ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties

Macromolecules

Volumn 48, Issue 14, 2015, Pages 4967-4973

  Bates, Christopher M ^a   Chang, Alice B ^a   Momčilović, Nebojša ^a   Jones, Simon C ^b   Grubbs, Robert H ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; DENDRIMERS; ETHYLENE; LITHIUM; POLYETHYLENE OXIDES; POLYMERS; RHEOLOGY;

BLEND RATIOS; BRUSH POLYMERS; GRAFTED POLYSTYRENE; LINEAR BLOCK COPOLYMERS; PACKED CYLINDERS; RHEOLOGICAL PROPERTY; SELF-ASSEMBLE; TRIFLUOROMETHANE;

SELF ASSEMBLY;

EID: 84937889073     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/acs.macromol.5b00880     Document Type: Article

References (37)

1. Hallinan, D. T.; Balsara, N. P. Polymer Electrolytes Annu. Rev. Mater. Res. 2013, 43 (1) 503-525
2. Schulze, M. W.; McIntosh, L. D.; Hillmyer, M. A.; Lodge, T. P. High-Modulus, High-Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation Nano Lett. 2013, 14 (1) 122-126
3. McIntosh, L. D.; Schulze, M. W.; Irwin, M. T.; Hillmyer, M. A.; Lodge, T. P. Evolution of Morphology, Modulus, and Conductivity in Polymer Electrolytes Prepared via Polymerization-Induced Phase Separation Macromolecules 2015, 48 (5) 1418-1428
4. Young, W.-S.; Kuan, W.-F.; Epps, T. H. Block copolymer electrolytes for rechargeable lithium batteries J. Polym. Sci., Part B: Polym. Phys. 2014, 52 (1) 1-16
5. Singh, M.; Odusanya, O.; Wilmes, G. M.; Eitouni, H. B.; Gomez, E. D.; Patel, A. J.; Chen, V. L.; Park, M. J.; Fragouli, P.; Iatrou, H.; Hadjichristidis, N.; Cookson, D.; Balsara, N. P. Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes Macromolecules 2007, 40 (13) 4578-4585
6. Bouchet, R.; Phan, T. N. T.; Beaudoin, E.; Devaux, D.; Davidson, P.; Bertin, D.; Denoyel, R. Charge Transport in Nanostructured PS-PEO-PS Triblock Copolymer Electrolytes Macromolecules 2014, 47 (8) 2659-2665
7. Young, N. P.; Devaux, D.; Khurana, R.; Coates, G. W.; Balsara, N. P. Investigating polypropylene-poly(ethylene oxide)-polypropylene triblock copolymers as solid polymer electrolytes for lithium batteries Solid State Ionics 2014, 263 (0) 87-94
8. Trapa, P. E.; Won, Y.-Y.; Mui, S. C.; Olivetti, E. A.; Huang, B.; Sadoway, D. R.; Mayes, A. M.; Dallek, S. Rubbery Graft Copolymer Electrolytes for Solid-State, Thin-Film Lithium Batteries J. Electrochem. Soc. 2005, 152 (1) A1-A5
9. Trapa, P. E.; Acar, M. H.; Sadoway, D. R.; Mayes, A. M. Synthesis and Characterization of Single-Ion Graft Copolymer Electrolytes J. Electrochem. Soc. 2005, 152 (12) A2281-A2284
10. Gavelin, P.; Jannasch, P.; Wesslén, B. Amphiphilic polymer gel electrolytes. I. preparation of gels based on poly(ethylene oxide) graft copolymers containing different ionophobic groups J. Polym. Sci., Part A: Polym. Chem. 2001, 39 (13) 2223-2232
11. Daigle, J.-C.; Vijh, A.; Hovington, P.; Gagnon, C.; Hamel-Pâquet, J.; Verreault, S.; Turcotte, N.; Clément, D.; Guerfi, A.; Zaghib, K. Lithium battery with solid polymer electrolyte based on comb-like copolymers J. Power Sources 2015, 279 (0) 372-383
12. Sun, J.; Stone, G. M.; Balsara, N. P.; Zuckermann, R. N. Structure-Conductivity Relationship for Peptoid-Based PEO-Mimetic Polymer Electrolytes Macromolecules 2012, 45 (12) 5151-5156
13. Niitani, T.; Shimada, M.; Kawamura, K.; Kanamura, K. Characteristics of new-type solid polymer electrolyte controlling nano-structure J. Power Sources 2005, 146 (1-2) 386-390
14. Wang, C.; Sakai, T.; Watanabe, O.; Hirahara, K.; Nakanishi, T. All Solid-State Lithium-Polymer Battery Using a Self-Cross-Linking Polymer Electrolyte J. Electrochem. Soc. 2003, 150 (9) A1166-A1170
15. Kuan, W.-F.; Remy, R.; Mackay, M. E.; Epps, T. H. Controlled ionic conductivity via tapered block polymer electrolytes RSC Adv. 2015, 5 (17) 12597-12604
16. Niitani, T.; Amaike, M.; Nakano, H.; Dokko, K.; Kanamura, K. Star-Shaped Polymer Electrolyte with Microphase Separation Structure for All-Solid-State Lithium Batteries J. Electrochem. Soc. 2009, 156 (7) A577-A583
17. Xia, Y.; Kornfield, J. A.; Grubbs, R. H. Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers Macromolecules 2009, 42 (11) 3761-3766
18. Fetters, L. J.; Lohse, D. J.; Richter, D.; Witten, T. A.; Zirkel, A. Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties Macromolecules 1994, 27 (17) 4639-47
19. Young, W.-S.; Albert, J. N. L.; Schantz, A. B.; Epps, T. H. Mixed-Salt Effects on the Ionic Conductivity of Lithium-Doped PEO-Containing Block Copolymers Macromolecules 2011, 44 (20) 8116-8123
20. Cowie, J. M. G.; Sadaghianizadeh, K. Effect of side chain length and crosslinking on the ac conductivity of oligo (ethyleneoxide) comb-branch polymer-salt mixtures Solid State Ionics 1990, 42 (3-4) 243-249
21. Zhang, Y.; Costantini, N.; Mierzwa, M.; Pakula, T.; Neugebauer, D.; Matyjaszewski, K. Super soft elastomers as ionic conductors Polymer 2004, 45 (18) 6333-6339
22. Lascaud, S.; Perrier, M.; Vallee, A.; Besner, S.; Prudhomme, J.; Armand, M. Phase Diagrams and Conductivity Behavior of Poly(ethylene oxide)-Molten Salt Rubbery Electrolytes Macromolecules 1994, 27 (25) 7469-7477
23. Heimenz, P. C.; Lodge, T. P. Polymer Chemistry, 2 nd ed.; CRC Press: Boca Raton, FL, 2007.
24. Zhao, C.; Wu, D.; Huang, N.; Zhao, H. Crystallization and thermal properties of PLLA comb polymer J. Polym. Sci., Part B: Polym. Phys. 2008, 46 (6) 589-598
25. Teran, A. A.; Balsara, N. P. Thermodynamics of Block Copolymers with and without Salt J. Phys. Chem. B 2014, 118 (1) 4-17
26. Meyer, W. H. Polymer Electrolytes for Lithium-Ion Batteries Adv. Mater. 1998, 10 (6) 439-448
27. Panday, A.; Mullin, S.; Gomez, E. D.; Wanakule, N.; Chen, V. L.; Hexemer, A.; Pople, J.; Balsara, N. P. Effect of Molecular Weight and Salt Concentration on Conductivity of Block Copolymer Electrolytes Macromolecules 2009, 42 (13) 4632-4637
28. Hu, M.; Xia, Y.; McKenna, G. B.; Kornfield, J. A.; Grubbs, R. H. Linear Rheological Response of a Series of Densely Branched Brush Polymers Macromolecules 2011, 44, 6935-6943
29. Gomez, E. D.; Panday, A.; Feng, E. H.; Chen, V.; Stone, G. M.; Minor, A. M.; Kisielowski, C.; Downing, K. H.; Borodin, O.; Smith, G. D.; Balsara, N. P. Effect of Ion Distribution on Conductivity of Block Copolymer Electrolytes Nano Lett. 2009, 9 (3) 1212-1216
30. Ganesan, V.; Pyramitsyn, V.; Bertoni, C.; Shah, M. Mechanisms Underlying Ion Transport in Lamellar Block Copolymer Membranes ACS Macro Lett. 2012, 1 (4) 513-518
31. Hou, W.-H.; Chen, C.-Y.; Wang, C.-C.; Huang, Y.-H. The effect of different lithium salts on conductivity of comb-like polymer electrolyte with chelating functional group Electrochim. Acta 2003, 48 (6) 679-690
32. Chintapalli, M.; Chen, X. C.; Thelen, J. L.; Teran, A. A.; Wang, X.; Garetz, B. A.; Balsara, N. P. Effect of Grain Size on the Ionic Conductivity of a Block Copolymer Electrolyte Macromolecules 2014, 47 (15) 5424-5431
33. Hong, S. W.; Gu, W.; Huh, J.; Sveinbjornsson, B. R.; Jeong, G.; Grubbs, R. H.; Russell, T. P. On the Self-Assembly of Brush Block Copolymers in Thin Films ACS Nano 2013, 7 (11) 9684-9692
34. Yuan, R.; Teran, A. A.; Gurevitch, I.; Mullin, S. A.; Wanakule, N. S.; Balsara, N. P. Ionic Conductivity of Low Molecular Weight Block Copolymer Electrolytes Macromolecules 2013, 46 (3) 914-921
35. Teran, A. A.; Mullin, S. A.; Hallinan, D. T.; Balsara, N. P. Discontinuous Changes in Ionic Conductivity of a Block Copolymer Electrolyte through an Order-Disorder Transition ACS Macro Lett. 2012, 1 (2) 305-309
36. van Gurp, M.; Palmen, J. Time-Temperature Superposition for Polymer Blends Rheol. Bull. 1998, 67, 5-8
37. Pakula, T.; Zhang, Y.; Matyjaszewski, K.; Lee, H.-i.; Boerner, H.; Qin, S.; Berry, G. C. Molecular brushes as Super-soft elastomers Polymer 2006, 47 (20) 7198-7206