Tailoring the yield and characteristics of wood cellulose nanocrystals (CNC) using concentrated acid hydrolysis

Cellulose

Volumn 22, Issue 3, 2015, Pages 1753-1762

  Chen, Liheng ^a,c   Wang, Qianqian ^b,c   Hirth, Kolby ^c   Baez, Carlos ^c   Agarwal, Umesh P ^c   Zhu, J Y ^c,d  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

^b JIANGSU UNIVERSITY   (China)

^c FOREST PRODUCTS LABORATORY   (United States)

^d UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

Cellulose nanocrystals (CNC); CNC yield optimization; Concentrated acid hydrolysis; Crystal length and morphology; Crystallinity; Surface charge

Indexed keywords

CELLULOSE; CELLULOSE DERIVATIVES; HYDROLYSIS; KRAFT PULP; MORPHOLOGY; NANOCRYSTALS; OPTICAL PROPERTIES; SURFACE CHARGE;

CELLULOSE NANOCRYSTAL (CNC); CONCENTRATED ACIDS; CRYSTAL LENGTH; CRYSTALLINITIES; YIELD OPTIMIZATION;

WOOD;

EID: 84937758344     PISSN: 09690239     EISSN: 1572882X     Source Type: Journal    
DOI: 10.1007/s10570-015-0615-1     Document Type: Article

References (32)

1. Agarwal UP, Reiner RS, Ralph SA (2010) Celulose I crystallinity determination using FT-Raman spectroscopy: univariate and multivariate methods. Cellulose 17(4):721–733
2. Araki J, Wada M, Kuga S, Okano T (1998) Flow properties of microcrystalline cellulose suspension prepared by acid treatment of native cellulose. Colloids Surf A 142:75–82
3. Beck S, Bouchard J, Berry R (2011) Controlling the reflection wavelength of iridescent solid films of nanocrystalline cellulose. Biomacromolecules 12(1):167–172
4. Beck-Candanedo S, Roman M, Gray DG (2005) Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules 6:1048–1054
5. Biyani MV, Foster EJ, Weder C (2013) Light-healable supramolecular nanocomposites based on modified cellulose nanocrystals. ACS Macro Lett 2(3):236–240
6. Bondeson D, Mathew A, Oksman K (2006) Optimization of the isolation of manocrystals from microcrystalline cellulose by acid hydrolysis. Cellulose 13:171–180
7. Camarero Espinosa S, Kuhnt T, Foster EJ, Weder C (2013) Isolation of thermally stable cellulose nanocrystals by phosphoric acid hydrolysis. Biomacromolecules 14(4):1223–1230
8. Capadona JR, Shanmuganathan K, Tyler DJ, Rowan SJ, Weder C (2008) Stimuli-responsive polymer nanocomposites inspired by the sea cucumber dermis. Science 319(5868):1370–1374
9. Chen Y, Liu C, Chang PR, Cao X, Anderson DP (2009) Bionanocomposites based on pea starch and cellulose nanowhiskers hydrolyzed from pea hull fibre: effect of hydrolysis time. Carbohydr Polym 76(4):607–615
10. Coulibaly S, Roulin A, Balog S, Biyani MV, Foster EJ, Rowan SJ, Fiore GL, Weder C (2014) Reinforcement of optically healable supramolecular polymers with cellulose nanocrystals. Macromolecules 47(1):152–160
11. Davis MW (1998) A rapid modified method for compositional carbohydrate analysis of lignocellulosics by high pH anion-exchange chromatography with pulsed amperometric detection (HPAEC/PAD). J Wood Chem Technol 18(2):235–352
12. Dong XM, Gray DG (1997) Induced circular dichroism of isotropic and magnetically-oriented chiral nematic suspensions of cellulose crystallites. Langmuir 13(11):3029–3034
13. Dong XM, Revol JF, Gray DG (1998) Effect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose. Cellulose 5:19–32
14. Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500
15. Hamad WY, Hu TQ (2010) Structure–process–yield interrelations in nanocrystalline cellulose extraction. Can J Chem Eng 88:392–402
16. Hsu L, Weder C, Rowan SJ (2011) Stimuli-responsive, mechanically-adaptive polymer nanocomposites. J Mater Chem 21(9):2812–2822
17. Kargarzadeh H, Ahmad I, Abdullah I, Dufresne A, Zainudin SY, Sheltami RM (2012) Effects of hydrolysis conditions on the morphology, crystallinity, and thermal stability of cellulose nanocrystals extracted from kenaf bast fibers. Cellulose 19(3):855–866
18. Kelly JA, Shukaliak AM, Cheung CCY, Shopsowitz KE, Hamad WY, MacLachlan MJ (2013) Responsive photonic hydrogels based on nanocrystalline cellulose. Angew Chem Int Ed 52(34):8912–8916
19. Luo X, Gleisner R, Tian S, Negron J, Horn E, Pan XJ, Zhu JY (2010) Evaluation of mountain beetle infested lodgepole pine for cellulosic ethanol production by SPORL pretreatment. Ind Eng Chem Res 49(17):8258–8266
20. Marchessault RH, Morehead FF, Koch MJ (1961) Some hydrodynamic properties of neutral suspensions of cellulose crystallites as realted to size and shape. J Colloid Sci 16:327–344
21. Mukherjee SM, Woods HJ (1953) X-ray and electron microscope studies of the degradation of cellulose by sulphuric acid. Biochim Biophys Acta 10:499–511
22. Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Ceseealrlcuh lose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3:10
23. Potter KA, Jorfi M, Householder KT, Foster EJ, Weder C, Capadona JR (2014) Curcumin-releasing mechanically adaptive intracortical implants improve the proximal neuronal density and blood-brain barrier stability. Acta Biomater 10(5):2209–2222
24. Revol J-F, Godbout DL, Gray DG; Pulp and Paper Research Institute of Canada, assignee (1997) Solidified liquid crystals of cellulose with optically variable properties. US Patent 5, 629, 055
25. Revol J-F, Godbout L, Dong X-M, Gray DG, Chanzy H, Maret G (1994) Chiral nematic suspensions of cellulose crystallites; phase separation and magnetic field orientation. Liq Cryst 16:127–134
26. Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794
27. Šturcová A, Davies GR, Eichhorn SJ (2005) Elastic modulus and stress-transfer properties of tunicate cellulose whiskers. Biomacromolecules 6(2):1055–1061
28. Wang QQ, Zhu JY, Reiner RS, Verrill SP, Baxa U, McNeil SE (2012) Approaching zero cellulose loss in cellulose nanocrystal (CNC) production: recovery and characterization of cellulosic solid residues (CSR) and CNC. Cellulose 19(6):2033–2047
29. Wang Q, Zhao X, Zhu JY (2014) Kinetics of strong acid hydrolysis of a bleached kraft pulp for producing cellulose nanocrystals (CNCs). Ind Eng Chem Res 53(27):11007–11014
30. Xu X, Wang H, Jiang L, Wang X, Payne SA, Zhu JY, Li R (2014) Comparison between cellulose nanocrystal and cellulose nanofibril reinforced poly(ethylene oxide) nanofibers and their novel shish-kebab-like crystalline structures. Macromolecules 47(10):3409–3416
31. Yu H, Qin Z, Liang B, Liu N, Zhou Z, Chen L (2013) Facile extraction of thermally stable cellulose nanocrystals with a high yield of 93 % through hydrochloric acid hydrolysis under hydrothermal conditions. J Mater Chem A 1(12):3938–3944
32. Zhou Y, Fuentes-Hernandez C, Khan TM, Liu JC, Hsu J, Shim JW, Dindar A, Youngblood JP, Moon RJ, Kippelen B (2013) Recyclable organic solar cells on cellulose nanocrystal substrates. Sci Rep 3:1536