Li2O2 oxidation: the charging reaction in the aprotic Li-O2 batteries

Science Bulletin

Volumn 60, Issue 14, 2015, Pages 1227-1234

  Cui, Qinghua ^a,b   Zhang, Yelong ^a,b   Ma, Shunchao ^a,b   Peng, Zhangquan ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Aprotic Li O2 battery; Charge transport; Initial location upon oxidation; Kinetics; Li2O2 oxidation; Morphology

Indexed keywords

EID: 84941144386     PISSN: 20959273     EISSN: 20959281     Source Type: Journal    
DOI: 10.1007/s11434-015-0837-5     Document Type: Article

References (41)

1. Yang Z, Zhang J, Kintner-Meyer MC et al (2011) Electrochemical energy storage for green grid. Chem Rev 111:3577–3613
2. 2 batteries. Chem Rev 114:5611–5640
3. Wagner FT, Lakshmanan B, Mathias MF (2010) Electrochemistry and the future of the automobile. J Phys Chem Lett 1:2204–2219
4. Whittingham MS (2004) Lithium batteries and cathode materials. Chem Rev 104:4271–4302
5. Armand M, Tarascon J (2008) Building better batteries. Nature 451:652–657
6. 2 and Li-S batteries with high energy storage. Nat Mater 11:19–29
7. Abraham KM, Jiang ZA (1996) Polymer electrolyte-based rechargeable lithium/oxygen battery. J Electrochem Soc 143:1–5
8. Yang FY, Liu QC, Xu JJ et al (2013) Development of key materials in non-aqueous Li-air battery. Chin Sci Bull (Chin Ver) 58:3199–3212 (in Chinese)
9. Zhang M, Xu Q, Sang L et al (2014) A novel monoclinic manganite/multi-walled carbon nanotubes composite as a cathode material of lithium-air batteries. Chin Sci Bull 59:2973–2979
10. 2 battery. Science 337:563–566
11. 2 electrode for lithium batteries. J Am Chem Soc 128:1390–1393
12. Laoire CO, Mukerjee S, Abraham KM et al (2009) Elucidating the mechanism of oxygen reduction for lithium-air battery applications. J Phys Chem C 113:20127–20134
13. 2 batteries. Energy Environ Sci 4:2999–3007
14. 2 battery. J Electrochem Soc 158:A302–A308
15. Leskes M, Drewett NE, Hardwick LJ et al (2012) Direct detection of discharge products in lithium-oxygen batteries by solid-state NMR spectroscopy. Angew Chem Int Ed 124:8688–8691
16. 2 battery and its effect on charge. Energy Environ Sci 6:1772–1778
17. 2. Chem Mater 26:2952–2959
18. Lu J, Lei Y, Lau KC et al (2013) A nanostructured cathode architecture for low charge overpotential in lithium-oxygen batteries. Nat Commun 4:2383
19. 2 nanoparticles. Nano Lett 13:4679–4684
20. Kim BG, Kim HJ, Back S et al (2014) Improved reversibility in lithium-oxygen battery: understanding elementary reactions and surface charge engineering of metal alloy catalyst. Sci Rep 4:4225
21. Laoire CO, Mukerjee S, Abraham KM et al (2010) Influence of nonaqueous solvents on the electrochemistry of oxygen in the rechargeable lithium-air battery. J Phys Chem C 114:9178–9186
22. + electrolyte. Angew Chem Int Ed 50:6351–6355
23. Luntz AC, McCloskey BD (2014) Nonaqueous Li-air batteries: a status report. Chem Rev 114:11721–11750
24. 2 batteries. J Phys Chem Lett 4:93–99
25. 2 batteries. Energy Environ Sci 6:2518–2528
26. 2 electrochemistry on C and its kinetic overpotentials: some implications for Li-air batteries. J Phys Chem C 116:23897–23905
27. 2 batteries based on a large surface area carbon cathode. J Am Chem Soc 135:15364–15372
28. 2 kinetic overpotentials: Tafel plots from experiment and first-principles theory. J Phys Chem Lett 4:556–560
29. 2 batteries: high activity of chromium oxides. Phys Chem Chem Phys 16:2297–2304
30. 2 for rechargeable Li-air battery applications. Phys Chem Chem Phys 14:10540–10546
31. 2. Nano Lett 13:2209–2214
32. Zheng H, Xiao D, Li X et al (2014) New insight in understanding oxygen reduction and evolution in solid-state lithium-oxygen batteries using an in situ environmental scanning electron microscope. Nano Lett 14:4245–4249
33. 2. Adv Mater 25:3129–3133
34. 2 0001 surfaces. J Mater Sci 47:7564–7570
35. Radin MD, Rodriguez JF, Tian F et al (2012) Lithium peroxide surfaces are metallic while lithium oxide surfaces are not. J Am Chem Soc 134:1093–10103
36. Hummelshoj JS, Blomqvist J, Datta S et al (2010) Communications: elementary oxygen electrode reactions in the aprotic Li-air battery. J Chem Phys 132:071101
37. Ong SP, Mo Y, Ceder G (2012) Low hole polaron migration barrier in lithium peroxide. Phys Rev B 85:081105
38. 2 for Li-air batteries. Phys Rev B 85:035210
39. 2: implications for Li-air batteries. J Phys Chem C 117:5568–5577
40. Radin MD, Siegel DJ (2013) Charge transport in lithium peroxide: relevance for rechargeable metal–air batteries. Energy Environ Sci 6:2370–2379
41. 2 batteries. Adv Energy Mater 5:1400664