Combining Fast Li-Ion Battery Cycling with Large Volumetric Energy Density: Grain Boundary Induced High Electronic and Ionic Conductivity in Li4Ti5O12 Spheres of Densely Packed Nanocrystallites

Chemistry of Materials

Volumn 27, Issue 16, 2015, Pages 5647-5656

  Wang, Chao ^a   Wang, Shuan ^a   He, Yan Bing ^a   Tang, Linkai ^a   Han, Cuiping ^a   Yang, Cheng ^a   Wagemaker, Marnix ^b   Li, Baohua ^a   Yang, Quan Hong ^a   Kim, Jang Kyo ^c   Kang, Feiyu ^a  

^a TSINGHUA UNIVERSITY   (China)

^b DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

^c HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

AMPHIBIOUS VEHICLES; CARBON; CHARGING (BATTERIES); ELECTRIC BATTERIES; ELECTRIC TOOLS; ELECTRODES; ELECTRON TRANSPORT PROPERTIES; GRAIN BOUNDARIES; IONS; LITHIUM; LITHIUM COMPOUNDS; NANOCRYSTALLITES; NANOCRYSTALS; SECONDARY BATTERIES; SELF ASSEMBLY;

ELECTRONIC AND IONIC CONDUCTIVITY; ELECTRONIC CONDUCTIVITY; GRAVIMETRIC ENERGY DENSITIES; HIGH-RATE PERFORMANCE; INTERCONNECTED NETWORK; ION DIFFUSION COEFFICIENT; SELF ASSEMBLY PROCESS; VOLUMETRIC ENERGY DENSITIES;

LITHIUM-ION BATTERIES;

EID: 84940035498     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/acs.chemmater.5b02027     Document Type: Article

References (44)

1. Dunn, B.; Kamath, H.; Tarascon, J.-M. Electrical energy storage for the grid: a battery of choices Science 2011, 334, 928 10.1126/science.1212741
2. Park, G.; Gunawardhana, N.; Nakamura, H.; Lee, Y.-S.; Yoshio, M. The study of electrochemical properties and lithium deposition of graphite at low temperature J. Power Sources 2012, 199, 293 10.1016/j.jpowsour.2011.10.058
3. Zhang, S. S.; Xu, K.; Jow, T. R. The low temperature performance of Li-ion batteries J. Power Sources 2003, 115, 137 10.1016/S0378-7753(02)00618-3
4. 2-based Li-ion battery J. Power Sources 2006, 160, 1349 10.1016/j.jpowsour.2006.02.087
5. Bruce, P. G.; Scrosati, B.; Tarascon, J.-M. Nanomaterials for Rechargeable Lithium Batteries Angew. Chem., Int. Ed. 2008, 47, 2930 10.1002/anie.200702505
6. Choi, N.-S.; Chen, Z.; Freunberger, S. A.; Ji, X.; Sun, Y.-K.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho, J.; Bruce, P. G. Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors Angew. Chem., Int. Ed. 2012, 51, 9994 10.1002/anie.201201429
7. 12 for lithium ion batteries J. Am. Chem. Soc. 2008, 130, 14930 10.1021/ja806104n
8. 4 nanoparticles on graphene as flexible paper for supercapacitor J. Mater. Chem. A 2014, 2, 12068 10.1039/C4TA01442A
9. 12 Spinel J. Am. Chem. Soc. 2009, 131, 17786 10.1021/ja902423e
10. 12 anodes for room-temperature sodium-ion batteries Nat. Commun. 2013, 4, 1870 10.1038/ncomms2878
11. 12 Spinel: The Full Static Picture from Electron Microscopy Adv. Mater. 2012, 24, 3233 10.1002/adma.201200450
12. 12 Nanosheets with a N-Doped Carbon Coating for High Rate Lithium Ion Batteries Adv. Funct. Mater. 2013, 23, 5429 10.1002/adfm.201300495
13. 12 Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method Adv. Funct. Mater. 2011, 21, 4349 10.1002/adfm.201101123
14. Shen, L.; Li, H.; Uchaker, E.; Zhang, X.; Cao, G. General Strategy for Designing Core-Shell Nanostructured Materials for High-Power Lithium Ion Batteries Nano Lett. 2012, 12, 5673 10.1021/nl302854j
15. Zhang, B.; Yu, Y.; Liu, Y.; Huang, Z.-D.; He, Y.-b.; Kim, J.-K. Percolation threshold of graphene nanosheets as conductive additives in Li 4 Ti 5 O 12 anodes of Li-ion batteries Nanoscale 2013, 5, 2100 10.1039/c2nr33099g
16. 12 porous electrodes for Li-ion batteries J. Power Sources 2011, 196, 10692 10.1016/j.jpowsour.2011.08.114
17. Feckl, J. M.; Fominykh, K.; Doblinger, M.; Fattakhova-Rohlfing, D.; Bein, T. Nanoscale porous framework of lithium titanate for ultrafast lithium insertion Angew. Chem., Int. Ed. 2012, 51, 7459 10.1002/anie.201201463
18. 12 anode of a lithium-ion battery J. Am. Chem. Soc. 2012, 134, 7874 10.1021/ja301266w
19. 12-C Nanotube Arrays as High-Rate and Long-Life Anode Materials for Flexible Li-Ion Batteries Nano Lett. 2014, 14, 2597 10.1021/nl5004174
20. 12 nanowire arrays for high rate lithium ion batteries Adv. Mater. 2012, 24, 6502 10.1002/adma.201203151
21. 12 hollow spheres with enhanced lithium storage capability Adv. Mater. 2013, 25, 2296 10.1002/adma.201204912
22. 12 coated with N-doped carbon from ionic liquids for Li-ion batteries Adv. Mater. 2011, 23, 1385 10.1002/adma.201003294
23. Amine, K.; Belharouak, I.; Chen, Z.; Tran, T.; Yumoto, H.; Ota, N.; Myung, S. T.; Sun, Y. K. Nanostructured anode material for high-power battery system in electric vehicles Adv. Mater. 2010, 22, 3052 10.1002/adma.201000441
24. 12/C composite with super rate performance Energy Environ. Sci. 2012, 5, 9595 10.1039/c2ee22591c
25. 12 Li-ion battery electrodes combining high rates with high energy density Electrochem. Commun. 2013, 35, 124 10.1016/j.elecom.2013.08.014
26. 4 Electrodes for High Performance Li-Ion Batteries Adv. Energy Mater. 2013, 3, 572 10.1002/aenm.201200704
27. 4 Composite Electrodes J. Electrochem. Soc. 2010, 157, A1347 10.1149/1.3497353
28. Chen, D.; Cao, L.; Huang, F.; Imperia, P.; Cheng, Y.-B.; Caruso, R. A. Synthesis of Monodisperse Mesoporous Titania Beads with Controllable Diameter, High Surface Areas, and Variable Pore Diameters (14-23 nm) J. Am. Chem. Soc. 2010, 132, 4438 10.1021/ja100040p
29. Monnier, A.; Schüth, F.; Huo, Q.; Kumar, D.; Margolese, D.; Maxwell, R. S.; Stucky, G. D.; Krishnamurty, M.; Petroff, P.; Firouzi, A.; Janicke, M.; Chmelka, B. F. Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures Science 1993, 261, 1299 10.1126/science.261.5126.1299
30. 12 electrode J. Power Sources 2012, 202, 253 10.1016/j.jpowsour.2011.11.037
31. 12 and their low-temperature electrochemical performance J. Power Sources 2010, 195, 4997 10.1016/j.jpowsour.2010.02.020
32. Aurbach, D.; Daroux, M. L.; Faguy, P. W.; Yeager, E. Identification of Surface Films Formed on Lithium in Propylene Carbonate Solutions J. Electrochem. Soc. 1987, 134, 1611 10.1149/1.2100722
33. Han, C.; He, Y.-B.; Li, B.; Li, H.; Ma, J.; Du, H.; Qin, X.; Yang, Q.-H.; Kang, F. Highly Crystalline Lithium Titanium Oxide Sheets Coated with Nitrogen-Doped Carbon enable High-Rate Lithium-Ion Batteries ChemSusChem 2014, 7, 2567 10.1002/cssc.201402305
34. 12-based batteries and its remedy Sci. Rep. 2012, 2, Article no. 913 10.1038/srep00913
35. 12 anode material at high current rates J. Mater. Chem. 2012, 22, 19054 10.1039/c2jm34523d
36. Noda, A.; Hayamizu, K.; Watanabe, M. Pulsed-Gradient Spin-Echo 1H and 19F NMR Ionic Diffusion Coefficient, Viscosity, and Ionic Conductivity of Non-Chloroaluminate Room-Temperature Ionic Liquids J. Phys. Chem. B 2001, 105, 4603 10.1021/jp004132q
37. 12-A comparison of results from solid state NMR and impedance spectroscopy Phys. Chem. Chem. Phys. 2007, 9, 1239 10.1039/b616269j
38. 12 (0 ≤ x ≤ 3) measured by Li-7 solid state NMR. Phys. Chem. Chem. Phys. 2007, 9, 6199.
39. 12 J. Phys. Chem. B 2009, 113, 224 10.1021/jp8073706
40. 12 Battery Electrodes Adv. Funct. Mater. 2013, 23, 1214 10.1002/adfm.201201684
41. 2: A Nanocomposite Anode Material for Li-Ion Batteries Adv. Energy Mater. 2011, 1, 212 10.1002/aenm.201000051
42. 12 at the Early Stages of Chemical Li Insertion Chem. Mater. 2015, 27, 1740 10.1021/cm504564k
43. 12 need carbon in lithium ion batteries? Carbon-free electrode with exceptionally high electrode capacity Chem. Commun. 2012, 48, 516 10.1039/C1CC16462G
44. Li, Y.; El Gabaly, F.; Ferguson, T. R.; Smith, R. B.; Bartelt, N. C.; Sugar, J. D.; Fenton, K. R.; Cogswell, D. A.; Kilcoyne, A. L. D.; Tyliszczak, T.; Bazant, M. Z.; Chueh, W. C. Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes Nat. Mater. 2014, 13, 1149 10.1038/nmat4084