Spin-crossover anticooperativity induced by weak intermolecular interactions

Journal of Physical Chemistry Letters

Volumn 5, Issue 3, 2014, Pages 496-500

  Novikov, Valentin V ^a   Ananyev, Ivan V ^a   Pavlov, Alexander A ^a   Fedin, Matvey V ^b   Lyssenko, Konstantin A ^a   Voloshin, Yan Z ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b INTERNATIONAL TOMOGRAPHY CENTER   (Russian Federation)

Author keywords

clathrochelates; cobalt(II); cooperativity; macrocyclic compounds; molecular switches; spin crossover

Indexed keywords

CLATHROCHELATES; COOPERATIVITY; MACROCYCLIC COMPOUNDS; MOLECULAR SWITCHES; SPIN CROSSOVERS;

CHEMICAL ANALYSIS; COBALT; HYDROPHOBICITY;

COBALT COMPOUNDS;

EID: 84893818646     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz402678q     Document Type: Article

References (33)

1. Sato, O.; Tao, J.; Zhang, Y. Z. Control of Magnetic Properties Through External Stimuli Angew. Chem., Int. Ed. 2007, 46, 2152-2187 (Pubitemid 46973610)
2. Gütlich, P.; Garcia, Y.; Goodwin, H. A. Spin Crossover Phenomena in Fe(II) Complexes Chem. Soc. Rev. 2000, 29, 419-427
3. Miyamachi, T.; Gruber, M.; Davesne, V.; Bowen, M.; Boukari, S.; Joly, L.; Scheurer, F.; Rogez, G.; Yamada, T. K.; Ohresser, P.; Beaurepaire, E. Robust Spin Crossover and Memristance Across a Single Molecule. Nat. Commun. 2012, 3.
4. Halder, G. J.; Kepert, C. J.; Moubaraki, B.; Murray, K. S.; Cashion, J. D. Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material Science 2002, 298, 1762-1765 (Pubitemid 35404114)
5. Cavallini, M.; Bergenti, I.; Milita, S.; Ruani, G.; Salitros, I.; Qu, Z. R.; Chandrasekar, R.; Ruben, M. Micro- and Nanopatterning of Spin-Transition Compounds into Logical Structures Angew. Chem., Int. Ed. 2008, 47, 8596-8600
6. Gütlich, P.; Goodwin, H. A. Spin Crossover in Transition Metal Compounds I-III; Springer: New York, 2004; Vols. 233-235.
7. Kahn, O.; Martinez, C. J. Spin-transition Polymers: From Molecular Materials Toward Memory Devices Science 1998, 279, 44-48 (Pubitemid 28079148)
8. Bao, X.; Leng, J. D.; Meng, Z. S.; Lin, Z.; Tong, M. L.; Nihei, M.; Oshio, H. Tuning the Spin States of Two Apical Iron(Ii) Ions in the Trigonal-bipyramidal [{Fe(II)(mu-bpt)3}2Fe(II)3(mu3-O)]2+ Cations through the Choice of Anions Chem.-Eur. J. 2010, 16, 6169-74
9. Gutlich, P.; Hauser, A.; Spiering, H. Thermal and Optical Switching of Iron(II) Complexes Angew. Chem., Int. Ed. Engl. 1994, 33, 2024-2054 (Pubitemid 24987674)
10. Spiering, H.; Meissner, E.; Koppen, H.; Muller, E. W.; Gutlich, P. The Effect of the Lattice Expansion on High-Spin Reversible Low-Spin Transitions Chem. Phys. 1982, 68, 65-71
11. Sinitskiy, A. V.; Tchougreeff, A. L.; Dronskowski, R. Phenomenological Model of Spin Crossover in Molecular Crystals as Derived from Atom-Atom Potentials Phys. Chem. Chem. Phys. 2011, 13, 13238-13246
12. Halcrow, M. A. Structure:Function Relationships in Molecular Spin-Crossover Complexes Chem. Soc. Rev. 2011, 40, 4119-4142
13. Real, J. A.; Gaspar, A. B.; Niel, V.; Munoz, M. C. Communication Between Iron(II) Building Blocks in Cooperative Spin Transition Phenomena Coord. Chem. Rev. 2003, 236, 121-141
14. Weber, B.; Bauer, W.; Pfaffeneder, T.; Dirtu, M. M.; Naik, A. D.; Rotaru, A.; Garcia, Y. Influence of Hydrogen Bonding on the Hysteresis Width in Iron(II) Spin-Crossover Complexes Eur. J. Inorg. Chem. 2011, 3193-3206
15. Reger, D. L.; Gardinier, J. R.; Smith, M. D.; Shahin, A. M.; Long, G. J.; Rebbouh, L.; Grandjean, F. Polymorphism in Fe[(p-IC6H4)B(3-Mepz)(3)](2) (pz = pyrazolyl): Impact of Supramolecular Structure on an Iron(II) Electronic Spin-State Crossover Inorg. Chem. 2005, 44, 1852-1866 (Pubitemid 40431478)
16. Yamada, M.; Ooidemizu, M.; Ikuta, Y.; Osa, S.; Matsumoto, N.; Iijima, S.; Kojima, M.; Dahan, F.; Tuchagues, J. P. Interlayer Interaction of Two-Dimensional Layered Spin Crossover Complexes [(FeH3)-H-II L-Me] [(FeLMe)-L-II]X (X- = CIO4-, BF4-, PF6-, AsF6-, and SbF6-; H3LMe = tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine Inorg. Chem. 2003, 42, 8406-8416
17. Voloshin, Y. Z.; Varzatskii, O. A.; Vorontsov, I. I.; Antipin, M. Y. Tuning a Metal's Oxidation State: The Potential of Clathrochelate Systems Angew. Chem., Int. Ed. 2005, 44, 3400-3402 (Pubitemid 40793593)
18. Voloshin, Y. Z.; Varzatskii, O. A.; Novikov, V. V.; Strizhakova, N. G.; Vorontsov, I. I.; Vologzhanina, A. V.; Lyssenko, K. A.; Romanenko, G. V.; Fedin, M. V.; Ovcharenko, V. I. Tris-Dioximate Cobalt(I,II,III) Clathrochelates: Stabilization of Different Oxidation and Spin States of an Encapsulated Metal Ion by Ribbed Functionalization Eur. J. Inorg. Chem. 2010, 5401-5415
19. Krivokapic, I.; Zerara, M.; Daku, M. L.; Vargas, A.; Enachescu, C.; Ambrus, C.; Tregenna-Piggott, P.; Amstutz, N.; Krausz, E.; Hauser, A. Spin-Crossover in Cobalt(II) Imine Complexes Coord. Chem. Rev. 2007, 251, 364-378
20. Evans, D. F. The Determination of the Paramagnetic Susceptibility of Substances in Solution by Nuclear Magnetic Resonance J. Chem. Soc. 1959, 2003-2005
21. Haddad, M. S.; Federer, W. D.; Lynch, M. W.; Hendrickson, D. N. Spin-Crossover Ferric Complexes: Unusual Effects of Grinding and Doping Solids J. Am. Chem. Soc. 1981, 131-139
22. Echeverría, J.; Cremades, E.; Amoroso, A. J.; Alvarez, S. Jahn-Teller Distortions of Six-Coordinate CuII Compounds: Cis or Trans? Chem. Commun. 2009, 4242-4
23. Cremades, E.; Echeverría, J.; Alvarez, S. The Trigonal Prism in Coordination Chemistry Chem.-Eur. J. 2010, 16, 10380-10396
24. Scott, H. S.; Ross, T. M.; Chilton, N. F.; Gass, I. A.; Moubaraki, B.; Chastanet, G.; Paradis, N.; Letard, J. F.; Vignesh, K. R.; Rajaraman, G.; Battena, S. R.; Murray, K. S. Crown-Linked Dipyridylamino-Triazine Ligands and Their Spin-Crossover Iron(II) Derivatives: Magnetism, Photomagnetism and Cooperativity Dalton Trans. 2013, 42, 16494-16509
25. Real, J. A.; Bolvin, H.; Bousseksou, A.; Dworkin, A.; Kahn, O.; Varret, F.; Zarembowitch, J. 2-Step Spin Crossover in the New Dinuclear Compound [Fe(Bt)(Ncs)2]2bpym, with Bt = 2,21′-Bi-2-Thiazoline and Bpym = 2,2′-Bipyrimidine-Experimental Investigation and Theoretical Approach J. Am. Chem. Soc. 1992, 114, 4650-4658
26. Bolvin, H.; Kahn, O. Cooperativity and Anticooperativity in Spin Transition Compounds-Macroscopic Approach and Orbital Modelization Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 1993, 234, 275-282
27. Jenkins, D. M.; Peters, J. C. Spin-State Tuning at Pseudotetrahedral d(7) Ions: Examining the Structural and Magnetic Phenomena of Four-Coordinate [BP3]CoII-X Systems J. Am. Chem. Soc. 2005, 127, 7148-65 (Pubitemid 40676741)
28. Toftlund, H. Spin Equilibrium in Solutions Monatsh. Chem. 2001, 132, 1269-1277
29. Belov, A. S.; Dolganov, A. V.; Novikov, V. V.; Vologzhanina, A. V.; Fedin, M. V.; Kuznetsov, E. V.; Bubnov, Y. N.; Voloshin, Y. Z. Template Synthesis, Structure and Electropolymerization of the 2-Thiopheneboron-Capped Cobalt(II) Clathrochelates Inorg. Chem. Commun. 2013, 29, 160-164
30. Reinen, D.; Atanasov, M. The Influence of Jahn-Teller Coupling on the High-Spin/Low-Spin Equilibria of Octahedral MIIIL6 Polyhedra (MIII: Mn-Cu), with NiF6 3- as the Model Example. In The Jahn-Teller Effect; Köppel, H.; Yarkony, D. R.; Barentzen, H., Eds.; Springer: Berlin Heidelberg, 2009; Vol. 97, pp 451-486.
31. Kundu, T. K.; Manoharan, P. T. An Electron Paramagnetic Resonance Investigation of a Macrobicyclic Cage Complex of Ag(II). Dynamic and Static Jahn-Teller Distortions Chem. Phys. Lett. 1997, 264, 338-344 (Pubitemid 127168651)
32. Nielsen, P.; Toftlund, H.; Bond, A. D.; Boas, J. F.; Pilbrow, J. R.; Hanson, G. R.; Noble, C.; Riley, M. J.; Neville, S. M.; Moubaraki, B.; Murray, K. S. Systematic Study of Spin Crossover and Structure in [Co(terpyRX)(2)](Y)(2) Systems (terpyRX=4′-alkoxy-2,2′:6′,2″-terpyridine, X=4, 8, 12, Y = BF4-, ClO4-, PF6-, BPh4-) Inorg. Chem. 2009, 48, 7033-7047
33. Reinen, D.; Atanasov, M.; Kohler, P.; Babel, D. Jahn-Teller Coupling and the Influence of Strain in T-g and E-g Ground and Excited States-a Ligand Field and DFT Study on Halide (MX6)-X-III Model Complexes [M = Ti-III-Cu-III, X = F-, Cl-] Coord. Chem. Rev. 2010, 254, 2703-2754