Fischer-tropsch synthesis: Investigation of the partitioning of dissociated H2 and D2 on activated cobalt catalysts

ACS Catalysis

Volumn 2, Issue 7, 2012, Pages 1452-1456

  Shafer, Wilson D ^a   Jacobs, Gary ^a   Davis, Burtron H ^a  

^a UNIVERSITY OF KENTUCKY   (United States)

Author keywords

cobalt catalyst; Fischer Tropsch synthesis; H D isotope effect; inverse kinetic isotope effect

Indexed keywords

CO HYDROGENATION; COBALT CATALYST; FISCHER-TROPSCH SYNTHESIS CATALYSTS; HYDROGEN-DEUTERIUM EXCHANGE; ISOTOPE EFFECT; ISOTOPIC EFFECTS; KINETIC ISOTOPE EFFECTS; KINETIC ISOTOPIC EFFECTS; METAL SURFACES; RATE DETERMINING STEP;

ADSORPTION; CARRIER MOBILITY; CATALYSTS; COBALT; DEUTERIUM; EXPERIMENTS; GAS CHROMATOGRAPHY; HYDROGEN; HYDROGENATION; TEMPERATURE PROGRAMMED DESORPTION;

FISCHER-TROPSCH SYNTHESIS;

EID: 84863624921     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs300269m     Document Type: Article

References (17)

1. Fischer, F.; Tropsch, H. Brennst. Chem. 1923, 4, 276-285
2. Zhang, X.-G.; Xu, Y.-S.; Guo, X. X. J. Mol. Catal. 1988, 43, 381-394
3. Zhou, M.; Tan, K. F.; Borgna, A.; Saeys, M. J. Phys. Chem. C 2009, 113, 8357-8365
4. Dry, M. E. Catal. Today 1990, 6, 183-206
5. Winslow, P.; Bell, A. T. J. Catal. 1985, 91, 142-154
6. Bell, A. T.; Kellner, C. S. J. Catal. 1981, 67, 175-185
7. Ojeda, M.; Li, A.-W.; Nabar, R.; Nilekar, A. U.; Mavrikakis, M.; Iglesia, E. J. Phys. Chem. C 2010, 114, 19761-19770
8. Zheng, S.; Liu, Y.; Li, J.; Shi, B. Appl. Catal., A 2007, 330, 63-68
9. Shi, B.; Davis, B. H. Appl. Catal., A 2004, 277, 61-69
10. Espinoza, R. L.; Visagie, J. L.; van Berge, P. J.; Bolder, F. H. US Patent 5,733,839, 1998.
11. Sietsma, J. R. A.; van Dillen, A. J.; de Jongh, P. E.; de Jong, K. P.; PCT Int Appl WO 2008029177 (2008).
12. Sietsma, J. R. A.; van Dillen, A. J.; de Jongh, P. E.; de Jong, K. P.; PCT Int Appl WO 2007071899 2007.
13. Sietsma, J. R. A.; Meeldijk, J. D.; den Breejen, J. P.; Versluijs-Helder, M.; Jos van Dillen, A.; de Jongh, P. E.; de Jong, K. P. Angew. Chem., Int. Ed. 2007, 46, 4547-4549
14. Cronauer, D. C.; Jacobs, G.; Linganiso, L.; Kropf, A. J.; Elam, J. W.; Christensen, S. T.; Marshall, C. L.; Davis, B. H. Catal. Lett. 2011, 141, 968-976
15. Jacobs, G.; Ji, Y.; Davis, B. H.; Cronauer, D.; Kropf, A. J.; Marshall, C. L. Appl. Catal., A 2007, 333, 177-191
16. Jacobs, G.; Das, T. K.; Zhang, Y.; Li, J.; Racoillet, G.; Davis, B. H. Appl. Catal., A 2002, 233, 263-281
17. Prins, R. Chem. Rev. 2012, dx.doi.org/10.1021/cr200346z