A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior

Journal of the American Chemical Society

Volumn 137, Issue 31, 2015, Pages 9792-9795

  Novikov, Valentin V ^a   Pavlov, Alexander A ^a   Nelyubina, Yulia V ^a   Boulon, Marie Emmanuelle ^b   Varzatskii, Oleg A ^c   Voloshin, Yan Z ^a   Winpenny, Richard E P ^b  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

^c INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Ukraine)

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY; COBALT; COORDINATION REACTIONS; GROUND STATE; MAGNETIC ANISOTROPY; MAGNETS; METAL IONS; METALS; MOLECULES; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

COBALT COMPLEXES; FUNCTIONALIZATIONS; MACRO-CYCLIC LIGANDS; MAGNET BEHAVIOR; MOLECULAR SPECIES; PRISMATIC COORDINATION; SINGLE-MOLECULE MAGNET; TRIGONAL PRISMS;

COBALT COMPOUNDS;

COBALT DERIVATIVE; COORDINATION COMPOUND; MACROCYCLIC COMPOUND; SINGLE MOLECULE MAGNET; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; GEOMETRY; MAGNETIC ANISOTROPY; MAGNETISM; MOLECULE; PHYSICAL PARAMETERS; REACTION TIME; TEMPERATURE DEPENDENCE;

EID: 84939239452     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b05739     Document Type: Article

References (42)

1. Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141 10.1038/365141a0
2. Gatteschi, D.; Sessoli, R.; Villain, J. Molecular Nanomagnets; Oxford University Press: Oxford, U.K., 2006.
3. Mannini, M.; Pineider, F.; Sainctavit, P.; Danieli, C.; Otero, E.; Sciancalepore, C.; Talarico, A. M.; Arrio, M.-A.; Cornia, A.; Gatteschi, D. Nat. Mater. 2009, 8, 194 10.1038/nmat2374
4. Winpenny, R. E. Angew. Chem., Int. Ed. 2008, 47, 7992 10.1002/anie.200802742
5. Bogani, L.; Wernsdorfer, W. Nat. Mater. 2008, 7, 179 10.1038/nmat2133
6. Karotsis, G.; Kennedy, S.; Teat, S. J.; Beavers, C. M.; Fowler, D. A.; Morales, J. J.; Evangelisti, M.; Dalgarno, S. J.; Brechin, E. K. J. Am. Chem. Soc. 2010, 132, 12983 10.1021/ja104848m
7. Peng, J.-B.; Zhang, Q.-C.; Kong, X.-J.; Zheng, Y.-Z.; Ren, Y.-P.; Long, L.-S.; Huang, R.-B.; Zheng, L.-S.; Zheng, Z. J. Am. Chem. Soc. 2012, 134, 3314 10.1021/ja209752z
8. Sessoli, R.; Powell, A. K. Coord. Chem. Rev. 2009, 253, 2328 10.1016/j.ccr.2008.12.014
9. Ishikawa, N.; Sugita, M.; Ishikawa, T.; Koshihara, S.-y.; Kaizu, Y. J. Am. Chem. Soc. 2003, 125, 8694 10.1021/ja029629n
10. Meihaus, K. R.; Long, J. R. Dalton Trans. 2015, 44, 2517 10.1039/C4DT02391A
11. Freedman, D. E.; Harman, W. H.; Harris, T. D.; Long, G. J.; Chang, C. J.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 1224 10.1021/ja909560d
12. Harman, W. H.; Harris, T. D.; Freedman, D. E.; Fong, H.; Chang, A.; Rinehart, J. D.; Ozarowski, A.; Sougrati, M. T.; Grandjean, F.; Long, G. J. J. Am. Chem. Soc. 2010, 132, 18115 10.1021/ja105291x
13. Craig, G. A.; Murrie, M. Chem. Soc. Rev. 2015, 44, 2135 10.1039/C4CS00439F
14. Layfield, R. A. Organometallics 2014, 33, 1084 10.1021/om401107f
15. Woodruff, D. N.; Winpenny, R. E.; Layfield, R. A. Chem. Rev. 2013, 113, 5110 10.1021/cr400018q
16. Feltham, H. L.; Brooker, S. Coord. Chem. Rev. 2014, 276, 1 10.1016/j.ccr.2014.05.011
17. Ako, A. M.; Hewitt, I. J.; Mereacre, V.; Clérac, R.; Wernsdorfer, W.; Anson, C. E.; Powell, A. K. Angew. Chem. 2006, 118, 5048 10.1002/ange.200601467
18. Neese, F.; Pantazis, D. A. Faraday Discuss. 2011, 148, 229 10.1039/C005256F
19. Palii, A.; Clemente-Juan, J.; Coronado, E.; Klokishner, S.; Ostrovsky, S.; Reu, O. Inorg. Chem. 2010, 49, 8073 10.1021/ic1011296
20. Gomez-Coca, S.; Cremades, E.; Aliaga-Alcalde, N.; Ruiz, E. J. Am. Chem. Soc. 2013, 135, 7010 10.1021/ja4015138
21. Zadrozny, J. M.; Xiao, D. J.; Atanasov, M.; Long, G. J.; Grandjean, F.; Neese, F.; Long, J. R. Nat. Chem. 2013, 5, 577 10.1038/nchem.1630
22. Zadrozny, J. M.; Atanasov, M.; Bryan, A. M.; Lin, C. Y.; Rekken, B. D.; Power, P. P.; Neese, F.; Long, J. R. Chem. Sci. 2013, 4, 125 10.1039/C2SC20801F
23. Atanasov, M.; Zadrozny, J. M.; Long, J. R.; Neese, F. Chem. Sci. 2013, 4, 139 10.1039/C2SC21394J
24. Gatteschi, D.; Sessoli, R. Angew. Chem., Int. Ed. 2003, 42, 268 10.1002/anie.200390099
25. Zhu, Y.-Y.; Cui, C.; Zhang, Y.-Q.; Jia, J.-H.; Guo, X.; Gao, C.; Qian, K.; Jiang, S.-D.; Wang, B.-W.; Wang, Z.-M. Chem. Sci. 2013, 4, 1802 10.1039/c3sc21893g
26. Novikov, V. V.; Pavlov, A. A.; Belov, A. S.; Vologzhanina, A. V.; Savitsky, A.; Voloshin, Y. Z. J. Phys. Chem. Lett. 2014, 5, 3799 10.1021/jz502011z
27. Novikov, V. V.; Ananyev, I. V.; Pavlov, A. A.; Fedin, M. V.; Lyssenko, K. A.; Voloshin, Y. Z. J. Phys. Chem. Lett. 2014, 5, 496 10.1021/jz402678q
28. Voloshin, Y. Z.; Varzatskii, O. A.; Vorontsov, I. I.; Antipin, M. Y. Angew. Chem., Int. Ed. 2005, 44, 3400 10.1002/anie.200463070
29. Varzatskii, O. A.; Penkova, L. V.; Kats, S. V.; Dolganov, A. V.; Vologzhanina, A. V.; Pavlov, A. A.; Novikov, V. V.; Bogomyakov, A. S.; Nemykin, V. N.; Voloshin, Y. Z. Inorg. Chem. 2014, 53, 3062 10.1021/ic4029047
30. Damjanovic, M.; Katoh, K.; Yamashita, M.; Enders, M. J. Am. Chem. Soc. 2013, 135, 14349 10.1021/ja4069485
31. Chilton, N. F.; Anderson, R. P.; Turner, L. D.; Soncini, A.; Murray, K. S. J. Comput. Chem. 2013, 34, 1164 10.1002/jcc.23234
32. Kahn, O. Molecular magnetism; Wiley-VCH, Inc.: New York, 1993.
33. McGarvey, B. R.; Telser, J. Inorg. Chem. 2012, 51, 6000 10.1021/ic201189a
34. Neese, F. Wiley Interdisciplinary Reviews: Computational Molecular Science 2012, 2, 73 10.1002/wcms.81
35. Atanasov, M.; Ganyushin, D.; Pantazis, D. A.; Sivalingam, K.; Neese, F. Inorg. Chem. 2011, 50, 7460 10.1021/ic200196k
36. Abragam, A.; Bleaney, B. Electron paramagnetic resonance of transition ions; Oxford University Press: Oxford, U.K., 2012.
37. Ruamps, R.; Maurice, R.; Batchelor, L.; Boggio-Pasqua, M.; Guillot, R.; Barra, A. L.; Liu, J.; Bendeif, E.; Pillet, S.; Hill, S. J. Am. Chem. Soc. 2013, 135, 3017 10.1021/ja308146e
38. Gómez-Coca, S.; Urtizberea, A.; Cremades, E.; Alonso, P. J.; Camón, A.; Ruiz, E.; Luis, F. Nat. Commun. 2014, 5, 4300 10.1038/ncomms5300
39. Cole, K. S.; Cole, R. H. J. Chem. Phys. 1941, 9, 341 10.1063/1.1750906
40. Shrivastava, K. Phys. Status Solidi B 1983, 117, 437 10.1002/pssb.2221170202
41. Colacio, E.; Ruiz, J.; Ruiz, E.; Cremades, E.; Krzystek, J.; Carretta, S.; Cano, J.; Guidi, T.; Wernsdorfer, W.; Brechin, E. K. Angew. Chem., Int. Ed. 2013, 52, 9130 10.1002/anie.201304386
42. Singh, A.; Shrivastava, K. Phys. Status Solidi B 1979, 95, 273 10.1002/pssb.2220950131