Li-ion diffusion in the equilibrium nanomorphology of spinel Li 4+xTi5O12

Journal of Physical Chemistry B

Volumn 113, Issue 1, 2009, Pages 224-230

  Wagemaker, Marnix ^a   Van Eck, Ernst R H ^b   Kentgens, Arno P M ^b   Mulder, Fokko M ^a  

^a Faculty of Applied Sciences   (Netherlands)

^b RADBOUD UNIVERSITY NIJMEGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ANODES; CRYSTALLIZATION; ELECTROCHEMICAL ELECTRODES; EMPLOYMENT; IONS; LITHIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLID SOLUTIONS; SOLIDIFICATION;

ATOMIC LEVELS; CYCLEABILITY; DEBYE LENGTHS; DOMAIN BOUNDARIES; DOMAIN SIZES; FLAT VOLTAGES; FUNDAMENTAL PROPERTIES; HIGH-POWER; HIGH-RATE CAPABILITIES; ION DIFFUSIONS; ION ELECTRODES; ION MOBILITIES; LATTICE PARAMETERS; LI- ION BATTERIES; LITHIATION; NANO MORPHOLOGIES; NMR SPECTROSCOPIES; SPINEL MATERIALS; STATE-OF-THE ARTS; STRAIN PROPERTIES; TWO-PHASE REACTIONS;

LITHIUM BATTERIES;

EID: 61949286934     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp8073706     Document Type: Article

References (28)

1. Deschanv, A.; Raveau, B.; Sekkal, Z. Synthesis and Crystallographic Study of New Solid Solution of Spinelle Lil+Xti2-Xo4 Less Than or Equal to X Less Than or Equal to 0,333. Mater. Res. Bull. 1971, 6 (8), 699-704.
2. Johnston, D. C. Superconducting and Normal State Properties of Lil+Chi Ti2-Chi O4 Spinel Compounds 0.1. Preparation, Crystallography, Superconducting Properties, Electrical-Resistivity, Dielectric Behavior, and Magnetic-Susceptibility. J. Low Temp. Phys. 1976, 25 (1-2), 145-175.
3. Colbow, K. M.; Dahn, J. R.; Haering, R. R. Structure and Electrochemistry of the Spinel Oxides Liti2o4 and Li4/3ti5/3o4. J. Power Sources 1989, 26 (3-4), 397-402.
4. Ferg, E.; Gummow, R. J.; Dekock, A.; Thackeray, M. M. Spinal Anodes for Lithium-Ion Batteries. J. Electrochem. Soc. 1994, 141 (11), L147-L150.
5. Ohzuku, T.; Ueda, A.; Yamamoto, N. Zero-Strain Insertion Material of Li[Li1/3ti5/3]O-4 for Rechargeable Lithium Cells. J. Electrochem. Soc. 1995, 142 (5), 1431-1435.
6. Amatucci, G. G.; Badway, F.; Du Pasquier, A.; Zheng, T. An asymmetric hybrid nonaqueous energy storage cell. J. Electrochem. Soc. 2001, 148 (8), A930-A939.
7. Kavan, L.; Gratzel, M. Facile synthesis of nanocrystalline Li4Ti5O12 (spinel) exhibiting fast Li insertion. Electrochem. Solid State Lett. 2002, 5 (2), A39-A42.
8. Scharner, S.; Weppner, W.; Schmid-Beurmann, P. Evidence of two-phase formation upon lithium insertion into the Li1.33Ti1.67O4 spinel. J. Electrochem. Soc. 1999, 146 (3), 857-861.
9. Cava, R. J.; Murphy, D. W.; Zahurak, S.; Santoro, A.; Roth, R. S. The Crystal-Structures of the Lithium-Inserted Metal-Oxides Li0.5tio2 Anatase, Liti2o4 Spinel, and Li2ti2o4. J. Solid State Chem. 1984, 53 (1), 64-75.
10. Verhoeven, V. W. J.; de Schepper, I. M.; Nachtegaal, G.; Kentgens, A. P. M.; Kelder, E. M.; Schoonman, J.; Mulder, F. M. Lithium dynamics in LiMn2O4 probed directly by two-dimensional Li-7 NMR. Phys. Rev. Lett. 2001, 86 (19), 4314-4317.
11. Murphy, D. W.; Cava, R. J.; Zahurak, S. M.; Santoro, A. Ternary Lixtio2 Phases from Insertion Reactions. Solid State Ionics 1983, 9-10, 413-417.
12. Wagemaker, M.; Simon, D. R.; Kelder, E. M.; Schoonman, J.; Ringpfeil, C.; Haake, U.; Lützenkirchen-Hecht, D.; Frahm, R.; Mulder, F. M. A Kinetic Two-Phase and Equilibrium Solid Solution in Spinel Li4+xTi5O12. Adv. Mater. 2006, 18 (23), 3169-3173.
13. Whittingham, M. S.; Dines, M. B. Normal-Butyllithium - Effective, General Cathode Screening Agent. J. Electrochem. Soc. 1977, 124 (9), 1387-1388.
14. Ernst, M.; Kentgens, A. P. M.; Meier, B. H. 2D exchange NMR spectra under slow MAS: A simplified scheme to obtain pure-phase spectra without unwanted cross peaks. J. Magn. Resort. 1999, 138 (1), 66-73.
15. Kartha, J. P.; Tunstall, D. P.; Irvine, J. T. S. An NMR investigation of lithium occupancy of different sites in the oxide superconductor LiTi2O4 and related compounds. J. Solid State Chem. 2000, 152 (2), 397-402.
16. Dalton, M.; Tunstall, D. P.; Todd, J.; Arumugam, S.; Edwards, P. P. A Li-7 Nmr-Study of the Superconducting Spinel Li1+Xti2-Xo4. J. Phys.: Condens. Matter 1994, 6 (42), 8859-8870.
17. Wilkening, M.; Amade, R.; Iwaniak, W.; Heitjans, P. Ultraslow Li diffusion in spinel-type structured Li4Ti5O12 - A comparison of results from solid state NMR and impedance spectroscopy. Phys. Chem. Chem. Phys. 2007, 9 (10), 1239-1246.
18. Vleck, J. H. V. Phys. Rev. 1948, 74, 1168.
19. Koller, H.; Engelhardt, G.; Kentgens, A. P. M.; Sauer, J. Na-23 Nmr-Spectroscopy of Solids - Interpretation of Quadrupole Interaction Parameters and Chemical-Shifts. J. Phys. Chem. 1994, 98 (6), 1544-1551.
20. Schmidt-Rohr, K. S.; Spiess, K. Multidimensional Solid-State NMR and Polymers. Academic Press: London, 1994.
21. Xu, Z.; Stebbins, J. F. Cation Dynamics and Diffusion in Lithium Orthosilicate - 2-Dimensional Li-6 Nmr. Science 1995, 270 (5240), 1332-1334.
22. Wagemaker, M.; Kentgens, A. P. M.; Mulder, F. M. Equilibrium lithium transport between nanocrystalline phases in intercalated TiO2 anatase. Nature 2002, 418 (6896), 397-399.
23. Kavan, L.; Prochazka, J.; Spitler, T. M.; Kalbac, M.; Zukalova, M. T.; Drezen, T.; Gratzel, M. Li insertion into Li4Ti5O12 p(Spinel) - Charge capability vs. particle size in thin-film electrodes. J. Electrochem. Soc. 2003, 150 (7), A1000-A1007.
24. Wagemaker, M.; Van Der Ven, A.; Morgan, D.; Ceder, G.; Mulder, F. M.; Kearley, G. J. Thermodynamics of spinel LixTiO2 from first principles. Chem. Phys. 2005, 317 (2-3), 130-136.
25. Bloembergen, N.; Purcell, E. M.; Pound, R. V. Relaxation Effects in Nuclear Magnetic Resonance Absorption. Phys. Rev. 1948, 73 (7), 679-712.
26. Wagemaker, M.; van de Krol, R.; Kentgens, A. P. M.; van Well, A. A.; Mulder, F. M. Two phase morphology limits lithium diffusion in TiO2 (anatase): A Li-7 MAS NMR study. J. Am. Chem. Soc. 2001, 123 (46), 11454-11461.
27. Ernst, R. R.; Bodenhausen, G.; Wokaun, A. Principles of nuclear magnetic resonance in one and two dimensions. Clarendon Press: Oxford, 1994.
28. Maier, J. Ionic-Conduction in-Space Charge Regions. Prog. Solid State Chem. 1995, 23 (3), 171-263.