industries (ed. Herkes, F.) 207-220 (Marcel Dekker, New York, 1998
5. Chen, Y., Wang, C., Liu, H., Qiu, J. & Bao, X. Ag/SiO2: a novel catalyst with high activity and selectivity for hydrogenation of chloronitrobenzenes. Chem. Commun. 5298-5300 (2005
6. Corma, A. & Serna, P. Chemoselective hydrogenation of nitro compounds with supported gold catalysts. Science 313, 332-334 (2006
7. He, D., Shi, H., Wu, Y. & Xu, B.-Q. Synthesis of chloroanilines: selective hydrogenation of the nitro in chloronitrobenzenes over zirconia-supported gold catalyst. Green Chem. 9, 849-851 (2007
8. He, L. et al. Efficient and selective room-temperature gold-catalyzed reduction of nitro compounds with CO and H2O as the hydrogen source. Angew. Chem. Int. Ed. 48, 9538-9541 (2009
9. Shimizu, K. I., Miyamoto, Y. & Satsuma, A. Size-and support-dependent silver cluster catalysis for chemoselective hydrogenation of nitroaromatics. J. Catal. 270, 86-94 (2010
10. Mitsudome, T. et al. Design of a silver-cerium dioxide core-shell nanocomposite catalyst for chemoselective reduction reactions. Angew. Chem. Int. Ed. 51, 136-139 (2012
11. Boronat, M. et al. A molecular mechanism for the chemoselective hydrogenation of substituted nitroaromatics with nanoparticles of gold on TiO2 catalysts: a cooperative effect between gold and the support. J. Am. Chem. Soc. 129, 16230-16237 (2007
12. Cardenas-Lizana, F., Gomez-Quero, S. & Keane, M. A. Exclusive production of chloroaniline from chloronitrobenzene over Au/TiO2 and Au/Al2O3. ChemSusChem 1, 215-221 (2008
13. Liu, L., Qiao, B., Chen, Z., Zhang, J. & Deng, Y. Novel chemoselective hydrogenation of aromatic nitro compounds over ferric hydroxide supported nanocluster gold in the presence of CO and H2O. Chem. Commun. 653-655 (2009
14. Shimizu, K. I. et al. Chemoselective hydrogenation of nitroaromatics by supported gold catalysts: mechanistic reasons of size-and support-dependent activity and selectivity. J. Phys. Chem. C. 113, 17803-17810 (2009
15. Serna, P., Concepcion, P. & Corma, A. Design of highly active and chemoselective bimetallic gold-platinum hydrogenation catalysts through kinetic and isotopic studies. J. Catal. 265, 19-25 (2009
16. Wang, A., Liu, X., Mou, C. Y. & Zhang, T. Understanding the synergistic effects of gold bimetallic catalysts. J. Catal. 308, 258-271 (2013
17. Westerhaus, F. A. et al. Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined complexes. Nat. Chem. 5, 537-543 (2013
18. Jagadeesh, R. V. et al. Nanoscale Fe2O3-based catalysts for selective hydrogenation of nitroarenes to anilines. Science 342, 1073-1076 (2013
19. Zhao, F., Ikushima, Y. & Arai, M. Hydrogenation of nitrobenzene with supported platinum catalysts in supercritical carbon dioxide: effects of pressure, solvent, and metal particle size. J. Catal. 224, 479-483 (2004
20. Corma, A., Serna, P. & Calvino, J. J. Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics. J. Am. Chem. Soc. 130, 8748-8753 (2008
21. Yang, X. F. et al. Single-atom catalysts: a new frontier in heterogeneous catalysis. Acc. Chem. Res. 46, 1740-1748 (2013
22. Qiao, B. et al. Single-atom catalysis of CO oxidation using Pt1/FeOx. Nat. Chem. 3, 634-641 (2011
23. Moses-DeBusk, M. et al. CO oxidation on supported single Pt atoms: experimental and ab initio density functional studies of CO interaction with Pt atom on y-Al2O3(010) surface. J. Am. Chem. Soc. 135, 12634-12645 (2013
24. Fu, Q., Saltsburg, H. & Flytzani-Stephanopoulos, M. Active nonmetallic Au and Pt species on ceria-based water-gas shift catalysts. Science 301, 935-938 (2003
25. Lin, J. et al. Remarkable performance of Ir1/FeOx single-atom catalyst in water gas shift reaction. J. Am. Chem. Soc. 135, 15314-15317 (2013
26. Yang, M., Allard, L. F. & Flytzani-Stephanopoulos, M. Atomically dispersed Au-(OH)x species bound on titania catalyze the low-temperature water-gas shift reaction. J. Am. Chem. Soc. 135, 3768-3771 (2013
27. Guo, X. et al. Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen. Science 344, 616-619 (2014
28. Kwak, J. H., Kovarik, L. & Szanyi, J. Heterogeneous catalysis on atomically dispersed supported metals: CO2 reduction on multifunctional Pd catalysts. ACS Catal. 3, 2094-2100 (2013
29. Zhang, X. et al. Catalytically active single-atom niobium in graphitic layers. Nat. Commun. 4, 1924 (2013
30. Zhang, L. et al. Efficient and durable Au alloyed Pd single-atom catalyst for the ullmann reaction of aryl chlorides in water. ACS Catal. 4, 1546-1553 (2014
31. Kyriakou, G. et al. Isolated metal atom geometries as a strategy for selective heterogeneous hydrogenations. Science 335, 1209-1212 (2012
32. Liu, J. Advanced electron microscopy of metal-support interactions in supported metal catalysts. ChemCatChem 3, 934-948 (2011
33. Zhai, Y. et al. Alkali-stabilized Pt-OHx species catalyze low-temperature watergas shift reactions. Science 329, 1633-1636 (2010
34. Sanchez, S. I. et al. The emergence of nonbulk properties in supported metal clusters: negative thermal expansion and atomic disorder in Pt nanoclusters supported on gamma-Al2O3. J. Am. Chem. Soc. 131, 7040-7054 (2009
35. Serna, P., Boronat, M. & Corma, A. Tuning the behavior of Au and Pt catalysts for the chemoselective hydrogenation of nitroaromatic compounds. Top. Catal. 54, 439-446 (2011