Production of formic acid from CO2 reduction by means of potassium borohydride at ambient conditions

Chemical Engineering Science

Volumn 137, Issue , 2015, Pages 301-307

  Fletcher, Cameron ^a   Jiang, Yijiao ^b   Amal, Rose ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

^b MACQUARIE UNIVERSITY   (Australia)

Author keywords

Borohydride; CO2 reduction; Formic acid formation; In situ NMR technique; Reaction mechanism

Indexed keywords

CARBON; CARBON DIOXIDE; FORMIC ACID; POTASSIUM;

AMBIENT CONDITIONS; BOROHYDRIDE SOLUTIONS; BOROHYDRIDES; ELEMENTARY REACTION; NUCLEAR MAGNETIC RESONANCE TECHNIQUES; REACTION MECHANISM; REACTION TEMPERATURE; SITU NMR;

NUCLEAR MAGNETIC RESONANCE;

EID: 84936946863     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2015.06.040     Document Type: Article

References (24)

1. Andrieux J., Demirci U.B., Hannauer J., Gervais C., Goutaudier C., Miele P. Spontaneous hydrolysis of sodium borohydride in harsh conditions. Int. J. Hydrogen Energy 2011, 36:224-233.
2. 11B NMR of model systems. Dalt. Trans. 2004, 2621-2634.
3. Brown H.C., Krishnamurthy S. Forty years of hydride reductions. Tetrahedron 1979, 35:567-607.
4. Centi G., Iaquaniello G., Perathoner S. Can we afford to waste carbon dioxide? Carbon dioxide as a valuable source of carbon for the production of light olefins. ChemSusChem 2011, 4:1265-1273.
5. Centi G., Perathoner S. Opportunities and prospects in the chemical recycling of carbon dioxide to fuels. Catal. Today 2009, 148:191-205.
6. Churikov A.V., Gamayunova I.M., Zapsis K.V., Churikov M.A., Ivanishchev A.V. Influence of temperature and alkalinity on the hydrolysis rate of borohydride ions in aqueous solution. Int. J. Hydrogen Energy 2012, 37:335-344.
7. Dovgaliuk I., Ban V., Sadikin Y., Černý R., Aranda L., Casati N., Devillers M., Filinchuk Y. The first halide-free bimetallic aluminum borohydride: synthesis, structure, stability, and decomposition pathway. J. Phys. Chem. C 2014, 118:145-153.
8. 2-promoted hydrolysis of KBH4 for efficient hydrogen co-generation. Int. J. Hydrogen Energy 2014, 39:19603-19608.
9. 11B NMR measurements. J. Phys. Chem. B 2006, 110:17024-17033.
10. 3 as an intermediate in tetrahydridoborate hydrolysis. J. Am. Chem. Soc. 1972, 94:6371-6376.
11. Liu B.H., Li Z.P. Current status and progress of direct borohydride fuel cell technology development. J. Power Sources 2009, 187:291-297.
12. Molina Concha B., Chatenet M., Ticianelli E.A., Lima F.H.B. In situ infrared (FTIR) study of the mechanism of the borohydride oxidation reaction on smooth Pt electrode. J. Phys. Chem. C 2011, 115:12439-12447.
13. Ouyang L.Z., Zhong H., Li Z.M., Cao Z.J., Wang H., Liu J.W., Zhu X.K., Zhu M. Low-cost method for sodium borohydride regeneration and the energy efficiency of its hydrolysis and regeneration process. J. Power Sources 2014, 269:768-772.
14. Quadrelli E.A., Centi G. Green carbon dioxide. ChemSusChem 2011, 4:1179-1181.
15. Reed J.W., Jolly W.L. Reduction of organic compounds with the hydroxyborohydride ion. J. Org. Chem. 1977, 42:3963-3965.
16. Richards S.A., Hollerton J.C. Delving Deeper. Essential Practical NMR for Organic Chemistry 2010, 67-100. John Wiley & Sons, Ltd, Chichester, United Kingdom.
17. Ruman T., Kuśnierz A., Jurkiewicz A., Leś A., Rode W. The synthesis, reactivity and 1H NMR investigation of the hydroxyborohydride anion. Inorg. Chem. Commun. 2007, 10:1074-1078.
18. Sahin O., Dolas H., Ozdemir M. The effect of various factors on the hydrogen generation by hydrolysis reaction of potassium borohydride. Int. J. Hydrogen Energy 2007, 32:2330-2336.
19. Sakakura T., Choi J.-C., Yasuda H. Transformation of carbon dioxide. Chem. Rev. 2007, 107:2365-2387.
20. 3OH- hydrolyzed intermediate on the AgI surface treated with different electrochemical methods. Catal. Today 2011, 170:120-125.
21. Santos D.M.F., Sequeira C.a.C. Cyclic voltammetry investigation of borohydride oxidation at a gold electrode. Electrochim. Acta 2010, 55:6775-6781.
22. Schreiner P.R., Schaefer H.F., von Ragué Schleyer P. The structure and stability of BH5. Does correlation make it a stable molecule? Qualitative changes at high levels of theory. J. Chem. Phys. 1994, 101:7625.
23. 2 hydrogenation to methanol at pressures up to 950bar. J. Supercrit. Fluids 2013, 78:70-77.
24. Topham S., Bazzanella A., Schiebahn S., Luhr S., Zhao L., Otto A., Stolten D. Carbon Dioxide. Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany.