Black-to-Transmissive Electrochromism with Visible-to-Near-Infrared Switching of a Co(II)-Based Metallo-Supramolecular Polymer for Smart Window and Digital Signage Applications

ACS Applied Materials and Interfaces

Volumn 7, Issue 33, 2015, Pages 18266-18272

  Hsu, Chih Yu ^a,c   Zhang, Jian ^a,b   Sato, Takashi ^a,b   Moriyama, Satoshi ^b,c   Higuchi, Masayoshi ^a,b  

^a Electronic Functional Materials Group Polymer Materials Unit ^*  (Japan)

^b NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^c JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

aqueous; bisterpyridine; cobalt; electrochromism; metallo supramolecular polymer

Indexed keywords

ELECTROCHROMISM; ELECTROMAGNETIC WAVE ABSORPTION; INFRARED DEVICES; ITO GLASS; LIGHT ABSORPTION; METAL IONS; METALS; POLYMER FILMS; POLYMERS; REDOX REACTIONS; SOLUTIONS; SUPRAMOLECULAR CHEMISTRY; THIN FILMS;

AQUEOUS; AQUEOUS ELECTROLYTE SOLUTIONS; BISTERPYRIDINE; CENTRAL METALS; DIGITAL SIGNAGE; ELECTROCHROMIC PERFORMANCE; HYDROXIDE IONS; METALLO-SUPRAMOLECULAR;

COBALT;

EID: 84940546569     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.5b02990     Document Type: Article

References (35)

1. Platt, J. R. Electrochromism, a Possible Change of Color Producible in Dyes by an Electric Field J. Chem. Phys. 1961, 34, 862-863 10.1063/1.1731686
2. Monk, P. M. S.; Mortimer, R. J.; Rosseinsky, D. R. Electrochromism and Electrochromic Devices; Cambridge University Press: Cambridge, U.K., 2007.
3. Mortimer, R. J. Electrochromic Materials Chem. Soc. Rev. 1997, 26, 147-156 10.1039/cs9972600147
4. Pichot, F.; Beck, J. H.; Elliott, C. M. A Series of Multicolor Electrochromic Ruthenium(II) Trisbipyridine Complexes: Synthesis and Electrochemistry J. Phys. Chem. A 1999, 103, 6263-6267 10.1021/jp991196w
5. Yamamoto, K.; Higuchi, M.; Shiki, S.; Tsuruta, M.; Chiba, H. Stepwise Radial Complexation of Imine Groups in Phenylazomethine Dendrimers Nature 2002, 415, 509-511 10.1038/415509a
6. Nishihara, H.; Kanaizuka, K.; Nishimori, Y.; Yamanoi, Y. Construction of Redox- and Photo-Functional Molecular Systems on Electrode Surface for Application to Molecular Devices Coord. Chem. Rev. 2007, 251, 2674-2687 10.1016/j.ccr.2007.04.002
7. Burnworth, M.; Tang, L.; Kumpfer, J. R.; Duncan, A. J.; Beyer, F. L.; Fiore, G. L.; Rowan, S. J.; Weder, C. Optically Healable Supramolecular Polymers Nature 2011, 472, 334-337 10.1038/nature09963
8. Wojtecki, R. J.; Meador, M. A.; Rowan, S. J. Using the Dynamic Bond to Access Macroscopically Responsive Structurally Dynamic Polymers Nat. Mater. 2011, 10, 14-27 10.1038/nmat2891
9. Whittell, G. R.; Hager, M. D.; Schubert, U. S.; Manners, I. Functional Soft Materials from Metallopolymers and Metallosupramolecular Polymers Nat. Mater. 2011, 10, 176-188 10.1038/nmat2966
10. Garcia-Canadas, J.; Meacham, A. P.; Peter, L. M.; Ward, M. D. A Near-Infrared Electrochromic Window Based on an Sb-Doped SnO2 Electrode Modified with a Ru-Dioxolene Complex Angew. Chem., Int. Ed. 2003, 42, 3011-3014 10.1002/anie.200351338
11. Yao, C.-J.; Zhong, Y.-W.; Yao, J. Five-Stage Near-Infrared Electrochromism in Electropolymerized Films Composed of Alternating Cyclometalated Bisruthenium and Bis-triarylamine Segments Inorg. Chem. 2013, 52, 10000-10008 10.1021/ic401288g
12. Higuchi, M. Stimuli-Responsive Metallo-Supramolecular Polymer Films: Design, Synthesis and Device Fabrication J. Mater. Chem. C 2014, 2, 9331-9341 10.1039/C4TC00689E
13. Han, F. S.; Higuchi, M.; Kurth, D. G. Metallo-Supramolecular Polyelectrolytes Self-assembled from Various Pyridine Ring Substituted Bis-terpyridines and Metal Ions: Photophysical, Electrochemical and Electrochromic Properties J. Am. Chem. Soc. 2008, 130, 2073-2081 10.1021/ja710380a
14. Hu, C.-W.; Sato, T.; Zhang, J.; Moriyama, S.; Higuchi, M. Multi-Colour Electrochromic Properties of Fe/Ru-Based Bimetallo-Supramolecular Polymers J. Mater. Chem. C 2013, 1, 3408-3413 10.1039/c3tc30440j
15. Chen, P.; Meyer, T. J. Medium Effects on Charge Transfer in Metal Complexes Chem. Rev. 1998, 98, 1439-1478 10.1021/cr941180w
16. Operschall, B.; Bianchi, E.; Griesser, R.; Sigel, H. Influence of Decreasing Solvent Polarity (1,4-Dioxane/Water Mixtures) on the Stability and Structure of Complexes Formed by Copper(II), 2,2′-Bipyridine or 1,10-Phenanthroline and Guanosine 5′-Diphosphate: Evaluation of Isomeric Equilibria J. Coord. Chem. 2009, 62, 23-39 10.1080/00958970802474888
17. Levina, V. A.; Filippov, O. A.; Gutsul, E. I.; Belkova, N. V.; Epstein, L. M.; Lledos, A.; Shubina, E. S. Neutral Transition Metal Hydrides as Acids in Hydrogen Bonding and Proton Transfer: Media Polarity and Specific Solvation Effects J. Am. Chem. Soc. 2010, 132, 11234-11246 10.1021/ja103862r
18. Potts, K. T.; Usifer, D. A.; Guadalupe, A.; Abruna, H. D. 4-Vinyl-, 6-Vinyl-, and 4′-Viny1-2,2′:6′,2{combining double acute accent}-terpyridinyl Ligands: Their Synthesis and the Electrochemistry of Their Transition-Metal Coordination Complexes J. Am. Chem. Soc. 1987, 109, 3961-3967 10.1021/ja00247a021
19. Dadci, L.; Elias, H.; Frey, U.; Hörnig, A.; Koelle, U.; Merbach, A. E.; Paulus, H.; Schneider, J. S. π-Arene Aqua Complexes of Cobalt, Rhodium, Iridium, and Ruthenium: Preparation, Structure, and Kinetics of Water Exchange and Water Substitution Inorg. Chem. 1995, 34, 306-315 10.1021/ic00105a048
20. Feldheim, D. L.; Baldy, C. J.; Sebring, P.; Hendrickson, S. M.; Elliott, C. M. Synthesis and Catalytic Activity of Transition Metal Polymers Containing Alkane-Linked Bipyridine and Terpyridine Ligands J. Electrochem. Soc. 1995, 142, 3366-3372 10.1149/1.2049988
21. Krishnan, C. V.; Sutin, N. Homogeneous Catalysis of the Photoreduction of Water by Visible Light. 2. Mediation by a Tris(2,2′-bipyridine)ruthenium(II)-Cobalt(II) Bipyridine System J. Am. Chem. Soc. 1981, 103, 2141-2142 10.1021/ja00398a066
22. Thoi, V. S.; Sun, Y.; Long, J. R.; Chang, C. J. Complexes of Earth-Abundant Metals for Catalytic Electrochemical Hydrogen Generation under Aqueous Conditions Chem. Soc. Rev. 2013, 42, 2388-2400 10.1039/C2CS35272A
23. Schull, T. L.; Henley, L.; Deschamps, J. R.; Butcher, R. J.; Maher, D. P.; Klug, C. A.; Swider-Lyons, K.; Dressick, W. J.; Bujoli, B.; Greenwood, A. E.; Congiardo, L. K. B.; Knight, D. A. Organometallic Supramolecular Mixed-Valence Cobalt(I)/Cobalt(II) Aquo Complexes Stabilized with the Water-Soluble Phosphine Ligand p-TPPTP (p-triphenylphosphine triphosphonic acid) Organometallics 2007, 26, 2272-2276 10.1021/om060898m
24. Robin, M. B.; Day, P. Mixed Valence Chemistry-A Survey and Classification Adv. Inorg. Chem. Radiochem. 1968, 10, 247-422 10.1016/S0065-2792(08)60179-X
25. Szymczak, N. K.; Berben, L. A.; Peters, J. C. Redox Rich Dicobalt Macrocycles as Templates for Multi-Electron Transformations Chem. Commun. 2009, 6729-6731 10.1039/b913946j
26. Beaujuge, P. M.; Ellinger, S.; Reynolds, J. R. The Donor-Acceptor Approach Allows a Black-to-Transmissive Switching Polymeric Electrochrome Nat. Mater. 2008, 7, 795-799 10.1038/nmat2272
27. Shi, P.; Amb, C. M.; Knott, E. P.; Thompson, E. J.; Liu, D. Y.; Mei, J.; Dyer, A. L.; Reynolds, J. R. Broadly Absorbing Black to Transmissive Switching Electrochromic Polymers Adv. Mater. 2010, 22, 4949-4953 10.1002/adma.201002234
28. İçli, M.; Pamuk, M.; Algi, F.; Onal, A. M.; Cihaner, A. A New Soluble Neutral State Black Electrochromic Copolymer via a Donor-Acceptor Approach Org. Electron. 2010, 11, 1255-1260 10.1016/j.orgel.2010.05.001
29. Yen, H.-J.; Lin, K.-Y.; Liou, G.-S. Transmissive to Black Electrochromic Aramids with High Near-Infrared and Multicolor Electrochromism based on Electroactive Tetraphenylbenzidine Units J. Mater. Chem. 2011, 21, 6230-6237 10.1039/c1jm10210a
30. Ding, G.; Cho, C. M.; Chen, C.; Zhou, D.; Wang, X.; Tan, A. Y. X.; Xu, J.; Lu, X. Black-to-Transmissive Electrochromism of Azulene-based Donor-Acceptor Copolymers Complemented by Poly(4-styrene sulfonic acid)-doped Poly(3,4-ethylenedioxythiophene) Org. Electron. 2013, 14, 2748-2755 10.1016/j.orgel.2013.07.037
31. Weissbecher, J.; Loas, A.; Gorun, S. M.; Schlettwein, D. Switching of the Rate-limiting Step in the Electrochromic Reduction of Fluorinated Phthalocyanine Thin Films by Decreased Intermolecular Coupling Electrochim. Acta 2015, 157, 232-244 10.1016/j.electacta.2015.01.063
32. Buriez, O.; Labbé, E.; Périchon, J. Unexpected Stabilization of a Simple Cobalt(I) Salt in Acetonitrile at a Glassy Carbon Electrode J. Electroanal. Chem. 2006, 593, 99-104 10.1016/j.jelechem.2006.03.018
33. Chen, D.; Fabre, P.-L.; Reynes, O. Electrocarboxylation of Chloroacetonitrile by a Cobalt(I) Complex of Terpyridine Electrochim. Acta 2011, 56, 8603-8610 10.1016/j.electacta.2011.07.052
34. Guadalupe, A. R.; Usifer, D. A.; Potts, K. T.; Hurrell, H. C.; Mogstad, A.-E.; Abruna, H. D. Novel Chemical Pathways and Charge-Transport Dynamics of Electrodes Modified with Electropolymerized Layers of [Co(v-terpy)2]2+ J. Am. Chem. Soc. 1988, 110, 3462-3466 10.1021/ja00219a020
35. Takada, K.; Sakamoto, R.; Yi, S.-T.; Katagiri, S.; Kambe, T.; Nishihara, H. Electrochromic Bis(terpyridine)metal Complex Nanosheets J. Am. Chem. Soc. 2015, 137, 4681-4689 10.1021/ja510788b