Hydrogenation of CO2 to methanol and CO on Cu/ZnO/Al2O3: Is there a common intermediate or not? This work is dedicated to the memory and achievements of Dr. Haldor Topsøe.

Journal of Catalysis

Volumn 328, Issue , 2015, Pages 43-48

  Kunkes, Edward L ^a   Studt, Felix ^b,e   Abild Pedersen, Frank ^b,e   Schlögl, Robert ^a,c   Behrens, Malte ^a,d  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^c MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^d UNIVERSITY OF DUISBURG ESSEN   (Germany)

^e Stanford University   (United States)

Author keywords

CO2 hydrogenation; Copper; DFT; H D substitution; Kinetics; Mechanism; Methanol; Reverse water gas shift

Indexed keywords

ALUMINUM COMPOUNDS; CARBON DIOXIDE; CARRIER MOBILITY; CATALYSTS; CHEMICAL SHIFT; COPPER; COPPER COMPOUNDS; DESIGN FOR TESTABILITY; DEUTERIUM; ENZYME KINETICS; HYDROGENATION; KINETICS; MECHANISMS; METHANOL; PALLADIUM COMPOUNDS; REACTION INTERMEDIATES; SILICON COMPOUNDS; SURFACE REACTIONS; SYNTHESIS GAS MANUFACTURE; ZINC COMPOUNDS;

CO2 HYDROGENATION; CU/ZNO/AL2O3 CATALYSTS; INVERSE KINETIC ISOTOPE EFFECTS; KINETIC ISOTOPE EFFECTS; METHANOL FORMATIONS; RATE DETERMINING STEP; REVERSE WATER GAS SHIFT; ZERO-POINT ENERGIES;

WATER GAS SHIFT;

EID: 84937901885     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2014.12.016     Document Type: Article

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