Investigating Li Microstructure Formation on Li Anodes for Lithium Batteries by in Situ 6Li/7Li NMR and SEM

Journal of Physical Chemistry C

Volumn 119, Issue 29, 2015, Pages 16443-16451

  Chang, Hee Jung ^a   Trease, Nicole M ^a,d   Ilott, Andrew J ^b   Zeng, Dongli ^c   Du, Lin Shu ^a   Jerschow, Alexej ^b   Grey, Clare P ^a,d  

^a STONY BROOK UNIVERSITY   (United States)

^b NEW YORK UNIVERSITY   (United States)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

^d UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ANODES; LITHIUM; LITHIUM-ION BATTERIES; MICROSTRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY;

ELECTROCHEMICAL CONDITIONS; HIGHER FREQUENCIES; ISOTOPICALLY ENRICHED; LI NMR SPECTROSCOPIES; LITHIUM ION RECHARGEABLE BATTERIES; METAL COUNTER ELECTRODES; MICROSTRUCTURE FORMATION; NUCLEAR MAGNETIC RESONANCE (NMR);

LITHIUM COMPOUNDS;

EID: 84937826111     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b03396     Document Type: Article

References (48)

1. Armand, M.; Tarascon, J. M. Building Better Batteries Nature 2008, 451, 652-657
2. Brissot, C.; Rosso, M.; Chazalviel, J. N.; Lascaud, S. Dendritic Growth Mechanisms in Lithium/Polymer Cells J. Power Sources 1999, 81, 925-929
3. Tarascon, J. M.; Armand, M. Issues and Challenges Facing Rechargeable Lithium Batteries Nature 2001, 414, 359-367
4. Rosso, M.; Brissot, C.; Teyssot, A.; Dolle, M.; Sannier, L.; Tarascon, J. M.; Bouchetc, R.; Lascaud, S. Dendrite Short-Circuit and Fuse Effect on Li/Polymer/Li Cells Electrochim. Acta 2006, 51, 5334-5340
5. Fong, R.; Vonsacken, U.; Dahn, J. R. Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical-Cells J. Electrochem. Soc. 1990, 137, 2009-2013
6. Scrosati, B. Recent Advances in Lithium Ion Battery Materials Electrochim. Acta 2000, 45, 2461-2466
7. Zhang, S. S. A Review on the Separators of Liquid Electrolyte Li-Ion Batteries J. Power Sources 2007, 164, 351-364
8. Bates, J. B. Protective Lithium Ion Conducting Ceramic Coating for Lithium Metal Anodes and Associate Method. U.S. patent 5314765, 1994.
9. Augustin, S.; Hennige, V.; Horpel, G.; Hying, C. Ceramic but Flexible: New Ceramic Membrane Foils for Fuel Cells and Batteries Desalination 2002, 146, 23-28
10. Hirai, T.; Yoshimatsu, I.; Yamaki, J. Influence of Electrolyte on Lithium Cycling Efficiency with Pressurized Electrode Stack J. Electrochem. Soc. 1994, 141, 611-614
11. Aurbach, D.; Zinigrad, E.; Cohen, Y.; Teller, H. A Short Review of Failure Mechanisms of Lithium Metal and Lithiated Graphite Anodes in Liquid Electrolyte Solutions Solid State Ionics 2002, 148, 405-416
12. Arora, P.; Zhang, Z. M. Battery Separators Chem. Rev. 2004, 104, 4419-4462
13. Goodenough, J. B.; Kim, Y. Challenges for Rechargeable Li Batteries Chem. Mater. 2010, 22, 587-603
14. Aurbach, D.; Gofer, Y.; Langzam, J. The Correlation between Surface-Chemistry, Surface-Morphology, and Cycling Efficiency of Lithium Electrodes in a Few Polar Aprotic Systems J. Electrochem. Soc. 1989, 136, 3198-3205
15. Crowther, O.; West, A. C. Effect of Electrolyte Composition on Lithium Dendrite Growth J. Electrochem. Soc. 2008, 155, A806-A811
16. Zhang, X. W.; Li, Y. X.; Khan, S. A.; Fedkiw, P. S. Inhibition of Lithium Dendrites by Fumed Silica-Based Composite Electrolytes J. Electrochem. Soc. 2004, 151, A1257-A1263
17. Dolle, M.; Sannier, L.; Beaudoin, B.; Trentin, M.; Tarascon, J. M. Live Scanning Electron Microscope Observations of Dendritic Growth in Lithium/Polymer Cells Electrochem. Solid-State Lett. 2002, 5, A286-A289
18. Arakawa, M.; Tobishima, S.; Nemoto, Y.; Ichimura, M.; Yamaki, J. Lithium Electrode Cycleability and Morphology Dependence on Current-Density J. Power Sources 1993, 43, 27-35
19. Tobishima, S. I.; Hayashi, K.; Nemoto, Y.; Yamaki, J. I. Multi-Component Nonaqueous Electrolytes for Rechargeable Lithium Cells Electrochim. Acta 1998, 43, 925-933
20. Yuichi Sato, M. K.; Niki, H.; Ueno, M.; Murata, K.; Shirogami, T.; Takamura, T. Long Life Sealed Nickel-Zinc Cell Using a New Separator J. Power Sources 1983, 9, 147-159
21. Trease, N. M.; Zhou, L.; Chang, H. J.; Zhu, B. Y.; Grey, C. P. In Situ NMR of Lithium Ion Batteries: Bulk Susceptibility Effects and Practical Considerations Solid State Nucl. Magn. Reson. 2012, 42, 62-70
22. Liu, X. H.; Zhong, L.; Zhang, L. Q.; Kushima, A.; Mao, S. X.; Li, J.; Ye, Z. Z.; Sullivan, J. P.; Huang, J. Y. Lithium Fiber Growth on the Anode in a Nanowire Lithium Ion Battery During Charging. Appl. Phys. Lett. 2011, 98, 183107.
23. Orsini, F.; Du Pasquier, A.; Beaudoin, B.; Tarascon, J. M.; Trentin, M.; Langenhuizen, N.; De Beer, E.; Notten, P. In Situ Scanning Electron Microscopy (SEM) Observation of Interfaces within Plastic Lithium Batteries J. Power Sources 1998, 76, 19-29
24. Lopez, C. M.; Vaughey, J. T.; Dees, D. W. Morphological Transitions on Lithium Metal Anodes J. Electrochem. Soc. 2009, 156, A726-A729
25. Hoffman, R. E. Measurement of Magnetic Susceptibility and Calculation of Shape Factor of NMR Samples J. Magn. Reson. 2006, 178, 237-247
26. Epelboin, I.; Froment, M.; Garreau, M.; Thevenin, J.; Warin, D. Behavior of Secondary Lithium and Aluminum-Lithium Electrodes in Propylene Carbonate J. Electrochem. Soc. 1980, 127, 2100-2104
27. Yoshimatsu, I.; Hirai, T.; Yamaki, J. Lithium Electrode Morphology During Cycling in Lithium Cells J. Electrochem. Soc. 1988, 135, 2422-2427
28. 3 J. Mater. Chem. 2012, 22, 8799-8809
29. Key, B.; Morcrette, M.; Tarascon, J. M.; Grey, C. P. Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)Lithiation Mechanisms J. Am. Chem. Soc. 2011, 133, 503-512
30. Grey, C. P.; Lee, Y. J. Lithium MAS NMR Studies of Cathode Materials for Lithium-Ion Batteries Solid State Sci. 2003, 5, 883-894
31. Key, B.; Bhattacharyya, R.; Morcrette, M.; Seznec, V.; Tarascon, J. M.; Grey, C. P. Real-Time NMR Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries J. Am. Chem. Soc. 2009, 131, 9239-9249
32. Chevallier, F.; Letellier, M.; Morcrette, M.; Tarascon, J. M.; Frackowiak, E.; Rouzaud, J. N.; Beguin, F. In Situ Li-7 Nuclear Magnetic Resonance Observation of Reversible Lithium Insertion into Disordered Carbons Electrochem. Solid-State Lett. 2003, 6, A225-A228
33. Jung, H. Elucidation of the Local and Long-Range Structural Changes That Occur in Germanium Anodes in Lithium-Ion Batteries Chem. Mater. 2015, 27, 1031-1041
34. Bhattacharyya, R.; Key, B.; Chen, H.; Best, A. S.; Hollenkamp, A. F.; Grey, C. P. In Situ NMR Observation of the Formation of Metallic Lithium Microstructures in Lithium Batteries Nat. Mater. 2010, 9, 504-510
35. Lide, D. R.; Frederikse, H. P. R. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data, 78 th ed.; CRC Press: Boca Raton, FL, USA, 1997.
36. Kittel, C. Introduction to Solid State Physics, 8 th ed.; Wiley: New York, 1976; Vol. 8.
37. Dyson, F. J. Electron Spin Resonance Absorption in Metals 2. Theory of Electron Diffusion and the Skin Effect Phys. Rev. 1955, 98, 349-359
38. 7Li MRI of Li-Ion Battery Electrodes Reveals Microstructural Lithium Location Nat. Mater. 2012, 11, 311-315
39. Wandt, J.; Marino, C.; Jakes, P.; Eichel, R.; Gasteiger, H. A.; Granwehr, J. Operando Electron Paramagnetic Resonance Spectroscopy-Formation of Mossy Lithium on Lithium Anodes During Charge/Discharge Cycling Energy Environ. Sci. 2015, 8, 1358-1367
40. Sathiya, M.; Leriche, J. B.; Salager, E.; Gourier, D.; Tarascon, J. M.; Vezin, H. Electron Paramagnetic Resonance Imaging for Real-Time Monitoring of Li-Ion Batteries Nat. Commun. 2015, 6, 6276
41. http://www.gelifesciences.com/webapp/wcs/stores/servlet/catalog/en/GELifeSciences-us/products/AlternativeProductStructure-16176/28418346 (accessed May 13, 2015).
42. Salomir, R.; de Senneville, B. D.; Moonen, C. T. W. A Fast Calculation Method for Magnetic Field Inhomogeneity Due to an Arbitrary Distribution of Bulk Susceptibility Concepts Magn. Reson. 2003, 19B, 26-34
43. Marques, J. P.; Bowtell, R. Application of a Fourier-Based Method for Rapid Calculation of Field Inhomogeneity Due to Spatial Variation of Magnetic Susceptibility Concepts Magn. Reson. B 2005, 25B, 65-78
44. 7Li MRI Experiments and Calculations J. Magn. Reson. 2014, 245, 143-149
45. Harris, R. K.; Becker, E. D.; De Menezes, S. M. C.; Granger, P.; Hoffman, R. E.; Zilm, K. W. Further Conventions for NMR Shielding and Chemical Shifts Iupac Recommendations 2008 (reprinted from Pure Appl. Chem. 2008, 80, 59) Solid State Nucl. Magn. Reson. 2008, 33, 41-56
46. Slichter, C. P. Principles of Magnetic Resonance, 3 rd ed.; Springer-Verlag: Berlin, Germany, 1990; Vol. 1.
47. Kubo, A.; Spaniol, T. P.; Terao, T. The Effect of Bulk Magnetic Susceptibility on Solid State NMR Spectra of Paramagnetic Compounds J. Magn. Reson. 1998, 133, 330-340
48. 7Li Nuclear Magnetic Resonance Spectroscopy J. Power Sources 2013, 228, 237-243