Structural Defects of Silver Hollandite, AgxMn8Oy, Nanorods: Dramatic Impact on Electrochemistry

ACS Nano

Volumn 9, Issue 8, 2015, Pages 8430-8439

  Wu, Lijun ^a   Xu, Feng ^a,b   Zhu, Yimei ^a   Brady, Alexander B ^d   Huang, Jianping ^c   Durham, Jessica L ^c   Dooryhee, Eric ^e   Marschilok, Amy C ^c,d   Takeuchi, Esther S ^c,d,e   Takeuchi, Kenneth J ^c,d  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b Southeast University   (China)

^c STONY BROOK UNIVERSITY   (United States)

^d Stony Brook University   (United States)

^e BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

electron energy loss spectroscopy; lithium battery; octahedral molecular sieve; oxygen defects; silver hollandite; transmission electron microscopy

Indexed keywords

C (PROGRAMMING LANGUAGE); CRYSTALLITE SIZE; DISSOCIATION; ELECTRON EMISSION; ELECTRON ENERGY LEVELS; ELECTRON SCATTERING; ELECTRONS; ENERGY DISSIPATION; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; LITHIUM BATTERIES; MANGANESE; MANGANESE COMPOUNDS; MOLECULAR OXYGEN; MOLECULAR SIEVES; NANORODS; OXYGEN VACANCIES; SILVER; SURFACE DEFECTS; THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY;

BATTERY PERFORMANCE; BULK MEASUREMENT; OCTAHEDRAL MOLECULAR SIEVES; OXYGEN DEFECT; SELECTED AREA DIFFRACTION; SILVER HOLLANDITE; STRUCTURAL DEFECT; TUNNEL STRUCTURES;

ELECTRON ENERGY LOSS SPECTROSCOPY;

EID: 84940036554     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/acsnano.5b03274     Document Type: Article

References (36)

1. Nicolas-Tolentino, E.; Tian, Z.-R.; Zhou, H.; Xia, G.; Suib, S. L. Effects of Cu2+ Ions on the Structure and Reactivity of Todorokite- and Cryptomelane-Type Manganese Oxide Octahedral Molecular Sieves Chem. Mater. 1999, 11, 1733-1741 10.1021/cm9811040
2. Tsuji, M.; Komarneni, S. Selective Exchange of Divalent Transition Metal Ions in Cryptomelane-Type Manganic Acid with Tunnel Structure J. Mater. Res. 1993, 8, 611-616 10.1557/JMR.1993.0611
3. Li, L.; King, D. L. Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control Chem. Mater. 2005, 17, 4335-4343 10.1021/cm0506508
4. Dyer, A.; Pillinger, M.; Newton, J.; Harjula, R.; Möller, T.; Amin, S. Sorption Behavior of Radionuclides on Crystalline Synthetic Tunnel Manganese Oxides Chem. Mater. 2000, 12, 3798-3804 10.1021/cm001142v
5. Dharmarathna, S.; King'ondu, C. K.; Pedrick, W.; Pahalagedara, L.; Suib, S. L. Direct Sonochemical Synthesis of Manganese Octahedral Molecular Sieve (OMS-2) Nanomaterials Using Cosolvent Systems, Their Characterization, and Catalytic Applications Chem. Mater. 2012, 24, 705-712 10.1021/cm203366m
6. Huang, H.; Sithambaram, S.; Chen, C.-H.; King'ondu Kithongo, C.; Xu, L.; Iyer, A.; Garces, H. F.; Suib, S. L. Microwave-Assisted Hydrothermal Synthesis of Cryptomelane-Type Octahedral Molecular Sieves (OMS-2) and Their Catalytic Studies Chem. Mater. 2010, 22, 3664-3669 10.1021/cm100220g
7. Ching, S.; Suib, S. L. Synthetic Routes to Microporous Maganese Oxides Comments Inorg. Chem. 1997, 19, 263-282 10.1080/02603599708032741
8. Vicat, J.; Fanchon, E.; Strobel, P.; Duc Tran, Q. The Structure of K1.33Mn8O16 and Cation Ordering in Hollandite-Type Structures Acta Crystallogr., Sect. B: Struct. Sci. 1986, B42, 162-167 10.1107/S0108768186098415
9. Ozawa, T.; Suzuki, I.; Sato, H. Structural, Magnetic, and Electronic Transport Properties of Novel Hollandite-Type Molybdenum Oxide, Rb1.5Mo8O16 J. Phys. Soc. Jpn. 2006, 75, 014802-1-014802-8 10.1143/JPSJ.75.014802
10. Li, W.-N.; Crisostomo, V. M. B.; Nyutu, E. K.; Ding, Y.-S.; Suib, S. L. Transitional Metal Oxide (TMO) Nanorods: Synthesis, Characterization, Properties and Applications Nanorods, Nanotubes Nanomater. Res. Prog. 2008, 203-238
11. Suib, S. L.; O'Young, C.-L. Synthesis of Octahedral Molecular Sieves and Layered Materials Chem. Ind. (Boca Raton, FL, U. S.) 1997, 69, 215-231
12. Brock, S. L.; Duan, N.; Tian, Z. R.; Giraldo, O.; Zhou, H.; Suib, S. L. A Review of Porous Manganese Oxide Materials Chem. Mater. 1998, 10, 2619-2628 10.1021/cm980227h
13. Chang, F. M.; Jansen, M. Ag1.8Mn8O16: Square planar coordinated Ag+ ions in the channels of a novel hollandite variant Angew. Chem., Int. Ed. Engl. 1984, 23, 906-907 10.1002/anie.198409061
14. Chang, F. M.; Jansen, M. The First Silver Hollandite Rev. Chim. Miner. 1986, 23, 48-54
15. Chen, J.; Tang, X.; Liu, J.; Zhan, E.; Li, J.; Huang, X.; Shen, W. Synthesis and Characterization of Ag-hollandite Nanofibers and its Catalytic Application in Ethanol Oxidation Chem. Mater. 2007, 19, 4292-4299 10.1021/cm070904k
16. 16 Nanorods and their Electrochemical Lithium-Storage Properties J. Nanopart. Res. 2011, 13, 3139-3148 10.1007/s11051-010-0209-7
17. Zhu, S.; Marschilok, A. C.; Lee, C.-Y.; Takeuchi, E. S.; Takeuchi, K. J. Synthesis and Electrochemistry of Silver Hollandite Electrochem. Solid-State Lett. 2010, 13, A98-A100 10.1149/1.3428747
18. Takeuchi, K. J.; Yau, S. L. Z.; Menard, M. C.; Marschilok, A. C.; Takeuchi, E. S. Synthetic Control of Composition and Crystallite Size of Silver Hollandite, AgxMn8O16: Impact on Electrochemistry ACS Appl. Mater. Interfaces 2012, 4, 5547-5554 10.1021/am301443g
19. Takeuchi, K. J.; Yau, S. Z.; Subramanian, A.; Marschilok, A. C.; Takeuchi, E. S. The Electrochemistry of Silver Hollandite Nanorods, AgxMn8O16: Enhancement of Electrochemical Battery Performance via Dimensional and Compositional Control J. Electrochem. Soc. 2013, 160, A3090-A3094 10.1149/2.014305jes
20. Liu, S.; Akbashev, A. R.; Yang, X.; Liu, X.; Li, W.; Zhao, L.; Li, X.; Couzis, A.; Han, M.-G.; Zhu, Y. Hollandites as a New Class of Multiferroics Sci. Rep. 2014, 4, 6203 10.1038/srep06203
21. Kim, S.-W.; Lee, H.-W.; Muralidharan, P.; Seo, D.-H.; Yoon, W.-S.; Kim, D.; Kang, K. Electrochemical performance and ex situ analysis of ZnMn2O4 nanowires as anode materials for lithium rechargeable batteries Nano Res. 2011, 4, 505-510 10.1007/s12274-011-0106-0
22. Shao-Horn, Y.; Hackney, S. A.; Johnson, C. S.; Thackeray, M. M. Microstructural Features of α-MnO2 Electrodes for Lithium Batteries J. Electrochem. Soc. 1998, 145, 582-589 10.1149/1.1838307
23. Gao, T.; Norby, P. Frame Stability of Tunnel-Structured Cryptomelane Nanofibers: The Role of Tunnel Cations Eur. J. Inorg. Chem. 2013, 2013, 4948-4957 10.1002/ejic.201300602
24. Riedl, T.; Gemming, T.; Wetzig, K. Extraction of EELS White-Line Intensities of Manganese Compounds: Methods, Accuracy, and Valence Sensitivity Ultramicroscopy 2006, 106, 284-291 10.1016/j.ultramic.2005.09.002
25. Feng, Q.; Kanoh, H.; Miyai, Y.; Ooi, K. Alkali Metal Ions Insertion/Extraction Reactions with Hollandite-Type Manganese Oxide in the Aqueous Phase Chem. Mater. 1995, 7, 148-153 10.1021/cm00049a023
26. 2 Phase with the Tunnel Structure Phys. Chem. Chem. Phys. 2000, 2, 1473-1479 10.1039/a907614j
27. Huang, H.; Meng, Y.; Labonte, A.; Dobley, A.; Suib, S. L. Large-Scale Synthesis of Silver Manganese Oxide Nanofibers and Their Oxygen Reduction Properties J. Phys. Chem. C 2013, 117, 25352-25359 10.1021/jp409507h
28. Chen, J.; Tang, X.; Liu, J.; Zhan, E.; Li, J.; Huang, X.; Shen, W. Synthesis and Characterization of Ag-Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation Chem. Mater. 2007, 19, 4292-4299 10.1021/cm070904k
29. Suib, S. L. Structure, Porosity, and Redox in Porous Manganese Oxide Octahedral Layer and Molecular Sieve Materials J. Mater. Chem. 2008, 18, 1623-1631 10.1039/b714966m
30. 16: square planar coordinated Ag+ ions in the channels of a novel hollandite variant Angew. Chem., Int. Ed. Engl. 1984, 23, 906-907 10.1002/anie.198409061
31. Pearson, D. H.; Ahn, C. C.; Fultz, B. White Lines and d-Electron Occupancies for the 3d and 4d Transition Metals Phys. Rev. B: Condens. Matter Mater. Phys. 1993, 47, 8471-8478 10.1103/PhysRevB.47.8471
32. Kirkland, E. J. Advanced Computing in Electron Microscopy; Plenum: New York, 1998.
33. Hammersley, A. P.; Svensson, S. O.; Hanfland, M.; Fitch, A. N.; Häusermann, D. Two-Dimensional Detector Software: From Real Detector to Idealised Image or Two-Theta Scan High Pressure Res. 1996, 14, 235-248 10.1080/08957959608201408
34. Toby, B. H.; Von Dreele, R. B. GSAS-II: The Genesis of a Modern Open-Source all purpose Crystallography Software Package J. Appl. Crystallogr. 2013, 46, 544-549 10.1107/S0021889813003531
35. Pawley, G. Unit-Cell Refinement from Powder Diffraction Scans J. Appl. Crystallogr. 1981, 14, 357-361 10.1107/S0021889881009618
36. Toby, B.H. R Factors in Rietveld Analysis: How Good Is Good Enough? Powder Diffr. 2006, 21, 67 10.1154/1.2179804